[논문]Facile two-step synthesis of innovative anode design from tin-aminoclay (SnAC) and rGO for Li-ion batteries

Nhung Pham, Tuyet; Ko, Jaewook; Khac Hoang Bui, Vu; So, Seongjoon; Uk Lee, Hyun; Hur, Jaehyun; Lee, Young-Chul

doi:10.1016/j.apsusc.2020.147435

[해외논문] Facile two-step synthesis of innovative anode design from tin-aminoclay (SnAC) and rGO for Li-ion batteries

Applied surface science, v.532, 2020년, pp.147435 -

Nhung Pham, Tuyet (Phenikaa University Nano Institute (PHENA), PHENIKAA University) , Ko, Jaewook (Department of Chemical and Biological Engineering, Gachon University) , Khac Hoang Bui, Vu (Department of BioNano Technology, Gachon University) , So, Seongjoon (Department of Chemical and Biological Engineering, Gachon University) , Uk Lee, Hyun (Advanced Nano-surface Research Group, Korea Basic Science Institute (KBSI)) , Hur, Jaehyun (Department of Chemical and Biological Engineering, Gachon University) , Lee, Young-Chul (Department of BioNano Technology, Gachon University)

Abstract ▼ AI-Helper

Abstract A tin-aminoclay/reduced graphene oxide (SnO2-SnAC/rGO) electrode with significantly enhanced electrochemical performance was successfully fabricated by a facile two-step method entailing microwave treatment (1st step) and heat treatment (2nd step) synthesis processes. In step 1, the complete reduction of GO to rGO by microwave ensures the removal of most oxygen-containing functional groups on the material surface leading to improvement of its electrical conductivity along with the formation of SnO2 dots of 3–4 nm diameter. In step 2, the tin crystals are formed more stably in the SnAC/rGO framework by the heat-treatment process under Argon (Ar) gas via the direct conversion process of Sn2+ active sites within the SnAC structure. With this two-step process, the synthesized material possesses many unique synergistic effects, all leading to beneficial features (i.e., improved specific capacity, high rate capability, and long cycle life stability compared with SnO2-SnAC and pure rGO electrodes) for application to battery electrodes. Especially, SnO2-SnAC/rGO-500 °C (1:1) exhibits outstanding performance in terms of cyclic performance (650 mAh g−1 after 100 cycles at 100 mA g−1) and rate capability. Highlights SnO2-SnAC/rGO evolution by facile two-step synthesis. Direct growth of SnO2 nanoparticles within SnAC/rGO matrix. Synergistic effects between active SnO2 NPs and SnAC/rGO matrix. Promising anode material with high specific capacity of 950 mAh g−1. Graphical abstract [DISPLAY OMISSION]

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참고문헌 (48)

Chem. Soc. Rev. Chen 44 6230 2015 10.1039/C5CS00147A Structural design of graphene for use in electrochemical energy storage devices

상세보기
J. Power Sources Oh 244 575 2013 10.1016/j.jpowsour.2013.01.120 Facile synthesis of carbon layer-entangled Fe2O3 clusters as anode materials for improved Li-ion batteries

상세보기
Appl. Surf. Sci. Nguyen 509 2020 10.1016/j.apsusc.2019.144718 High-Performance ZnTe-TiO2-C Nanocomposite with Half-Cell and Full-Cell Applications as Promising Anode Material for Li-Ion Batteries

상세보기
J. Mater. Chem. A Wu 6 12932 2018 10.1039/C8TA03968B The recent progress of nitrogen-doped carbon nanomaterials for electrochemical batteries

상세보기
J. Power Sources Wang 413 117 2019 10.1016/j.jpowsour.2018.12.031 Probing C3N/Graphene heterostructures as anode materials for Li-ion batteries

상세보기
Thin Solid Films Oh 546 200 2013 10.1016/j.tsf.2013.05.136 Fabrication of thin silica layer-coated magnetite clusters (nFe3O4/silica) as anode materials for improved Li-ion batteries

상세보기
Sci. Rep. Zubir 4 4594 2014 10.1038/srep04594 Structural and functional investigation of graphene oxide-Fe3O4 nanocomposites for the heterogeneous Fenton-like reaction

상세보기
Phys. Chem. Chem. Phys. Ji 13 7170 2011 10.1039/c1cp20455f Fe3O4 nanoparticle-integrated graphene sheets for high-performance half and full lithium ion cells

상세보기
Electrochim. Acta Lian 58 81 2011 10.1016/j.electacta.2011.08.088 A novel Fe3O4-SnO2-graphene ternary nanocomposite as an anode material for lithium-ion batteries

상세보기
J. Power Sources Mun 437 2019 10.1016/j.jpowsour.2019.226946 Tin oxide evolution by heat-treatment with tin-aminoclay (SnAC) under argon condition for lithium-ion battery (LIB) anode applications

상세보기
J. Phys. Chem. C Xiang 122 9302 2018 10.1021/acs.jpcc.8b00768 Borophene as Conductive Additive to Boost the Performance of MoS2-Based Anode Materials

상세보기
Nanoscale Zhang 8 15340 2016 10.1039/C6NR04186H Borophene as an extremely high capacity electrode material for Li-ion and Na-ion batteries

상세보기
Nano. Res. Peng 10 3136 2017 10.1007/s12274-017-1531-5 Unexpected elastic isotropy in a black phosphorene/TiC2 van der Waals heterostructure with flexible Li-ion battery anode applications

상세보기
Acs Appl. Mater. Inter. Peng 8 13449 2016 10.1021/acsami.6b03368 Blue Phosphorene/MS2 (M = Nb, Ta) Heterostructures As Promising Flexible Anodes for Lithium-Ion Batteries

상세보기
Electrochim. Acta Ye 266 170 2018 10.1016/j.electacta.2018.02.032 In situ fabrication of nitrogen-doped carbon-coated SnO2/SnS heterostructures with enhanced performance for lithium storage

상세보기
Energy Environ. Sci. Zhang 7 302 2013 10.1039/C3EE43123A Strongly coupled carbon nanofiber-metal oxide coaxial nanocables with enhanced lithium storage properties

상세보기
J. Power Sources Li 282 1 2015 10.1016/j.jpowsour.2015.02.016 Rational design of metal oxide nanocomposite anodes for advanced lithium ion batteries

상세보기
Electrochim. Acta Hai 260 129 2018 10.1016/j.electacta.2017.11.068 High-performance MoS2-based nanocomposite anode prepared by high-energy mechanical milling: The effect of carbonaceous matrix on MoS2

상세보기
J. Nanosci. Nanotechnol. Kim 19 6630 2019 10.1166/jnn.2019.17085 Effects of Various Hybrid Carbon Matrices on the ZnSe Composite Anode for Lithium-Ion Batteries

상세보기
J. Power Sources Sarkar 306 791 2016 10.1016/j.jpowsour.2015.12.094 Heterostructure composites of rGO/GeO2/PANI with enhanced performance for Li ion battery anode material

상세보기
Chem. Commun. Chen 50 8856 2014 10.1039/C4CC02886D Mesoporous single crystals Li4Ti5O12 grown on rGO as high-rate anode materials for lithium-ion batteries

상세보기
Part. Part. Syst. Char. Wang 34 1700141 2017 10.1002/ppsc.201700141 High Rate and Long Cycle Life of a CNT/rGO/Si Nanoparticle Composite Anode for Lithium-Ion Batteries

상세보기
Nano Energy Chang 15 679 2015 10.1016/j.nanoen.2015.05.020 Three-dimensional carbon-coated Si/rGO nanostructures anchored by nickel foam with carbon nanotubes for Li-ion battery applications

상세보기
Cryst. Eng. Comm. Luo 17 1741 2015 10.1039/C4CE02315C Assembly of SnO2 quantum dots on RGO to form SnO2/N doped RGO as a high-capacity anode material for lithium ion batteries

상세보기
Cryst. Eng. Comm. Park 18 6049 2016 10.1039/C6CE00362A The confinement of SnO2 nanocrystals into 3D RGO architectures for improved rate and cyclic performance of LIB anode

상세보기
J. Mater. Chem. Datta 1 6707 2013 10.1039/c3ta00100h Aminoclay: a functional layered material with multifaceted applications

상세보기
App. Clay Sci. Narayanamoorthy 104 66 2015 10.1016/j.clay.2014.11.007 Physicochemical characterization of amino functionalized synthetic clay/Nafion nanocomposite film with embedded platinum nanoparticles for PEM fuel cells

상세보기
J. Mater. Chem. Patil 18 4605 2008 10.1039/b805653f Self-assembly of bio-inorganic nanohybrids using organoclay building blocks

상세보기
RSC Adv. Lee 4 4122 2014 10.1039/C3RA46602G Aminoclay-templated nanoscale zero-valent iron (nZVI) synthesis for efficient harvesting of oleaginous microalga, Chlorella sp. KR-1

상세보기
J. Mater. Chem. Datta 17 613 2007 10.1039/B617198B Water-solubilized aminoclay-metal nanoparticle composites and their novel properties

상세보기
RCS Adv. Pham 9 10536 2019 Preparation of Sn-aminoclay (SnAC)-templated Fe3O4 nanoparticles as an anode material for lithium-ion batteries
RSC Adv. Zong 3 23638 2013 10.1039/c3ra43359e Facile preparation, high microwave absorption and microwave absorbing mechanism of RGO-Fe3O4 composites

상세보기
J. Power Sources Zhang 280 107 2015 10.1016/j.jpowsour.2015.01.092 Rapid synthesis of α-Fe2O3/rGO nanocomposites by microwave autoclave as superior anodes for sodium-ion batteries

상세보기
J. Mater. Chem. A Botas 3 13402 2015 10.1039/C5TA03265B Sn-and SnO2-graphene flexible foams suitable as binder-free anodes for lithium ion batteries

상세보기
Arab. J. Chem. Hurtado 27 2017 One-step synthesis of reduced graphene oxide/gold nanoparticles under ambient conditions
Chem. Eng. J. Tran 395 2020 Thermolytically grafted silicon particles with ultrathin carbonaceous coating rich of phenyl moieties as lithium-storage anode material

상세보기
Adv. Mater. Compton 22 892 2010 10.1002/adma.200902069 Electrically conductive “alkylated” graphene paper via chemical reduction of amine-functionalized graphene oxide paper

상세보기
Nanoscale Achari 5 5316 2013 10.1039/c3nr01108a Amphiphilic aminoclay-RGO hybrids: a simple strategy to disperse a high concentration of RGO in water

상세보기
Appl. Sci. Jin 7 19 2017 10.3390/app7010019 Characterization of Reduced Graphene Oxide (rGO)-Loaded SnO2 Nanocomposite and Applications in C2H2 Gas Detection

상세보기
Sci. Rep. Wang 5 9164 2015 10.1038/srep09164 Designed hybrid nanostructure with catalytic effect: beyond the theoretical capacity of SnO2 anode material for lithium ion batteries

상세보기
Sci. Rep. Zhu 7 3276 2017 10.1038/s41598-017-03603-1 Construction of SnO2−Graphene Composite with Half-Supported Cluster Structure as Anode toward Superior Lithium Storage Properties

상세보기
J. Power Sources Kim 327 171 2016 10.1016/j.jpowsour.2016.07.053 TiO2-reduced graphene oxide nanocomposites by microwave-assisted forced hydrolysis as excellent insertion anode for Li-ion battery and capacitor

상세보기
Electrochim. Acta Liu 166 12 2015 10.1016/j.electacta.2015.03.081 Fe2O3-reduced graphene oxide composites synthesized via microwave-assisted method for sodium ion batteries

상세보기
Mat. Sci. Eng: A Dutkiewicz 628 124 2015 10.1016/j.msea.2015.01.018 Microstructure and properties of bulk copper matrix composites strengthened with various kinds of graphene nanoplatelets

상세보기
Nanoscale Guex 9 9562 2017 10.1039/C7NR02943H Experimental review: chemical reduction of graphene oxide (GO) to reduced graphene oxide (rGO) by aqueous chemistry

상세보기
Nano Energy Cong 13 482 2015 10.1016/j.nanoen.2015.03.016 Flexible nitrogen-doped graphene/SnO2 foams promise kinetically stable lithium storage

상세보기
Curr. Appl. Phys. Kim 13 1923 2013 10.1016/j.cap.2013.08.003 Synthesis and characterization of TiO2-coated magnetite clusters (nFe3O4@TiO2) as anode materials for Li-ion batteries

상세보기
Chem. Eng. J. Bui 336 757 2018 10.1016/j.cej.2017.12.052 Aminoclays for biological and environmental applications: An updated review

상세보기

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