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[해외논문] Cobalt-Hydride-Catalyzed Hydrosilylation of 3-Alkynes Accompanying π-Bond Migration

ACS catalysis, v.11 no.3, 2021년, pp.1548 - 1553  

Kim, Yeong Bum (Department of Chemistry , Korea Advanced Institute of Science and Technology (KAIST) , Daejeon 34141 , Korea) ,  Kim, Dongwook (Center for Catalytic Hydrocarbon Functionalization , Institute for Basic Science (IBS) , Daejeon 34141 , Korea) ,  Dighe, Shashikant U. (Center for Catalytic Hydrocarbon Functionalization , Institute for Basic Science (IBS) , Daejeon 34141 , Korea) ,  Chang, Sukbok (Center for Catalytic Hydrocarbon Functionalization , Institute for Basic Science (IBS) , Daejeon 34141 , Korea) ,  Park, Jung-Woo

Abstract AI-Helper 아이콘AI-Helper

We describe a protocol for cobalt-catalyzed hydrosilylation of 3-alkynes with accompanying π-bond migration. Mechanistic studies indicate that (i) cobalt(I)-hydride bearing a bulky bisphosphine ligand is the key intermediate and (ii) π-bond migration occurs prior to hydrosilylation. The cascad...

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