[논문]Plastic waste residue-derived boron and nitrogen co-doped porous hybrid carbon for a modified separator of a lithium sulfur battery

Gim, Hyeonseo; Park, Jae Hyun; Choi, Won Yeong; Yang, Jeongwoo; Kim, Dohyeun; Lee, Kyong-Hwan; Lee, Jae W.

doi:10.1016/j.electacta.2021.138243

[해외논문] Plastic waste residue-derived boron and nitrogen co-doped porous hybrid carbon for a modified separator of a lithium sulfur battery

Electrochimica acta, v.380, 2021년, pp.138243 -

Gim, Hyeonseo (Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST)) , Park, Jae Hyun (Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST)) , Choi, Won Yeong (Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST)) , Yang, Jeongwoo (Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST)) , Kim, Dohyeun (Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST)) , Lee, Kyong-Hwan (Energy Resources Upcycling Research Laboratory, Korea Institute of Energy Research (KIER)) , Lee, Jae W. (Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST))

Abstract ▼ AI-Helper

Abstract The continuous consumption of plastic has caused plastic waste accumulation and negative impacts on the environment. In response to this issue, plastic waste recycling through a pyrolysis process to produce liquid oils has been proposed. However, the pyrolysis process involves discarded or incinerated residue and effective utilization of the pyrolytic residue is required accordingly. This work introduces a hybrid carbon material that has not only high porosity but also polar sites, such as metal oxides and multi-hetero-atom (boron and nitrogen) doping sites. This material was synthesized from pyrolytic residue through a top-down process, unlike the conventional bottom-up synthesis process employed for hybrid carbon. The resultant material is used as a functional layer of a modified separator, and it can effectively suppress the shuttle effect with excellent lithium polysulfide trapping ability and positively contribute to redox reaction kinetics of lithium sulfur batteries. As a result, a resultant cell with the pyrolytic residue derived modified separator exhibited outstanding cyclic stability and electrochemical performance: the capacity decay per cycle was only 0.057% even after 500 cycles at a current density of 1 C. This work will provide a useful reference to suggest a promising approach for effective utilization of the pyrolytic plastic waste residue. Highlights Porous hybrid carbon was synthesized from pyrolytic plastic waste residues. Boron and nitrogen hetero-atoms were co-doped on hybrid porous carbon surface. The resultant carbon is used as a modified separator in lithium sulfur batteries. The resultant cell shows a low capacity decay of 0.057% over 500 cycles at 1 C. Graphical abstract [DISPLAY OMISSION]

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