[논문]Bioinspired redox-coupled conversion reaction in FeOOH-acetate hybrid nanoplatelets for Na ion battery

Park, Bum Chul; Cho, Jiung; Zhang, Jiliang; Amedzo-Adore, Mawuse; Lee, Dae Beom; Kim, Sung-Chul; Bae, Jong Seong; Uhm, Young Rang; Kim, Sang-Ok; Koo, Jehyoung; Kang, Yong-Mook; Kim, Young Keun

doi:10.1039/d2ta04990b

Bioinspired redox-coupled conversion reaction in FeOOH-acetate hybrid nanoplatelets for Na ion battery

Journal of materials chemistry. A, Materials for energy and sustainability, v.10 no.34, 2022년, pp.17740 - 17751

Park, Bum Chul (Department of Materials Science and Engineering, Korea University, Seoul 02841, Republic of Korea) , Cho, Jiung (Western Seoul Center, Korea Basic Science Institute, Seoul 03759, Republic of Korea) , Zhang, Jiliang (Department of Materials Science and Engineering, Korea University, Seoul 02841, Republic of Korea) , Amedzo-Adore, Mawuse (Department of Energy and Materials Engineering, Dongguk University, Seoul 04620, Republic of Korea) , Lee, Dae Beom (Department of Materials Science and Engineering, Korea University, Seoul 02841, Republic of Korea) , Kim, Sung-Chul (Advanced Analysis Center, Korea Institute of Science and Technology, Seoul 02792, Republic of Korea) , Bae, Jong Seong (Busan Center, Korea Basic Science Institute, Busan 46742, Republic of Korea) , Uhm, Young Rang (Nuclear Materials Research Division, Korea Atomic Energy Research Institute (KAERI), Daejeon 34057, Republic of Korea) , Kim, Sang-Ok (Energy Storage Research Center, Korea Institute of Science and Technology, Seoul 02792, Republic of Korea) , Koo, Jehyoung (Western Seoul Center, Korea Basic Science Institute, Seoul 03759, Republic of Korea) , Kang, Yong-Mook (Department of Mater) , Kim, Young Keun

Abstract ▼ AI-Helper

The considerable interest in rechargeable batteries is causing a rapid increase in demand and a surge in the price of raw materials. Earth-abundant iron oxyhydroxide (FeOOH) is a promising candidate as an anode material for sodium-ion rechargeable batteries (SIBs). However, the application of FeOOH is hindered by numerous technical limitations arising mainly from the irreversibility of the conversion reaction. Here, we manipulate biotic Fe redox from FeOOH-acetate hybrid nanoplatelets (FAHPs) to make the resulting conversion reaction with Na ions highly reversible. The extended lepidocrocite-type FAHP, in which FeOOH and acetate components are stacked in a layer-by-layer assembly, undergoes facile initial intercalation owing to its large interlayer spacing. Consequently, the redox reaction coupled with FeOOH reduction and acetate oxidation occurs in a similar way to the biotic Fe redox reaction. During the subsequent discharge-charge cycles, carbonate produced by the redox coupling of acetate and FeOOH serves as a stable and reversible host for Na ion storage. This study establishes a novel method for enabling highly reversible conversion reactions and enhancing the electrochemical capacity using not only Na ions but Li ions through the exploitation of the interplaying redox of inorganic and organic materials in hybrid structures.

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Bioinspired redox-coupled conversion reaction in FeOOH-acetate hybrid nanoplatelets for Na ion battery

Abstract ▼ AI-Helper

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