[논문]Reliable impedance analysis of Li-ion battery half-cell by standardization on electrochemical impedance spectroscopy (EIS)

Zhang, Baodan; Wang, Lingling; Zhang, Yiming; Wang, Xiaotong; Qiao, Yu; Sun, Shi-Gang

doi:10.1063/5.0139347

Reliable impedance analysis of Li-ion battery half-cell by standardization on electrochemical impedance spectroscopy (EIS)

The Journal of chemical physics, v.158 no.5, 2023년, pp.054202 -

Zhang, Baodan (State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University 1 , Xiamen 361005, People’s Republic of China) , Wang, Lingling (State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University 1 , Xiamen 361005, People’s Republic of China) , Zhang, Yiming (State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University 1 , Xiamen 361005, People’s Republic of China) , Wang, Xiaotong (State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Department of Chemistry, College) , Qiao, Yu , Sun, Shi-Gang

Abstract ▼ AI-Helper

Electrochemical impedance spectroscopy (EIS) is a powerful characterization technique for the in-depth investigation of kinetic/transport parameters detection, reaction mechanism understanding, and degradation effects exploration in lithium-ion battery (LIB) systems. However, due to the lack of standardized criterion/paradigm, severe misinterpretations occur frequently during an EIS measurement. In this paper, the significance of instrumental accuracy is described and the character/principle of selection on the simulation model is illuminated/proposed, showing that an adequate precision device and an appropriate fitting model are a prerequisite for a correct EIS analysis. Moreover, the drawbacks of conventional two-electrode EIS experiments for typical coin-type cells are rigorously pointed out by comparison with the ideal three-electrode configuration, where the real impedance information of the cathode would be masked by the sum of both the anode film resistance response and the unavoidable inductive loop signal. The three-electrode case enables efficient accurate observations on individual electrodes, thus facilitating abundant and useful information acquisition. Consequently, devices with a sufficient accuracy, rational simulation models, and advanced three-electrode cells are distinctly illustrated as standardized criterion/paradigm for EIS characterizations, which are essentially important for electrode and interface modifications in LIBs.

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Reliable impedance analysis of Li-ion battery half-cell by standardization on electrochemical impedance spectroscopy (EIS)

Abstract ▼ AI-Helper

참고문헌 (51)

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