$\require{mediawiki-texvc}$

연합인증

연합인증 가입 기관의 연구자들은 소속기관의 인증정보(ID와 암호)를 이용해 다른 대학, 연구기관, 서비스 공급자의 다양한 온라인 자원과 연구 데이터를 이용할 수 있습니다.

이는 여행자가 자국에서 발행 받은 여권으로 세계 각국을 자유롭게 여행할 수 있는 것과 같습니다.

연합인증으로 이용이 가능한 서비스는 NTIS, DataON, Edison, Kafe, Webinar 등이 있습니다.

한번의 인증절차만으로 연합인증 가입 서비스에 추가 로그인 없이 이용이 가능합니다.

다만, 연합인증을 위해서는 최초 1회만 인증 절차가 필요합니다. (회원이 아닐 경우 회원 가입이 필요합니다.)

연합인증 절차는 다음과 같습니다.

최초이용시에는
ScienceON에 로그인 → 연합인증 서비스 접속 → 로그인 (본인 확인 또는 회원가입) → 서비스 이용

그 이후에는
ScienceON 로그인 → 연합인증 서비스 접속 → 서비스 이용

연합인증을 활용하시면 KISTI가 제공하는 다양한 서비스를 편리하게 이용하실 수 있습니다.

Study of Solutions of Poly(dimethylsiloxane) in Benzene by NMR 원문보기

Polymer journal, v.6 no.6, 1974년, pp.480 - 488  

Muramoto, Akihiro (Material Research Laboratory, Toshiba Research and Development Center)

Abstract AI-Helper 아이콘AI-Helper

Solutions of poly(dimethylsiloxane) in benzene have been studied by the analysis of NMR spectra. It was found that they are characterized by the narrow-broad lines previously obtained for pure liquid poly(dimethylsiloxane). The width and the second moment of the absorption bands for the methyl group...

주제어

참고문헌 (40)

  1. Rochow, Eugene G., LeClair, Hugh G.. On the molecular structure of methyl silicone. Journal of inorganic and nuclear chemistry, vol.1, no.1, 92-111.

  2. Kusumoto, Hazime, Lawrenson, Ian J., Gutowsky, H. S.. Proton Magnetic Resonance Studies of Some Silicones. The Journal of chemical physics, vol.32, no.3, 724-728.

  3. Roth, Walter L.. THE POSSIBILITY OF FREE ROTATION IN THE SILICONES. Journal of the American Chemical Society, vol.69, no.2, 474-475.

  4. Ullman, Robert. Nuclear Magnetic Relaxation of Polymer Solutions. The Journal of chemical physics, vol.43, no.9, 3161-3177.

  5. Ullman, Robert. Nuclear Magnetic Relaxation of Polymer Solutions. Side-Chain Motion. The Journal of chemical physics, vol.44, no.4, 1558-1566.

  6. Powles, J. G., Hartland, A., Kail, J. A. E.. Proton magnetic resonance relaxation in a series of dimethylsiloxane polymers. Journal of polymer science, vol.55, no.161, 361-380.

  7. POWLES, J. G., HARTLAND, A.. Proton Magnetic Resonance in a Series of Dimethyl Siloxane Polymers. A Specific Long-Chain Effect?. Nature, vol.186, no.4718, 26-28.

  8. Adv. Polym. Sci. Berry G 261 5 1968 10.1007/BFb0050985 

  9. Lee, C. L., Polmanteer, K. E., King, E. G.. Flow behavior of narrow‐distribution polydimethylsiloxane. Journal of polymer science. Part A-2, Polymer physics, vol.8, no.11, 1909-1916.

  10. Tanner, J. E., Liu, Kang-Jen, Anderson, J. E.. Proton Magnetic Resonance Self-Diffusion Studies of Poly(ethylene oxide) and Polydimethylsiloxane Solutions. Macromolecules, vol.4, no.5, 586-588.

  11. Green, D K, Powles, J G. Nuclear spin-lattice relaxation, including the spin-rotation interaction, in liquid benzene and several benzene derivatives up to the critical temperature. Proceedings of the Physical Society, vol.85, no.1, 87-102.

  12. A nuclear magnetic resonance investigation of three solid benzenes. Proceedings of the Royal Society of London. Series A, Mathematical and physical sciences, vol.218, no.1135, 537-552.

  13. Andrew, E. R.. Molecular Motion in Certain Solid Hydrocarbons. The Journal of chemical physics, vol.18, no.5, 607-618.

  14. Bovey, F. A.. Spin-Lattice Relaxation and Molecular Structure. I. The Major Importance of Intermolecular Contributions. The Journal of chemical physics, vol.32, no.6, 1877-1878.

  15. Odajima, Akira. Nuclear Magnetic Resonance Studies of Water Sorbed on Fibrous Materials. Journal of the Physical Society of Japan, vol.14, no.3, 308-312.

  16. Rouse Jr., Prince E.. A Theory of the Linear Viscoelastic Properties of Dilute Solutions of Coiling Polymers. The Journal of chemical physics, vol.21, no.7, 1272-1280.

  17. Zh. Fiz. Khim. Kargin V. A 563 23 1949 

  18. Vysokomol. Soedin. Khazanovich T. N 112 5 1963 

  19. Chûjô, Riichirô, Aoki, Kiyosi, Satoh, Shiroh, Nagai, Eiichi. Local viscosity of polymer melts by pulsed NMR I. Polyethylene glycol. Journal of polymer science. Part B, Polymer letters, vol.1, no.9, 501-504.

  20. Liu, Kang-Jen, Ullman, Robert. Nuclear Magnetic Relaxation of Polydimethylsiloxanes in Solution. Macromolecules, vol.2, no.5, 525-528.

  21. Woessner, D. E.. Spin Relaxation Processes in a Two-Proton System Undergoing Anisotropic Reorientation. The Journal of chemical physics, vol.36, no.1, 1-4.

  22. Cuniberti, Carla. Proton magnetic relaxation times and molecular motions in polydimethylsiloxane. Journal of polymer science. Part A-2, Polymer physics, vol.8, no.12, 2051-2065.

  23. Resing, H. A.. Apparent Phase-Transition Effect in the NMR Spin-Spin Relaxation Time Caused by a Distribution of Correlation Times. The Journal of chemical physics, vol.43, no.2, 669-678.

  24. Anderson, J. E., Liu, Kang-Jen. Nuclear Relaxation in the Benzene-PMMA System. The Journal of chemical physics, vol.49, no.6, 2850-2856.

  25. Barry, Arthur J.. Viscometric Investigation of Dimethylsiloxane Polymers. Journal of applied physics, vol.17, no.12, 1020-1024.

  26. Anderson, J. E., Liu, Kang-Jen, Ullman, Robert. Nuclear magnetic relaxation in polymer solutions. Discussions of the Faraday Society, vol.49, 257-267.

  27. Flory, P. J., Semlyen, J. A.. Macrocyclization Equilibrium Constants and the Statistical Configuration of Poly(dimethylsiloxane) Chains. Journal of the American Chemical Society, vol.88, no.14, 3209-3212.

  28. Aggarwal, Eleanor H. (Weller), Bauer, S. H.. The Structure of Hexamethylcyclotrisiloxane as Determined by the Diffraction of Electrons on the Vapor. The Journal of chemical physics, vol.18, no.1, 42-50.

  29. Flory, P. J., Crescenzi, V., Mark, J. E.. Configuration of the Poly-(dimethylsiloxane) Chain. III. Correlation of Theory and Experiment. Journal of the American Chemical Society, vol.86, no.2, 146-152.

  30. Powles, J G, Hartland, A. Molecular Motion in Liquid n-Octyl Bromide by Proton Magnetic Resonance. Proceedings of the Physical Society, vol.75, no.4, 617-620.

  31. Liu, Kang-Jen. Nuclear Magnetic Resonance Studies of Polymer Solutions. IV. Polyethylene Glycols. Macromolecules, vol.1, no.3, 213-217.

  32. Liu, Kang‐Jen. Nuclear magnetic resonance studies of polymer solutions. I. Poly(methyl methacrylates). Journal of polymer science. Part A-2, Polymer physics, vol.5, no.6, 1199-1207.

  33. Liu, Kang‐Jen. NMR studies of polymer solutions. II. Polyethylene. Journal of polymer science. Part A-2, Polymer physics, vol.5, no.6, 1209-1219.

  34. Newing, M. J.. Thermodynamic studies of silicones in benzene solution. Transactions of the Faraday Society, vol.46, 613-620.

  35. Muramoto, Akihiko. Studies on the Interaction Parameter in Polysiloxane Solutions. Polymer journal, vol.1, no.4, 450-456.

  36. Debye, P., Chu, B., Woermann, D.. Critical Opalescence of Polystyrene in Cyclohexane : Range of Molecular Forces and Radius of Gyration. The Journal of chemical physics, vol.36, no.7, 1803-1808.

  37. Anderson, J. E., Liu, Kang-Jen, Ullman, Robert. Nuclear magnetic relaxation in polymer solutions. Discussions of the Faraday Society, vol.49, 257-267.

  38. Bloembergen, N., Purcell, E. M., Pound, R. V.. Relaxation Effects in Nuclear Magnetic Resonance Absorption. Physical review, vol.73, no.7, 679-712.

관련 콘텐츠

오픈액세스(OA) 유형

BRONZE

출판사/학술단체 등이 한시적으로 특별한 프로모션 또는 일정기간 경과 후 접근을 허용하여, 출판사/학술단체 등의 사이트에서 이용 가능한 논문

저작권 관리 안내
섹션별 컨텐츠 바로가기

AI-Helper ※ AI-Helper는 오픈소스 모델을 사용합니다.

AI-Helper 아이콘
AI-Helper
안녕하세요, AI-Helper입니다. 좌측 "선택된 텍스트"에서 텍스트를 선택하여 요약, 번역, 용어설명을 실행하세요.
※ AI-Helper는 부적절한 답변을 할 수 있습니다.

선택된 텍스트

맨위로