$\require{mediawiki-texvc}$

연합인증

연합인증 가입 기관의 연구자들은 소속기관의 인증정보(ID와 암호)를 이용해 다른 대학, 연구기관, 서비스 공급자의 다양한 온라인 자원과 연구 데이터를 이용할 수 있습니다.

이는 여행자가 자국에서 발행 받은 여권으로 세계 각국을 자유롭게 여행할 수 있는 것과 같습니다.

연합인증으로 이용이 가능한 서비스는 NTIS, DataON, Edison, Kafe, Webinar 등이 있습니다.

한번의 인증절차만으로 연합인증 가입 서비스에 추가 로그인 없이 이용이 가능합니다.

다만, 연합인증을 위해서는 최초 1회만 인증 절차가 필요합니다. (회원이 아닐 경우 회원 가입이 필요합니다.)

연합인증 절차는 다음과 같습니다.

최초이용시에는
ScienceON에 로그인 → 연합인증 서비스 접속 → 로그인 (본인 확인 또는 회원가입) → 서비스 이용

그 이후에는
ScienceON 로그인 → 연합인증 서비스 접속 → 서비스 이용

연합인증을 활용하시면 KISTI가 제공하는 다양한 서비스를 편리하게 이용하실 수 있습니다.

Shedding Light on the Oxygen Reduction Reaction Mechanism in Ether-Based Electrolyte Solutions: A Study Using Operando UV-Vis Spectroscopy

ACS applied materials & interfaces, v.10 no.13, 2018년, pp.10860 - 10869  

Hirshberg, Daniel (Department of Chemistry and BINA (BIU Institute of Nanotechnology and Advanced Materials) , Bar Ilan University , Ramat-Gan 5290002 , Israel) ,  Sharon, Daniel (Department of Chemistry and BINA (BIU Institute of Nanotechnology and Advanced Materials) , Bar Ilan University , Ramat-Gan 5290002 , Israel) ,  Afri, Michal (Department of Chemistry and BINA (BIU Institute of Nanotechnology and Advanced Materials) , Bar Ilan University , Ramat-Gan 5290002 , Israel) ,  Lavi, Ronit (Department of Chemistry and BINA (BIU Institute of Nanotechnology and Advanced Materials) , Bar Ilan University , Ramat-Gan 5290002 , Israel) ,  Frimer, Aryeh A. (Department of Chemistry and BINA (BIU Institute of Nanotechnology and Advanced Materials) , Bar Ilan University , Ramat-Gan 5290002 , Israel) ,  Metoki, Noa (Department of Materials Science and Engineering , Tel Aviv University , Tel Aviv 6997801 , Israel) ,  Eliaz, Noam (Department of Materials) ,  Kwak, Won-jin ,  Sun, Yang-Kook ,  Aurbach, Doron

Abstract AI-Helper 아이콘AI-Helper

Using UV-vis spectroscopy in conjunction with various electrochemical techniques, we have developed a new effective operando methodology for investigating the oxygen reduction reactions (ORRs) and their mechanisms in nonaqueous solutions. We can follow the in situ formation and presence of superoxid...

주제어

참고문헌 (42)

  1. Abraham, K. M., Jiang, Z.. A Polymer Electrolyte‐Based Rechargeable Lithium/Oxygen Battery. Journal of the Electrochemical Society : JES, vol.143, no.1, 1-5.

  2. Viswanathan, V., Nørskov, J. K., Speidel, A., Scheffler, R., Gowda, S., Luntz, A. C.. Li–O2 Kinetic Overpotentials: Tafel Plots from Experiment and First-Principles Theory. The journal of physical chemistry letters, vol.4, no.4, 556-560.

  3. Wang, Zhong-Li, Xu, Dan, Xu, Ji-Jing, Zhang, Xin-Bo. Oxygen electrocatalysts in metal–air batteries: from aqueous to nonaqueous electrolytes. Chemical Society reviews, vol.43, no.22, 7746-7786.

  4. Freunberger, Stefan A., Chen, Yuhui, Peng, Zhangquan, Griffin, John M., Hardwick, Laurence J., Bardé, Fanny, Novák, Petr, Bruce, Peter G.. Reactions in the Rechargeable Lithium–O2 Battery with Alkyl Carbonate Electrolytes. Journal of the American Chemical Society, vol.133, no.20, 8040-8047.

  5. Xu, W., Xu, K., Viswanathan, V.V., Towne, S.A., Hardy, J.S., Xiao, J., Nie, Z., Hu, D., Wang, D., Zhang, J.G.. Reaction mechanisms for the limited reversibility of Li-O2 chemistry in organic carbonate electrolytes. Journal of power sources, vol.196, no.22, 9631-9639.

  6. Lu, Yi-Chun, Gasteiger, Hubert A., Shao-Horn, Yang. Catalytic Activity Trends of Oxygen Reduction Reaction for Nonaqueous Li-Air Batteries. Journal of the American Chemical Society, vol.133, no.47, 19048-19051.

  7. Hassoun, Jusef, Croce, Fausto, Armand, Michel, Scrosati, Bruno. Investigation of the O2 Electrochemistry in a Polymer Electrolyte Solid‐State Cell. Angewandte Chemie. international edition, vol.50, no.13, 2999-3002.

  8. Black, Robert, Oh, Si Hyoung, Lee, Jin-Hyon, Yim, Taeeun, Adams, Brian, Nazar, Linda F.. Screening for SuperoxideReactivity in Li-O2 Batteries: Effect on Li2O2/LiOH Crystallization. Journal of the American Chemical Society, vol.134, no.6, 2902-2905.

  9. Zheng, Dong, Wang, Qiang, Lee, Hung‐Sui, Yang, Xiao‐Qing, Qu, Deyang. Catalytic Disproportionation of the Superoxide Intermediate from Electrochemical O2 Reduction in Nonaqueous Electrolytes. Chemistry : a European journal, vol.19, no.26, 8679-8683.

  10. Lu, Jun, Jung Lee, Yun, Luo, Xiangyi, Chun Lau, Kah, Asadi, Mohammad, Wang, Hsien-Hau, Brombosz, Scott, Wen, Jianguo, Zhai, Dengyun, Chen, Zonghai, Miller, Dean J., Sub Jeong, Yo, Park, Jin-Bum, Zak Fang, Zhigang, Kumar, Bijandra, Salehi-Khojin, Amin, Sun, Yang-Kook, Curtiss, Larry A., Amine, Khalil. A lithium–oxygen battery based on lithium superoxide. Nature, vol.529, no.7586, 377-382.

  11. Sharon, Daniel, Hirshberg, Daniel, Afri, Michal, Frimer, Aryeh A., Noked, Malachi, Aurbach, Doron. Aprotic metal-oxygen batteries: recent findings and insights. Journal of solid state electrochemistry : current research and development in science and technology, vol.21, no.7, 1861-1878.

  12. Sharon, Daniel, Hirshberg, Daniel, Afri, Michal, Frimer, Aryeh A., Aurbach, Doron. The importance of solvent selection in Li-O2 cells. Chemical communications : Chem comm, vol.53, no.22, 3269-3272.

  13. Li, Zhaolong, Ganapathy, Swapna, Xu, Yaolin, Heringa, Jouke R., Zhu, Quanyao, Chen, Wen, Wagemaker, Marnix. Understanding the Electrochemical Formation and Decomposition of Li 2 O 2 and LiOH with Operando X-ray Diffraction. Chemistry of materials : a publication of the American Chemical Society, vol.29, no.4, 1577-1586.

  14. Suzen, Sibel, Gurer-Orhan, Hande, Saso, Luciano. Detection of Reactive Oxygen and Nitrogen Species by Electron Paramagnetic Resonance (EPR) Technique. Molecules a journal of synthetic chemistry and natural product chemistry, vol.22, no.1, 181-.

  15. Sharon, Daniel, Hirsberg, Daniel, Salama, Michael, Afri, Michal, Frimer, Aryeh A., Noked, Malachi, Kwak, Wonjin, Sun, Yang-Kook, Aurbach, Doron. Mechanistic Role of Li+ Dissociation Level in Aprotic Li–O2 Battery. ACS applied materials & interfaces, vol.8, no.8, 5300-5307.

  16. Tan, P., Shyy, W., Zhao, T.S., Wei, Z.H., An, L.. Discharge product morphology versus operating temperature in non-aqueous lithium-air batteries. Journal of power sources, vol.278, 133-140.

  17. Sharon, Daniel, Hirsberg, Daniel, Afri, Michal, Chesneau, Frederick, Lavi, Ronit, Frimer, Aryeh A., Sun, Yang-Kook, Aurbach, Doron. Catalytic Behavior of Lithium Nitrate in Li-O2 Cells. ACS applied materials & interfaces, vol.7, no.30, 16590-16600.

  18. Erikson, Heiki, Sarapuu, Ave, Tammeveski, Kaido, Solla‐Gullón, Jose, Feliu, Juan M.. Shape‐Dependent Electrocatalysis: Oxygen Reduction on Carbon‐Supported Gold Nanoparticles. ChemElectroChem, vol.1, no.8, 1338-1347.

  19. Galiote, Nelson A., de Azevedo, Dayse C., Oliveira, Osvaldo N., Huguenin, Fritz. Investigating the Kinetic Mechanisms of the Oxygen Reduction Reaction in a Nonaqueous Solvent. The journal of physical chemistry. C, Nanomaterials and Interfaces, vol.118, no.38, 21995-22002.

  20. Xia, Chun, Waletzko, Michael, Chen, Limei, Peppler, Klaus, Klar, Peter. J., Janek, Jürgen. Evolution of Li2O2 Growth and Its Effect on Kinetics of Li–O2 Batteries. ACS applied materials & interfaces, vol.6, no.15, 12083-12092.

  21. Aetukuri, Nagaphani B., McCloskey, Bryan D., García, Jeannette M., Krupp, Leslie E., Viswanathan, Venkatasubramanian, Luntz, Alan C.. Solvating additives drive solution-mediated electrochemistry and enhance toroid growth in non-aqueous Li–O2 batteries. Nature chemistry, vol.7, no.1, 50-56.

  22. Johnson, Lee, Li, Chunmei, Liu, Zheng, Chen, Yuhui, Freunberger, Stefan A., Ashok, Praveen C., Praveen, Bavishna B., Dholakia, Kishan, Tarascon, Jean-Marie, Bruce, Peter G.. The role of LiO2 solubility in O2 reduction in aprotic solvents and its consequences for Li–O2 batteries. Nature chemistry, vol.6, no.12, 1091-1099.

  23. Torres, Walter, Mozhzhukhina, Nataliia, Tesio, Alvaro Y., Calvo, Ernesto J.. A Rotating Ring Disk Electrode Study of the Oxygen Reduction Reaction in Lithium Containing Dimethyl Sulfoxide Electrolyte: Role of Superoxide. Journal of the Electrochemical Society : JES, vol.161, no.14, A2204-A2209.

  24. Sharon, Daniel, Hirsberg, Daniel, Afri, Michal, Garsuch, Arnd, Frimer, Aryeh A., Aurbach, Doron. Reactivity of Amide Based Solutions in Lithium–Oxygen Cells. The journal of physical chemistry. C, Nanomaterials and Interfaces, vol.118, no.28, 15207-15213.

  25. Schwenke, K. Uta, Meini, Stefano, Wu, Xiaohan, Gasteiger, Hubert A., Piana, Michele. Stability of superoxide radicals in glyme solvents for non-aqueous Li–O2 battery electrolytes. Physical chemistry chemical physics : PCCP, vol.15, no.28, 11830-11839.

  26. Ganapathy, Swapna, Li, Zhaolong, Anastasaki, Maria S., Basak, Shibabrata, Miao, Xue-Fei, Goubitz, Kees, Zandbergen, Henny W., Mulder, Fokko M., Wagemaker, Marnix. Use of Nano Seed Crystals To Control Peroxide Morphology in a Nonaqueous Li–O2 Battery. The journal of physical chemistry. C, Nanomaterials and Interfaces, vol.120, no.33, 18421-18427.

  27. Kwabi, David G., Bryantsev, Vyacheslav S., Batcho, Thomas P., Itkis, Daniil M., Thompson, Carl V., Shao‐Horn, Yang. Experimental and Computational Analysis of the Solvent‐Dependent O2/Li+‐O2 Redox Couple: Standard Potentials, Coupling Strength, and Implications for Lithium–Oxygen Batteries. Angewandte Chemie. international edition, vol.55, no.9, 3129-3134.

  28. Wang, Qiang, Zheng, Dong, McKinnon, Meaghan E., Yang, Xiao-Qing, Qu, Deyang. Kinetic investigation of catalytic disproportionation of superoxide ions in the non-aqueous electrolyte used in Li–air batteries. Journal of power sources, vol.274, 1005-1008.

  29. Ortiz-Vitoriano, Nagore, Batcho, Thomas P., Kwabi, David G., Han, Binghong, Pour, Nir, Yao, Koffi Pierre Claver, Thompson, Carl V., Shao-Horn, Yang. Rate-Dependent Nucleation and Growth of NaO2 in Na–O2 Batteries. The journal of physical chemistry letters, vol.6, no.13, 2636-2643.

  30. Johnson, Lee, Li, Chunmei, Liu, Zheng, Chen, Yuhui, Freunberger, Stefan A., Ashok, Praveen C., Praveen, Bavishna B., Dholakia, Kishan, Tarascon, Jean-Marie, Bruce, Peter G.. The role of LiO2 solubility in O2 reduction in aprotic solvents and its consequences for Li–O2 batteries. Nature chemistry, vol.6, no.12, 1091-1099.

  31. Meini, Stefano, Solchenbach, Sophie, Piana, Michele, Gasteiger, Hubert A.. The Role of Electrolyte Solvent Stability and Electrolyte Impurities in the Electrooxidation of Li2O2in Li-O2Batteries. Journal of the Electrochemical Society : JES, vol.161, no.9, A1306-A1314.

  32. Balaish, Moran, Kraytsberg, Alexander, Ein-Eli, Yair. A critical review on lithium–air battery electrolytes. Physical chemistry chemical physics : PCCP, vol.16, no.7, 2801-2822.

  33. Zheng, Dong, Wang, Qiang, Lee, Hung‐Sui, Yang, Xiao‐Qing, Qu, Deyang. Catalytic Disproportionation of the Superoxide Intermediate from Electrochemical O2 Reduction in Nonaqueous Electrolytes. Chemistry : a European journal, vol.19, no.26, 8679-8683.

  34. Viswanathan, V., Nørskov, J. K., Speidel, A., Scheffler, R., Gowda, S., Luntz, A. C.. Li–O2 Kinetic Overpotentials: Tafel Plots from Experiment and First-Principles Theory. The journal of physical chemistry letters, vol.4, no.4, 556-560.

  35. Wang, Zhong-Li, Xu, Dan, Xu, Ji-Jing, Zhang, Xin-Bo. Oxygen electrocatalysts in metal–air batteries: from aqueous to nonaqueous electrolytes. Chemical Society reviews, vol.43, no.22, 7746-7786.

  36. Sharon, Daniel, Afri, Michal, Noked, Malachi, Garsuch, Arnd, Frimer, Aryeh A., Aurbach, Doron. Oxidation of Dimethyl Sulfoxide Solutions by Electrochemical Reduction of Oxygen. The journal of physical chemistry letters, vol.4, no.18, 3115-3119.

  37. Sharon, Daniel, Etacheri, Vinodkumar, Garsuch, Arnd, Afri, Michal, Frimer, Aryeh A., Aurbach, Doron. On the Challenge of Electrolyte Solutions for Li–Air Batteries: Monitoring Oxygen Reduction and Related Reactions in Polyether Solutions by Spectroscopy and EQCM. The journal of physical chemistry letters, vol.4, no.1, 127-131.

  38. Schwenke, K. Uta, Herranz, Juan, Gasteiger, Hubert A., Piana, Michele. Reactivity of the Ionic Liquid Pyr14TFSI with Superoxide Radicals Generated from KO2 or by Contact of O2 with Li7Ti5O12. Journal of the Electrochemical Society : JES, vol.162, no.6, A905-A914.

  39. Schwenke, K. Uta, Meini, Stefano, Wu, Xiaohan, Gasteiger, Hubert A., Piana, Michele. Stability of superoxide radicals in glyme solvents for non-aqueous Li–O2 battery electrolytes. Physical chemistry chemical physics : PCCP, vol.15, no.28, 11830-11839.

  40. Gokel, George W., Cram, Donald J., Liotta, Charles L., Harris, Henry P., Cook, Fred L.. Preparation and purification of 18-crown-6[1,4,7,10,13,16-hexaoxacyclooctadecane]. Journal of organic chemistry, vol.39, no.16, 2445-2446.

  41. Sharon, Daniel, Hirshberg, Daniel, Afri, Michal, Frimer, Aryeh A., Noked, Malachi, Aurbach, Doron. Aprotic metal-oxygen batteries: recent findings and insights. Journal of solid state electrochemistry : current research and development in science and technology, vol.21, no.7, 1861-1878.

  42. Liu, Rui-heng, Fu, Shi-yu, Zhan, Huai-yu, Lucia, Lucian A.. General Spectroscopic Protocol to Obtain the Concentration of the Superoxide Anion Radical. Industrial & engineering chemistry research, vol.48, no.20, 9331-9334.

LOADING...

관련 콘텐츠

이 논문과 함께 이용한 콘텐츠

저작권 관리 안내
섹션별 컨텐츠 바로가기

AI-Helper ※ AI-Helper는 오픈소스 모델을 사용합니다.

AI-Helper 아이콘
AI-Helper
안녕하세요, AI-Helper입니다. 좌측 "선택된 텍스트"에서 텍스트를 선택하여 요약, 번역, 용어설명을 실행하세요.
※ AI-Helper는 부적절한 답변을 할 수 있습니다.

선택된 텍스트

맨위로