[논문]Bicontinuously crosslinked polymer electrolyte membranes with high ion conductivity and mechanical strength

Lim, Jung Yup; Kang, Dong A.; Kim, Na Un; Lee, Jung Min; Kim, Jong Hak

doi:10.1016/j.memsci.2019.117250

[해외논문] Bicontinuously crosslinked polymer electrolyte membranes with high ion conductivity and mechanical strength

Journal of membrane science, v.589, 2019년, pp.117250 -

Lim, Jung Yup (Department of Chemical and Biomolecular Engineering, Yonsei University) , Kang, Dong A. (Department of Chemical and Biomolecular Engineering, Yonsei University) , Kim, Na Un (Department of Chemical and Biomolecular Engineering, Yonsei University) , Lee, Jung Min (The 4th R&D Institute, Agency for Defense Development) , Kim, Jong Hak (Department of Chemical and Biomolecular Engineering, Yonsei University)

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Abstract Recently, safety has become an important issue for energy storage devices due to explosion and leakage of conventional liquid electrolytes. Traditional polymer electrolytes also have a strong dependence on the tradeoff relationship and do not exhibit sufficient ionic conductivity as a solid; thus, they are often used as a gel. We report the preparation of a highly ion-conductive, mechanically strong solid electrolyte membranes based on bicontinuously crosslinked polymer electrolytes for solid-state supercapacitors. The solid electrolyte membranes are synthesized in situ via facile ring-opening polymerization in the presence of a conductive ionic liquid without any solvents. The crosslinking structure is based on the reaction of the amines of the polyethylenimine oligomer with the epoxy groups of hydrophilic poly(ethylene glycol) diglycidyl ether and hydrophobic bisphenol A diglycidyl ether at 50 °C for 3 h. This unique structure endows the solid electrolyte membranes with high tensile strength as well as high ion conductivity (2.41 × 10−3 S cm−1 at 25 °C). All the membranes have good thermal stability and an amorphous phase in which the ionic species are uniformly distributed in the matrix. Upon application to solid-state supercapacitors based on carbon electrodes, a capacitance of 19.8 F g−1 at 2 mV s−1 is obtained, with an excellent capacitance retention and a coulombic efficiency close to 100% for 10,000 cycles. The solid electrolyte membrane has potential applications in structural supercapacitors and batteries, which require high mechanical strength. Highlights Bicontinuously crosslinked polymer electrolyte (BCPE) membranes were prepared. Reaction is based on facile ring-opening polymerization in ionic liquid. Solid electrolyte membranes with high tensile strength and ion conductivity were obtained. All the membranes have good thermal stability and amorphous phase. The solid BCPE has potential applications in structural supercapacitors and batteries. Graphical abstract [DISPLAY OMISSION]

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참고문헌 (46)

Adv. Mater. Manthiram 27 1980 2015 10.1002/adma.201405115 Lithium-Sulfur batteries: progress and prospects

상세보기
Energy Environ. Sci. Zhou 7 1307 2014 10.1039/C3EE43182G Progress in flexible lithium batteries and future prospects

상세보기
Carbon Yang 127 557 2018 10.1016/j.carbon.2017.11.050 Phosphorus-doped 3D hierarchical porous carbon for high-performance supercapacitors: a balanced strategy for pore structure and chemical composition

상세보기
Chem. Eng. J. Mohammadi 334 66 2018 10.1016/j.cej.2017.10.029 Engineering rGO-CNT wrapped Co3S4 nanocomposites for high-performance asymmetric supercapacitors

상세보기
J. Membr. Sci. Kim 563 835 2018 10.1016/j.memsci.2018.06.023 Synthesis of a polyacrylonitrile/tetrachloro-1,4-benzoquinone gel polymer electrolyte for high-performance Li-air batteries

상세보기
ACS Appl. Mater. Interfaces Kwon 9 24250 2017 10.1021/acsami.7b07159 Highly conductive solid-state hybrid electrolytes operating at subzero temperatures

상세보기
Adv. Mater. Liu 29 1605531 2017 10.1002/adma.201605531 An artificial solid electrolyte interphase with high Li-ion conductivity, mechanical strength, and flexibility for stable lithium metal anodes

상세보기
Nat. Commun. Peng 7 11782 2016 10.1038/ncomms11782 A zwitterionic gel electrolyte for efficient solid-state supercapacitors

상세보기
Nano Energy. Chen 46 176 2018 10.1016/j.nanoen.2017.12.037 PEO/garnet composite electrolytes for solid-state lithium batteries: from “ceramic-in-polymer” to “polymer-in-ceramic

상세보기
Electrochim. Acta Cheng 253 430 2017 10.1016/j.electacta.2017.08.162 Electrochemical performance of all-solid-state lithium batteries using inorganic lithium garnets particulate reinforced PEO/LiClO4 electrolyte

상세보기
Nano Energy Zhang 28 447 2016 10.1016/j.nanoen.2016.09.002 And ion-conducting membrane electrolytes for solid-state lithium batteries: dispersion of garnet nanoparticles in insulating polyethylene oxide

상세보기
Polym. J. Jo 48 465 2016 10.1038/pj.2015.141 End-functionalized block copolymer electrolytes: effect of segregation strength on ion transport efficiency

상세보기
ACS Macro Lett. Inceoglu 3 510 2014 10.1021/mz5001948 Morphology-conductivity relationship of single-ion-conducting block copolymer electrolytes for lithium batteries

상세보기
J. Power Sources Saikia 390 1 2018 10.1016/j.jpowsour.2018.04.028 Highly conducting blend hybrid electrolytes based on amine ended block copolymers and organosilane with in-situ formed silica particles for lithium-ion batteries

상세보기
Mater. Des. Lee 149 25 2018 10.1016/j.matdes.2018.03.060 Polymethacrylate-comb-copolymer electrolyte for solid-state energy storage devices

상세보기
J. Mater. Chem. A. Lim 4 7848 2016 10.1039/C6TA00888G An amphiphilic block-graft copolymer electrolyte: synthesis, nanostructure, and use in solid-state supercapacitors

상세보기
J. Power Sources Hu 196 5604 2011 10.1016/j.jpowsour.2011.03.001 Graft copolymer-based lithium-ion battery for high-temperature operation

상세보기
J. Mater. Chem. A. Rolland 2 11839 2014 10.1039/C4TA02327G Chemically anchored liquid-PEO based block copolymer electrolytes for solid-state lithium-ion batteries

상세보기
Macromol. Res. Johnsi 26 100 2018 10.1007/s13233-018-6019-y Effect of alumina nanofiller and diphenyl phthalate plasticizer on a silver ion conducting polyethylene oxide based nanocomposite solid polymer electrolyte

상세보기
J. Mater. Chem. A. Xue 3 19218 2015 10.1039/C5TA03471J Poly(ethylene oxide)-based electrolytes for lithium-ion batteries

상세보기
J. Membr. Sci. Kim 566 122 2018 10.1016/j.memsci.2018.08.066 Design of a porous gel polymer electrolyte for sodium ion batteries

상세보기
Chem. Eng. J. Lee 334 939 2018 10.1016/j.cej.2017.10.109 Dual-phase all-polymeric membranes with graft copolymer filler for CO2 capture

상세보기
Chem. Eng. J. Kim 346 739 2018 10.1016/j.cej.2018.04.036 Synthesis of PVA-g-POEM graft copolymers and their use in highly permeable thin membrane composite membranes

상세보기
J. Power Sources Ma 317 103 2016 10.1016/j.jpowsour.2016.03.097 Cross-linked branching nanohybrid polymer electrolyte with monodispersed TiO2 nanoparticles for high performance lithium-ion batteries

상세보기
J. Am. Chem. Soc. Khurana 136 7395 2014 10.1021/ja502133j Suppression of lithium dendrite growth using cross-linked polyethylene/poly(ethylene oxide) electrolytes: a new approach for practical lithium-metal polymer batteries

상세보기
Nano Lett. Lin 16 459 2016 10.1021/acs.nanolett.5b04117 High ionic conductivity of composite solid polymer electrolyte via in situ synthesis of monodispersed SiO2 nanospheres in poly(ethylene oxide)

상세보기
Korean J. Chem. Eng. Ghosh 35 1389 2018 10.1007/s11814-018-0089-6 A review on metal nitrides/oxynitrides as an emerging supercapacitor electrode beyond oxide

상세보기
Electrochim. Acta Zhong 244 112 2017 10.1016/j.electacta.2017.05.110 Cross-linking of polymer and ionic liquid as high-performance gel electrolyte for solid-state supercapacitors

상세보기
Korean J. Chem. Eng. Lim 35 579 2018 10.1007/s11814-017-0302-z Simple modification with amine- and hydroxyl- group rich biopolymer on ordered mesoporous carbon/sulfur composite for lithium-sulfur batteries

상세보기
Nano Lett. Schulze 14 122 2014 10.1021/nl4034818 High-modulus, high-conductivity nanostructured polymer electrolyte membranes via polymerization-induced phase separation

상세보기
Macromol. Res. Choi 26 459 2018 10.1007/s13233-018-6061-9 Ion conduction, dielectric and mechanical properties of epoxy-based solid polymer electrolytes containing succinonitrile

상세보기
Electrochim. Acta Kido 175 5 2015 10.1016/j.electacta.2015.01.067 Li+ ion transport in polymer electrolytes based on a glyme-Li salt solvate ionic liquid

상세보기
J. Membr. Sci. Chi 443 54 2013 10.1016/j.memsci.2013.04.049 Synthesis, structure and gas permeation of polymerized ionic liquid graft copolymer membranes

상세보기
J. Mater. Chem. A. Na 5 19703 2017 10.1039/C7TA05358D Solvent-free synthesis of an ionic liquid integrated ether-abundant polymer as a solid electrolyte for electric double-layer capacitors

상세보기
Adv. Funct. Mater. Yang 20 2550 2010 10.1002/adfm.201000034 Harnessing surface wrinkle patterns in soft matter

상세보기
Entropy Mitra 19 140 2017 10.3390/e19040140 Ionic liquids confined in silica ionogels: structural, thermal, and dynamical behaviors

상세보기
Chem. Commun. Reichert 0 4767 2006 10.1039/B608496F Approaches to crystallization from ionic liquids: complex solvents-complex results, or, a strategy for controlled formation of new supramolecular architectures?

상세보기
ACS Appl. Mater. Interfaces Wang 5 8477 2013 10.1021/am4019115 Poly(ethylene oxide)-co-Poly(propylene oxide)-based gel electrolyte with high ionic conductivity and mechanical integrity for lithium-ion batteries

상세보기
Colloid Polym. Sci. Yuan 293 1945 2015 10.1007/s00396-015-3590-z Preparation and characterization of a novel ionic conducting foam-type polymeric gel based on polymer PVdF-HFP and ionic liquid [EMIM][TFSI]

상세보기
J. Chem. Phys. Costa 143 2015 10.1063/1.4926470 Polymer-ionic liquid ternary systems for Li-battery electrolytes: molecular dynamics studies of LiTFSI in a EMIm-TFSI and PEO blend

상세보기
Macromolecules Jansen 44 39 2011 10.1021/ma102438k High ionic liquid content polymeric gel membranes: preparation and performance

상세보기
Nanotechnology Moussa 27 442001 2016 10.1088/0957-4484/27/44/442001 Recent progress and performance evaluation for polyaniline/graphene nanocomposites as supercapacitor electrodes

상세보기
J. Power Sources Brandt 204 213 2012 10.1016/j.jpowsour.2011.12.025 Adiponitrile-based electrochemical double layer capacitor

상세보기
Electrochim. Acta Lai 56 6426 2011 10.1016/j.electacta.2011.04.136 Tetraethylammonium difluoro(oxalato)borate as electrolyte salt for electrochemical double-layer capacitors

상세보기
J. Electrochem. Soc. Hudak 164 A691 2017 10.1149/2.0721704jes Structural supercapacitors with enhanced performance using carbon nanotubes and polyaniline

상세보기
ECS Transactions Wang 72 31 2016 10.1149/07208.0031ecst Development of all-solid-state structural supercapacitor using an epoxy based adhesive polymer electrolyte

상세보기

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[해외논문] Bicontinuously crosslinked polymer electrolyte membranes with high ion conductivity and mechanical strength

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[해외논문] Bicontinuously crosslinked polymer electrolyte membranes with high ion conductivity and mechanical strength

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