[논문]Metal organic framework UiO-66 and activated carbon composite sorbent for the concurrent adsorption of cationic and anionic metals

Solis, Kurt Louis B.; Kwon, Young-Hwan; Kim, Moon-Hyeon; An, Ha-Rim; Jeon, Cheolho; Hong, Yongseok

doi:10.1016/j.chemosphere.2019.124656

[해외논문] Metal organic framework UiO-66 and activated carbon composite sorbent for the concurrent adsorption of cationic and anionic metals

Chemosphere, v.238, 2020년, pp.124656 -

Solis, Kurt Louis B. (Department of Environmental Engineering, Korea University) , Kwon, Young-Hwan (Department of Chemical Engineering, Daegu University) , Kim, Moon-Hyeon (Department of Environmental Engineering, Daegu University) , An, Ha-Rim (Advanced Nano-Surface Group, Korea Basic Science Institute) , Jeon, Cheolho (Advanced Nano-Surface Group, Korea Basic Science Institute) , Hong, Yongseok (Department of Environmental Engineering, Korea University)

Abstract ▼ AI-Helper

Abstract A composite sorbent for the simultaneous removal of both Hg2+ and SeO3 2− from aqueous media was produced from the solvothermal synthesis of a zirconium metal organic framework, UiO-66, in the presence of activated carbon. The composite sorbent has a large surface area of 1051 m2 g−1 with crystalized porous structures and has strong thermal stability up to 600 °C. The contaminant uptake of the sorbent follows a Langmuir adsorption isotherm with maximum sorption capacity of 205 mg g−1 and 168 mg g−1 for Hg2+ and SeO3 2−, respectively. Scanning electron microscopy-energy dispersive spectroscopy results show that the Se regions overlap exclusively with Zr-rich regions suggesting that SeO3 2− adsorption depends entirely on the exposed UiO-66 surface. In addition, X-ray photoelectron spectroscopy spectra of Se 3d and Hg 4f showed the association of SeO3 2− and Hg2+ on the UiO-66 and carbon surfaces, respectively. The sorbent could facilitate the development of a single process for the simultaneous removal of cationic Hg and anionic Se as well as other similar ionic metals with opposite charges from aqueous media. Highlights A UiO-66 and activated carbon composite sorbent is synthesized and characterized. Adsorption experiments indicates that the sorbent removes dissolved Hg2+ and SeO3 2- effectively. Langmuir isotherm best describes the adsorption of Hg2+ and SeO3 2- to the composite sorbent. The adsorption of SeO3 2- is localized to UiO-66 while Hg2+ adsorption is not site specific. Graphical abstract [DISPLAY OMISSION]

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