[논문]Impact of copper(II) on activation product removal from reactor decommissioning effluents in South Korea

Amphlett, J.T.M.; Pepper, S.E.; Riley, A.L.; Harwood, L.M.; Cowell, J.; Whittle, K.R.; Lee, T.S.; Ogden, M.D.

doi:10.1016/j.jiec.2019.10.022

[국내논문] Impact of copper(II) on activation product removal from reactor decommissioning effluents in South Korea

Journal of industrial and engineering chemistry : JIEC, v.82, 2020년, pp.261 - 268

Amphlett, J.T.M. (Separations and Nuclear Chemical Engineering Research (SNUCER), Department of Chemical and Biological Engineering, University of Sheffield) , Pepper, S.E. (Separations and Nuclear Chemical Engineering Research (SNUCER), Department of Chemical and Biological Engineering, University of Sheffield) , Riley, A.L. (Separations and Nuclear Chemical Engineering Research (SNUCER), Department of Chemical and Biological Engineering, University of Sheffield) , Harwood, L.M. (Department of Chemistry, University of Reading) , Cowell, J. (Department of Chemistry, University of Reading) , Whittle, K.R. (School of Engineering, University of Liverpool) , Lee, T.S. (Department of Organic Materials Engineering, Chungnam National University) , Ogden, M.D. (Separations and Nuclear Chemical Engineering Research (SNUCER), Department of Chemical and Biological Engineering, Univ)

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Abstract Decommissioning is one of the most important phases in the life of a nuclear reactor, having a major influence on public perception of such technology. Therefore, development of technologies that make decommissioning more safe, effective and efficient is integral to the success of the nuclear industry. In this paper, phosphonic acid functionalised silica has been studied to determine its suitability for treating nuclear decommissioning effluents produced in the HYBRID process, developed in South Korea. Cu2+ recovery from HCl media in both static and dynamic modes was investigated, as well as the effect of Cu2+ on Co2+ and Ni2+ recovery in a column loading system. Isothermal loading studies predicted a maximum loading capacity for Cu2+ of 22.82mgg−1, however complex loading behaviour was observed. Cu2+ sorption followed pseudo-second order kinetics with rapid uptake. Thermodynamic parameters have been extracted from collected kinetic data. Cu2+ outcompetes both Co2+ and Ni2+ for binding to the silica in column studies, which has implications for the use of phosphonic acid functionalised silica in treating decommissioning effluents. This work presents initial lab scale experiments, but shows the potential of Si based extractants for use in metals recovery in the nuclear industry. Highlights Cu recovery kinetics are very fast, with pseudo-second order rate constants being up to 2 orders of magnitude higher than other, similar extractants. Increasing influent flow rate has no effect on Cu2+ recovery in a column loading system. Cu2+ is extracted preferentially to Co2+ and Ni2+ by EBP-Si. Cu2+ extraction behaviour is complicated, with a change in mechanism being observed for [Cu2+] >0.04M. Graphical abstract [DISPLAY OMISSION]

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참고문헌 (41)

IAEA 2018 Energy, Electricity and Nuclear Power Estimates for the Period up to 2050
Energy Policy Chung 116 January 137 2018 10.1016/j.enpol.2018.02.007

상세보기
Prog. Nucl. Energy Nian 105 December 83 2018 10.1016/j.pnucene.2017.12.009

상세보기
Ann. Nucl. Energy Seo 120 749 2018 10.1016/j.anucene.2018.06.037

상세보기
J. Nucl. Sci. Technol. Kim 00 00 1 2018
Prog. Nucl. Energy Canner 104 October 271 2018 10.1016/j.pnucene.2017.10.007

상세보기
Met. Mater. Int. Jung 21 4 678 2015 10.1007/s12540-015-4572-x

상세보기
Morris 452 2000 Water Chemistry of Nuclear Reactor Systems 8
Choi 2015 Waste Management 2015
Won 2018 Proceedings of the ASME 2013 15th International Conference on Environmental Remediation and Radioactive Waste Management
Asian J. Chem. Won 26 5 1327 2015 10.14233/ajchem.2014.17221

상세보기
Lumetta 2006 Separations for the Nuclear Fuel Cycle in the 21st Century
J. Hazard. Mater. Veliscek-Carolan 318 266 2016 10.1016/j.jhazmat.2016.07.027

상세보기
Chem. Eng. J. Amphlett 342 133 2018 10.1016/j.cej.2018.01.090

상세보기
J. Ind. Eng. Chem. Moon 51 255 2017 10.1016/j.jiec.2017.03.009

상세보기
Eng. Life Sci. Akhtar 4 2 171 2004 10.1002/elsc.200420019

상세보기
Chem. Eng. J. Mahfouz 262 198 2015 10.1016/j.cej.2014.09.061

상세보기
Sep. Sci. Technol. Pepper 53 04 1 2017 Cobalt
J. Radioanal. Nucl. Chem. Hanzel 246 3 607 2000 10.1023/A:1006750620617

상세보기
Superlattices Microstruct. Gholami 61 33 2013 10.1016/j.spmi.2013.06.004

상세보기
Talanta Xie 74 836 2008 10.1016/j.talanta.2007.07.018

상세보기
Chem. Eng. J. Amphlett 334 1361 2018 10.1016/j.cej.2017.11.040

상세보기
Ind. Eng. Chem. Gregor 44 12 2834 1952 10.1021/ie50516a024

상세보기
J. Radioanal. Nucl. Chem. Abderrahim 279 1 237 2009 10.1007/s10967-007-7270-z

상세보기
Chem. Eng. J. Foo 156 1 2 2010 10.1016/j.cej.2009.09.013

상세보기
J. Colloid Interface Sci. Koresh 92 2 517 1983 10.1016/0021-9797(83)90173-X

상세보기
Ind. Eng. Chem. Res. Manu 48 19 8954 2009 10.1021/ie900273v

상세보기
J. Hazard. Mater. Yang 152 2 690 2008 10.1016/j.jhazmat.2007.07.060

상세보기
J. Colloid Interface Sci. Kumar 408 1 200 2013 10.1016/j.jcis.2013.07.019

상세보기
Chem. Eng. J. Wang 163 3 364 2010 10.1016/j.cej.2010.08.017

상세보기
J. Mater. Chem. Bai 22 33 17293 2012 10.1039/c2jm33831a

상세보기
Chem. Eng. J. Mohapatra 155 1-2 184 2009 10.1016/j.cej.2009.07.035

상세보기
Procedia Environ. Sci Li 16 Iii 646 2012 10.1016/j.proenv.2012.10.089

상세보기
Environ. Prog. Sustain. Energy Senthil Kumar 33 1 28 2014 10.1002/ep.11741

상세보기
J. Colloid Interface Sci. El-Batouti 259 2 223 2003 10.1016/S0021-9797(02)00173-X

상세보기
J. Dispers. Sci. Technol. Dong 38 2 180 2017 10.1080/01932691.2016.1149716

상세보기
Indian J. Chem. Technol. urkovi 18 2 137 2011
J. South African Inst. Min. Metall. Amphlett 12 1251 2018
Smith 2004 NIST Standard Reference Database 46
Z. Anal. Chem. Mukherji 226 5 401 1966 10.1007/BF00503688

상세보기
Sep. Sci. Technol. Ihara 36 15 3511 2001 10.1081/SS-100107917

상세보기

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[국내논문] Impact of copper(II) on activation product removal from reactor decommissioning effluents in South Korea

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