초록 ▼

The invention provides intermediates of the formula: as well as a method of their preparation by reacting a thiol having at least two hydroxyl groups with a mono-unsaturated organic compound in the presence of a base catalyst. A polymerizable urethane acrylate oligomer or urethane methacrylate olig

The invention provides intermediates of the formula: as well as a method of their preparation by reacting a thiol having at least two hydroxyl groups with a mono-unsaturated organic compound in the presence of a base catalyst. A polymerizable urethane acrylate oligomer or urethane methacrylate oligomer is formed by reacting a polyisocyanate with the intermediate. The polymerizable urethane acrylate oligomer or urethane methacrylate is blended with a polymerization initiator to form a composition which is useful in such applications as adhesives.

대표청구항 ▼

1. A polymerizable composition which comprises a urethane acrylate oligomer or urethane methacrylate oligomer of the formula: wherein n is 1 to 50R′=—H, —CH3;R″=is a linear or branched C1 to C30 alkyl group, a linear or branched C3 to C30 alkenyl group, a C6 to C22 aryl group, a polyethylene glycol

1. A polymerizable composition which comprises a urethane acrylate oligomer or urethane methacrylate oligomer of the formula: wherein n is 1 to 50R′=—H, —CH3;R″=is a linear or branched C1 to C30 alkyl group, a linear or branched C3 to C30 alkenyl group, a C6 to C22 aryl group, a polyethylene glycol containing group, a (poly)ethylene glycol mono methyl ether containing group, a (poly)ethylene glycol mono ethyl ether containing group, a lauryl group, a silicone containing group, an alkoxysilane containing group, Si(OCH3)3 containing group, a fluorinated alkyl group, a brominated alkyl group, or a benzene derivative, 2. A polymerizable composition comprising the polymerizable urethane acrylate oligomer or urethane methacrylate oligomer of claim 1, and a polymerization initiator. 3. The polymerizable composition of claim 2 wherein the polymerization initiator comprises at least one of a peroxide, an azo compound, and a free radical generating photoinitiator. 4. The polymerizable composition of claim 2 wherein the polymerization initiator comprises at least one of benzoyl peroxide, cumyl peroxide, 2,2′-azobis(2-methylpropionitryl) (AIBN), tert-butyl hydroperoxide, diethyl ether peroxide, bis(tert-butylcyclohexyl)peroxydicarbonate, cumyl hydroperxide and aliphatic hydroperoxides. 5. The polymerizable composition of claim 2 wherein the polymerization initiator comprises the least one free radical generating photoinitiator which is present in an amount sufficient to polymerize the urethane acrylate or methacrylate oligomer upon exposure to sufficient actinic radiation.