초록

'화학 반응의 동력학적 유도'에 도달하기 위한 처음 3년간의 연구목표는 '이온 반응 동력학을 체계적으로 이해하기 위한 실험적, 이론적 방법의 개발'이었다. 세부적으로 다음 4개의 항목으로 분류할 수 있다.1) 상태 선택적 이온을 만들기 위한 기기 제작2) 반응 동력학 계산을 위한 이론적 방법 개발3) 상태 선택적 이온의 동력학 실험4) 연구방법, 기기, 이론적 모델을 보완하기 위한 이온 분해반응의 실험과 계산

Abstract ▼

The research objective for the first three-year phase to achieve the main subject 'Control of Chemical Reaction Dynamics' was 'Development of the experimental and theoretical methods for systematic understanding of ion reaction dynamics'. Details can be classified into four categories.1) Development

The research objective for the first three-year phase to achieve the main subject 'Control of Chemical Reaction Dynamics' was 'Development of the experimental and theoretical methods for systematic understanding of ion reaction dynamics'. Details can be classified into four categories.1) Development of an instrument(s) for generation of state-selected ions2) Development of theoretical methods for dynamics calculation3) Dynamics experiments for state-selected ions4) Ion dissociation dynamics experiments and calculations to refine the research ideas, instrumentation, and theoretical models

목차 Contents

• Chapter 1 : Introduction...6
• Chapter 2 : State-of-the-art...8
• Chapter 3 : Method, Results and Discussion...10
• A. Experimental Method...10
• 1) Study of ion dissociation with continuous type mass spectrometer...10
• 2) Conversion of the continuous type mass spectrometer into the pulse type...11
• 3) Construction of REMPI/MATI PI-PD instrument...12
• 4) Generation of vacuum ultraviolet (VUV) laser by four-wave mixing...15
• B. Theoretical Method...17
• 1) Statistical Reaction rate theory...17
• 2) Classical trajectory calculation...17
• 3) Quantum dynamics...18
• C. Results and Discussion...18
• 1) Conversion of the double focusing mass spectrometer into the pulse type-PI-PD...18
• 2) Mode-selective chemistry of $CS_{2}^{+}$...21
• 3) State-selective chemistry...24
• 4) Chemical control of reaction paths...33
• 5) Computational reaction dynamics...37
• Chapter 4 : Conclusion...45
• Chapter 5 : Major Contribution...46
• References...48
• Appendix...50