초록

Abstract ▼

● CO₂ capture and storage through nanoporous Covalent Organic Polymers (COPs)
· Scaling up of existing COPs and their systems & pilot plant design
· Development of basic building blocks (bi, tri, tetra-functional), i.e. cores and linkers
· Synthesis of networks (2D or 3D) from de

● CO₂ capture and storage through nanoporous Covalent Organic Polymers (COPs)
· Scaling up of existing COPs and their systems & pilot plant design
· Development of basic building blocks (bi, tri, tetra-functional), i.e. cores and linkers
· Synthesis of networks (2D or 3D) from designed monomer units
· Designing nanoporous organics containing nitrogen-rich functionalities
· Studies on gas sorption behavior and construction of CO₂ capture and storage system
● CO₂ capture and storage through metal-organic frameworks (MOFs)
· Synthesis of organic linker for water stable CO₂ capturing MOFs
· Enhancement of CO₂ capture ability of MOFs at the ambient pressure
· Designing pellet type of nano-MOFs for application on vehicles

목차 Contents

• Cover Sheet ... 1
• Contents ... 2
• 1. Executive Summary ... 4
• 2. Project Description ... 6
• 2.1. Overview and Background ... 6
• 2.2. Description of Individual Research Plan ... 8
• 2.2.1. Covalent Organic Polymers (COPs) ... 8
• 2.2.1.1. Monomer Design and Synthesis ... 11
• 2.2.1.2. COPs Synthesis ... 13
• 2.2.1.3. Metal-COPs Composite Synthesis ... 14
• 2.2.1.4. Nano-COPs Composite Synthesis ... 15
• 2.2.1.5. Evaluation of Building blocks and COPs ... 16
• 2.2.1.6. Mass Production of Monomers and COPs ... 18
• 2.2.1.7. Morphology and Membrane Research ... 18
• 2.2.1.8. Computational Design ... 20
• 2.2.1.9. System Design and Simulations ... 22
• 2.2.1.10. System (CO2 capture and storage) ... 24
• 2.2.1.11. Timelines ... 26
• 2.2.1.12. Deliverables list ... 27
• 2.2.1.13. Milestones list ... 29
• 2.2.2. Metal-organic frameworks (MOFs) ... 31
• 2.2.2.1 Phase A: Development of MOFs for CO2 capture at the ambient conditions with high capture capacity and chemical, thermal stabilities ... 31
• 2.2.2.1.1 The exponential stability in water condition ... 32
• 2.2.2.1.2 Synthesis of organic ligands for MOFs for high capacity uptake capabilities ... 33
• 2.2.2.1.3 Selection of metal ion for MOFs with stabilities ... 34
• 2.2.2.1.4 Injection of water molecule on purpose to synthesize water stable MOFs ... 35
• 2.2.2.1.5 Synthesis of Metal Organic Frameworks ... 36
• 2.2.2.1.6 Evaluation ... 37
• 2.2.2.1.7 Analysis of CO2 storage mechanism by In-situ SAXS ... 40
• 2.2.2.2 Phase B: Fabrication of CO2 capturing cartridge using MOFs for applying on vehicles ... 41
• 2.2.2.2.1 Synthesis of nano-MOFs ... 41
• 2.2.2.2.2 Mass production of MOFs ... 42
• 2.2.2.2.3 MOF pellet for CO2 capturing membrane cartridge ... 42
• 2.2.2.2.4 Integrated CO2 management prototype ... 44
• 2.2.2.2.5 The regeneration of cartridge after CO2 capture process ... 45
• 2.2.2.3 Scope of works for MOF research ... 46
• 3. Estimated Budget ... 56
• 3.1. Overview ... 56
• 3.2. Budgeting Criteria ... 56
• 3.3. Detailed Budget ... 57
• 3.4. Equipments and Materials ... 58
• 4. Biographical Information ... 62
• 5.1.List for Core Participants ... 62
• 5.2. Biographies of Core Participants ... 62
• 5. Instrumental Information ... 67
• 6. Background IPs that will be used for this research ... 70
• 7. References ... 71
• 끝페이지 ... 72