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In the previous papers (Kim and Park, 1984 a, b), we have reported on alginic acid from Ecklonia cava. The seasonal and portional variation in the composition of uronic acids and their block structures of alginic acid from Sargassum ringgoldianum (collected from Ichon-ri at the coast of Ilgwang-myon...

In the previous papers (Kim and Park, 1984 a, b), we have reported on alginic acid from Ecklonia cava. The seasonal and portional variation in the composition of uronic acids and their block structures of alginic acid from Sargassum ringgoldianum (collected from Ichon-ri at the coast of Ilgwang-myon, Yangsan-gun, Kyongnam, Korea, in the period of January to December in 1982) are investigated, and their relationship between the chemical composition and some rotated properties is discussed in this study. The results are as follows: 1. One year average contents of alginic acid were $21.4\%$ in the stipe and $19.7\%$ in the frond, one-year average values of M/G ratios were 2.38 in the frond and 1.85 in the stipe. The value of frond was largest in the period of Jauuary to April and smallest in May and October to December. The value of stipe was largest January to April and smallest in May. In general, the proportions of M block in the both of frond and stipe were higher than those of G block. 2. The viscosity of frond alginic acid showed higher values of 31.1 cP in November, and lower (below 7.0 cP) in the stipe alginic acid. Furthermore, the dependence on temperature of frond alginic acid was also larger in November and others were lower. Ion exchange ability of frond alginic acid was highest in July and the exchange amounts were $Pb^{2+}\;5.2,\;Cu^{2+}\;3.1,\;Zn^{2+}\;1.7,\;Co^{2+}\;1.5$ meq/g, Na-Alg., and the ability of stipe alginic acid was highest in May and the amounts were $Pb^{2+}\;4.6,\;Cu^{2+}\;3.3,\;Zn^{2+}\;2.5,\;Co^{2+}\;1.4$ meq/g. Na-Alg.. The affinity with metallic ions appeared higher in order of $Pb^{2+}>Cu^{2+}>Zn^{2+}>Co^{2+}$, and the exchange ability assumed to relate with the block ratio of uronic acid.