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[국내논문] Growth of O- and Zn-polar ZnO films by DC magnetron sputtering 원문보기

한국결정성장학회지 = Journal of the Korean crystal growth and crystal technology, v.22 no.1, 2012년, pp.1 - 4  

Yoo, Jin-Yeop (Department of Nano-semiconductor Engineering, National Korea Maritime University) ,  Choi, Sung-Kuk (Department of Nano-semiconductor Engineering, National Korea Maritime University) ,  Jung, Soo-Hoon (Department of Nano-semiconductor Engineering, National Korea Maritime University) ,  Cho, Young-Ji (Department of Nano-semiconductor Engineering, National Korea Maritime University) ,  Lee, Sang-Tae (Department of Offshore Plant Management, National Korea Maritime University) ,  Kil, Gyung-Suk (Division of Electrical and Electronics Engineering, National Korea Maritime University) ,  Lee, Hyun-Jae (PAN-Xal Co., Ltd.) ,  Yao, Takafumi (Center for Interdisciplinary Research, Tohoku University) ,  Chang, Ji-Ho (Department of Nano-semiconductor Engineering, National Korea Maritime University)

Abstract AI-Helper 아이콘AI-Helper

O- and Zn-polar ZnO films were grown by DC magnetron sputtering. Growth of high-quality, single-crystal ZnO thin films were confirmed by XRD and pole figure analysis. O-polar ZnO was grown on an $Al_2O_3$ substrate, which was confirmed by a slow growth rate (378 nm/hr), a fast etching rat...

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제안 방법

  • The polarity of the ZnO films was estimated and determined by evaluating the growth rate, etching rate, and surface morphology of each film. Chemical etching was performed using a diluted HCl solution (0.3 Vol. %), and the thickness and surface morphologies of the samples were measured by profiler and atomic force microscopy, respectively.
  • In the present study, (002) and (101) omega scans and a (101) pole figure scan all were measured. The polarity of the ZnO films was estimated and determined by evaluating the growth rate, etching rate, and surface morphology of each film. Chemical etching was performed using a diluted HCl solution (0.

이론/모형

  • The sputtering condition of the ZnO film was optimized in terms of the surface morphology and growth rate of the ZnO film. High-resolution X-ray diffraction (HRXRD) measurement was used to evaluate the crystallinity of the ZnO film. In the present study, (002) and (101) omega scans and a (101) pole figure scan all were measured.
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참고문헌 (15)

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  2. T. Detchprohm, H. Amano, K. Hiramatsu and I. Akasaki, "The growth of thick GaN film on sapphire substrate by using ZnO buffer layer", J. Cryst. Growth 128 (1993) 384. 

  3. S. Gu, R. Zhang, Y. Shi, Y. Zheng, L. Zhang and T.F. Kuech, "Hydride vapor phase epitaxy growth of GaN on sapphire with ZnO buffer layers" Appl. Phys. A 74 (2002) 537. 

  4. S.W. Lee, T. Minegishi, W.H. Lee, H. Goto, H.J. Lee, S.H. Lee, H.-J. Lee, J.S. Ha, T. Goto, T. Hanada, M.W. Cho and T. Yao, "Strain-free GaN thick films grown on single crystalline ZnO buffer layer with in situ lift-off technique", Appl. Phys. Lett. 90 (2007) 061907. 

  5. K. Kim, J. Song, H. Jung, W. Choi, S. Park and J. Song, "The grain size effects on the photoluminescence of $ZnO/{\alpha}-Al_{2}O_{3}$ grown by radio-frequency magnetron sputtering", J. Appl. Phys. 87 (2000) 3573. 

  6. J.-H. Lim, C.-K. Kang, K.-K. Kim, I.-K. Park, D.-K. Hwang and S.-J. Park, "UV electroluminesecence emission from ZnO light-emitting diodes grown by hightemperature radiofrequency sputtering", Adv. Mater. 18 (2006) 2720. 

  7. X. Gu, M.A. Reshchikov, A. Teke, D. Johnstone, H. Morkoc, B. Nemeth and J. Nause, "GaN epitaxy on thermally treated c-plane bulk ZnO substrates with O and Zn faces", Appl. Phys. Lett. 84 (2004) 2268. 

  8. R. Cebulla, R. Wendt and K. Ellmer, "Al-doped zinc oxide films deposited by simultaneous rf and dc excitation of a magnetron plasma: Relationships between plasma parameters and structural and electrical film properties", J. Appl. Phys. 83 (1998) 1087. 

  9. K.K. Kim, J.H. Song, H.J. Jung, W.K. Choi, S.J. Park and J.H. Song, "The grain size effects on the photoluminescence of $ZnO/{\alpha}-Al_{2}O_{3}$ grown by radio-frequency magnetron sputtering", J. App. Phys. 87 (2000) 3573. 

  10. X. Wang, Y. Tomita, O.H. Roh, M. Ohsugi, S.B. Che, T. Ishtani and A. Yoshikawa, "Polarity control of ZnO films grown on nitrided c-sapphire by molecular-beam epitaxy", Appl. Phys. Lett. 86 (2005) 011921. 

  11. H. Tampo, P. Fons, A. Yamada, K.K. Kim, H. Shibata, K. Matsubara, S. Niki, H. Yoshikawa and H. Kanie, "Determination of crystallographic polarity of ZnO layers", Appl. Phys. Lett. 87 (2005) 141904. 

  12. J.S. Park, J.H. Chang, T. Minegishi, H.J. Lee, S.H. Park, I.H. Im, T. Hanada, S.K. Hong, M.W. Cho and T. Yao, "Growth of polarity-controlled ZnO films on (0001) $Al_{2}O_{3}$ ", Journal of Electronic Materials 37 (2008) 736. 

  13. H. Kato, M. Sano, K. Miyamoto and T. Yao, "Polarity control of ZnO on c-plane sapphire by plasma-assisted MBE", J. Cryst. Growth 275 (2005) e2459. 

  14. K. Sakurai, M. Kanehiro, K. Nakahara, T. Tanabe S. Fujita and S. Fujita, "Effects of oxygen plasma condition on MBE growth of ZnO", J. Cryst. Growth 209 (2000) 522. 

  15. J.H. Park, S.J. Jang, S.S. Kim and B.T. Lee, "Growth and characterization of single crystal ZnO thin films using inductively coupled plasma metal organic chemical vapor deposition", Appl. Phys. Lett. 89 (2006) 121108. 

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