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세라미스트 = Ceramist, v.21 no.4, 2018년, pp.312 - 330
조정근 (전남대학교 신소재공학과) , 김재국 (전남대학교 신소재공학과)
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Energy storage/conversion has become crucial not only to meet the present energy demand but also more importantly to sustain the modern society. Particularly, electrical energy storage is critical not only to support electronic, vehicular and load-levelling applications but also to efficiently comme...
| 핵심어 | 질문 | 논문에서 추출한 답변 |
|---|---|---|
| 대용량 전력저장 시스템이란? | 현재는 전기를 생산하기 위한 시설로 화력발전소, 원자력발전소 등을 이용하지만 화석연료의 고갈과 환경오염, 지구온난화 문제로 인해 풍력이나 태양광 같은 깨끗한 신 재생 에너지를 이용한 안정적인 에너지 생산을 추고하고 있다. 이러한 신재생 에너지 활용 확대를 위해서는 피크 시간대 에너지를 저장했다가 에너지가 필요한 시간 및 부족한 시간에 사용할 수 있도록 에너지를 조절 및 분배하는 대용량 전력저장 시스템(ESS; Energy Storage System)이 필요하다.1-3) (Fig. | |
| 리튬 이온 이차전지의 장점은? | 이를 위해 각 전지의 특성을 결정하는 원천소재기술 개발에 대한 전 세계적인 경쟁이 본격화 되고 있다. 이러한 전지 중 리튬 이온 이차전지는 높은 에너지 변환효율을 가지며, 유지 및 보수가 간단하여 대용량 전력저장 시스템용 전지로 가장 선호되고 있다. 특히, 리튬 이온 이차전지는 소형 전지시장 및 중대형 전지시장을 통제 할 수 있는 가장 유망한 기술 중 하나이며, 미래의 다양한 애플리케이션을 위한 소비량은 꾸준히 증가할 것으로 예상된다. | |
| 아연 이온 이차전지의 문제점은? | 대표적인 아연 이온 이차전지는 1950년대에 소개되었으며 음극으로 아연 금속, 양극으로MnO2 및 알칼리성 KOH 전해질로 구성된 Zn//MnO2 전지였으며 현재까지도 휴대용 저장장치에서 활용되고 있다. 그러나 충·방전과정에서 음극 및 양극 표면에 비가역적으로 형성되는 Zn(OH)2, Mn3O4로 인해 전도도 감소와 용량 감소가 발생하며, 이에 따른 에너지 밀도 감소로 인해 활용도가 현저히 낮은 편이다.10-13) 이를 보완하기 위해 2012년 Feiyu Kang 그룹의 연구에서는 전해질로 ZnSO4를 활용하여 약산성 조건으로 만들어 가역적인 아연 이온의 삽·탈리를 확인하였다. |
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