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[국내논문] Micro/Millimeter-Wave Dielectric Indialite/Cordierite Glass-Ceramics Applied as LTCC and Direct Casting Substrates: Current Status and Prospects 원문보기 논문타임라인

한국세라믹학회지 = Journal of the Korean Ceramic Society, v.56 no.6, 2019년, pp.526 - 533  

Ohsato, Hitoshi (Microelectronics Research Unit, Faculty of Information Technology and Electrical Engineering, University of Oulu) ,  Varghese, Jobin (Microelectronics Research Unit, Faculty of Information Technology and Electrical Engineering, University of Oulu) ,  Vahera, Timo (Microelectronics Research Unit, Faculty of Information Technology and Electrical Engineering, University of Oulu) ,  Kim, Jeong Seog (Department of Material Science and Engineering, Hoseo University) ,  Sebastian, Mailadil T. (Microelectronics Research Unit, Faculty of Information Technology and Electrical Engineering, University of Oulu) ,  Jantunen, Heli (Microelectronics Research Unit, Faculty of Information Technology and Electrical Engineering, University of Oulu) ,  Iwata, Makoto (Department of Physical Science and Engineering, Nagoya Institute of Technology)

Abstract AI-Helper 아이콘AI-Helper

Indialite/cordierite glass-ceramics demonstrate excellent microwave dielectric properties such as a low dielectric constant of 4.7 and an extremely high quality factor Qf of more than 200 × 103 GHz when crystallized at 1300℃/20 h, which are essential criteria for application to 5G/6G m...

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제안 방법

  • 23) The bulk densities of the sintered samples were measured by the Archimedes method. The microstructural analysis of the green tapes and thermally etched sintered samples was performed by scanning electron microscopy (FESEM; Zeiss Ultra Plus).

이론/모형

  • The microwave dielectric properties εr and Qf were determined by means of the Hakki-Coleman method,24,25) and TCf was estimated using the resonant cavity method.
  • The crystal structure of the specimens was measured via X-ray powder diffraction (XRPD; Bruker D8) using monochromatized Cu Kα radiation. The amount of indialite/cordierite was calculated by means of the Rietveld method using Fullprof Software.23) The bulk densities of the sintered samples were measured by the Archimedes method. The microstructural analysis of the green tapes and thermally etched sintered samples was performed by scanning electron microscopy (FESEM; Zeiss Ultra Plus).
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참고문헌 (31)

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  5. H. Ohsato, "Microwave Dielectrics with Perovskite-Type Structure," pp. 281-330 in Perovskite Materials-Synthesis, Characterization, Properties, and Applications, Ed. by L. Pan, G. Zhu, INTECH, Rijeka, 2016. 

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  7. M. T. Sebastian, R. Ubic, and H. Jantunen, "Low-Loss Dielectric Ceramic Materials and Their Properties," Int. Mater. Rev., 60 [7] 392-412 (2015). 

  8. Y. Guo, H. Ohsato, and K. Kakimoto, "Characterization and Dielectric Behavior of Willemite and $TiO_2$ -doped Willemite Ceramics at Millimeter-Wave Frequency," J. Eur. Ceram. Soc., 26 [10] 1827-30 (2006). 

  9. T. Tsunooka, H. Sugiura, Y. Higashida, T. Fukui, H. Okawa, and Y. Iwata, "Low-Permittivity Ceramic Dielectrics," JFCC Rev., 4 72-81 (1992). 

  10. H. Ohsato, "Microwave Materials with High Q and Low Dielectric Constant for Wireless Communications," MRS Proc., 833 55-62 (2005). 

  11. H. Ohsato, M. Ando, and T. Tsunooka, "Synthesis of Forsterite with High Q and Near Zero TCf for Microwave/ Millimeterwave Dielectrics," J. Korean Ceram. Soc., 44 [11] 597-606 (2007). 

  12. H. Ohsato, T. Tsunooka, T. Sugiyama, K. Kakimoto, and H. Ogawa, "Forsterite Ceramics for Millimeterwave Dielectrics," J. Electroceram., 17 [2-4] 445-50 (2006). 

  13. L. Pauling, "The Nature of Silicon-Oxygen Bonds," Am. Mineral., 65 321-23 (1980). 

  14. G. V. Gibbs, "The Polymorphism of Cordierite I: the Crystal Structure of Low Cordierite," Am. Mineral., 51 1068-87 (1966). 

  15. M. Terada, K. Kawamura, I. Kagomiya, K. Kakimoto, and H. Ohsato, "Effect of Ni Substitution on the Microwave Dielectric Properties of Cordierite," J. Eur. Ceram. Soc., 27 [8-9] 3045-48 (2007). 

  16. H. Ohsato, M. Terada, I. Kagomiya, K. Kawamura, K. Kakimoto, and E. S. Kim, "Sintering Conditions of Cordierite for Microwave/Millimeterwave Dielectrics," IEEE Trans. Ultrason. Ferroelectr. Freq. Control., 55 [5] 1082-85 (2008). 

  17. H. Ohsato, I. Kagomiya, M. Terada, and K. Kakimoto, "Origin of Improvement of Q Based on High Symmetry Accompanying Si-Al Disordering in Cordierite Millimeter-Wave Ceramics," J. Eur. Ceram. Soc., 30 [2] 315-18 (2010). 

  18. H. Ohsato, J. S. Kim, A. Y. Kim, C. I. Cheon, and K. W. Chae, "Millimeter-Wave Dielectric Properties of Cordierite/ Indialite Glass Ceramics," Jpn. J. Appl. Phys., 50 [9S2] 09NF01 (2011). 

  19. H. Ohsato, J. S. Kim, C. I. Cheon, and I. Kagomiya, "Millimeter-Wave Dielectrics of Indialite/Cordierite Glass Ceramics: Estimating Si/Al Ordering by Volume and Covalency of Si/Al Octahedron," J. Ceram. Soc. Jpn., 121 [1416] 649-54 (2013). 

  20. J. Varghese, T. Vahera, H. Ohsato, M. Iwata, and H. Jantunen, "Novel Low-Temperature Sintering Ceramic Substrate based on Indialite/Cordierite Glass Ceramics," Jpn. J. Appl. Phys., 56 [10S] 10PE01 (2017). 

  21. H. Ohsato, J. Varghese, A. Kan, J-S. Kim, I. Kagomiya, H. Ogawa, M. T. Sebastian, and H. Jantunen, "Volume Crystallization and Improved TCf of Indialite/Cordierite Glass Ceramics by $TiO_2$ Addition," J. Ceram. Soc. Jpn., in preparation. 

  22. H. Ohsato, J.-S. Kim, C.-I. Cheon, and I. Kagomiya, "Crystallization of Indialite/Cordierite Glass Ceramics for Millimeter-Wave Dielectrics," Ceram. Int., 41 S588-95 (2015). 

  23. Fullprof Software by Juan Rodriguez-Carvajal in France, http://www-llb.cea.fr/fullweb/powder.htm. Accessed on 26/11/2019. 

  24. B. W. Hakki and P. D. Coleman, "A Dielectric Resonator Method of Measuring Inductive in the Millimeter Range," IEEE Trans. Microwave Theory Tech., 8 [4] 402-10 (1960). 

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  28. I. Kagomiya and H. Ohsato, "Crystallized Glass Ceramic Dielectrics for High Frequency"; Japanese Patent Application No.2014-164285, 2014. 

  29. H. Ohsato, "Practicing Applied Mineralogy on the Electroceramics - Examples: Microwave and Millimeter-Wave Dielectrics," Jpn. Mag. Mineral. Petrol. Sci., 47 [1] 43-50 (2018). 

  30. R. E. Mistler and E. R. Twiname, Tape Casting: Theory and Practice; American Ceramic Society, Westerville, OH, 2000. 

  31. Y. T. Fei, S. J. Fan, R. Y. Sun, and M. Ishii, "Study on Phase Diagram of $Bi_2O_3-SiO_2$ System for Bridgman Growth of $Bi_4Si_3O_{12}$ Single Crystal," Prog. Cryst. Growth Charact. Mater., 40 [1-4] 183-88 (2000). 

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