[논문]토양-지하수내 미세플라스틱 거동 연구를 위한 수정진동자미세저울 기술 소개

김주혁; 명현아; 손상보; 권기덕

doi:10.22807/kjmp.2020.33.4.463

토양-지하수내 미세플라스틱 거동 연구를 위한 수정진동자미세저울 기술 소개
Application of Quartz Crystal Microbalance to Understanding the Transport of Microplastics in Soil and Groundwater 원문보기

광물과 암석 = Korean journal of mineralogy and petrology, v.33 no.4, 2020년, pp.463 - 475

김주혁 (강원대학교 자연과학대학 지질학과) , 명현아 (강원대학교 자연과학대학 지질학과) , 손상보 (강원대학교 자연과학대학 지질학과) , 권기덕 (강원대학교 자연과학대학 지질학과)

초록
AI-Helper

최근 토양과 지하수에서도 미세플라스틱이 발견되어 미세플라스틱 환경오염 관련 연구의 중요성이 크게 대두되고 있다. 주로 ㎛ - nm의 작은 입자로 존재하는 점토광물과 금속산화광물은 표면적이 넓어 미세플라스틱에 대한 흡착력 등 화학 반응도가 매우 높기 때문에, 광물표면 상호작용은 토양과 지하수 환경 내 미세플라스틱의 거동을 결정하는 중요한 역할을 할 수 있다. 따라서, 광물과 미세플라스틱 간의 상호작용에 대한 환경광물학 연구는 미세플라스틱 거동 예측 기술개발 및 오염대책 마련에 핵심이 되는 연구분야라 할 수 있다. 광물표면과 미세플라스틱(특히, 나노플라스틱) 연구에는 분자-나노수준의 분석기술이 요구된다. 이번 기술보고에서는 나노그람(=10-9 g) 수준의 질량 변화를 실시간으로 측정할 수 있는 초정밀 분석기기로, 광물표면에 흡·탈착되는 미세플라스틱 및 나노플라스틱의 미세한 질량 변화를 측정할 수 있는, 수정진동자미세저울(quartz crystal microbalance, QCM)을 소개한다. QCM 작동원리를 소개하고, 대표적인 QCM 연구결과와 기존 컬럼 실험과의 장단점을 비교하여 미세플라스틱 연구에 QCM 활용 가능성을 논의한다.

Abstract ▼ AI-Helper

Presence of microplastics in soil and groundwater has recently been reported and environmental concerns are raised as to the plastic pollution. In the subsurface environment, clay minerals and metal oxide minerals are commonly found as finely dispersed states. Because the minerals have high sorption capacities for diverse pollutants, interactions with mineral surface play an important role in the transport of microplastics in groundwater. Accordingly, environmental mineralogy investigating the interactions between microplastics and mineral surfaces is the essential research area to understand the fate and transport of microplastics in the subsurface environment. The microplastic-mineral surface research requires molecular- to nano-scale analyses to be able to probe the relatively weak interactions between them. The current report introduces a nano-scale analysis tool called quartz crystal microbalance (QCM) that can measure the sorbed/desorbed mass of nanoplastics on mineral surfaces at the level of a few nanograms (~10-9 g). This report briefly reviews the main principles in the QCM measurement and discusses applications of QCM to the environmental mineralogy research.

주제어

표/그림 (6)

그림 Fig. 1. Possible fate of agricultural mulching film in subsurface environment. Plastic mulches are weathered into micron- or nano-sized plastic particles, the transport of which would be controlled mainly by the interactions with mineral surfaces.
그림 Fig. 2. The number of published research articles containing a keyword of microplastics (MPs), nanoplastics (NPs), or plastic interactions with minerals (searched in Web of Science).
그림 Fig. 3. A schematic diagram of quartz crystal microbalance experiment.
그림 Fig. 4. QCM frequency changes as a function of nanoplastic (de)sorption time on SiO₂ surface. Adsorbed and desorbed amount of nanoplstics are proportional to the frequency changes. Aqueous suspension of nanoplastics is injected from 10 to 39 mins, and cleaning solution is injected from 39 to 55 mins.
그림 Fig. 5. QCM-determined amount of microplastics produced when a plastic bag is teared or cut by scissors. [Reprinted with permission from Sobhani et al. (2020)]
그림 Fig. 6. QCM-measured deposition rates of spherical or rod-shaped polystyrene microplastic particles on silica surface at different ionic strengths. Plastic surfaces are carboxylated and silica surface are coated with polylysine. Dashed lines are theoretical deposition rates. [Reprinted with permission from Seymour et al. (2013). Copyright (2020) American Chemical Society]

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저자의 다른 논문 :

표제어: PCR

동의어: Packet Collision Rate

용어 설명 출처 목록 (6)

용어 설명: PCR은 세균 특이성이 있는 primer를 이용하여 적은 수의 세균이 있을지라도 쉽게 검출할 수 있는 유용한 방법이며, 이를 이용하여 구강 내 치면세균막이나 타액에서 직접 세균을 검출할 수 있게 되었다[8].

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저장형식	Text(ASCII format) Excel format RefWorks Direct Export RIS format (for Reference Manager, ProCite, EndNote), Scholar's Aids, Mendeley
메일정보	받는사람 (필수) @ 보내는사람 (선택) @ 제목 내용 KISTI 검색결과 이메일 서비스
안내	총 건의 자료가 검색되었습니다. 다운받으실 자료의 인덱스를 입력하세요. (1-10,000) 검색결과의 순서대로 최대 10,000건 까지 다운로드가 가능합니다. 데이타가 많을 경우 속도가 느려질 수 있습니다.(최대 2~3분 소요) 다운로드 파일은 UTF-8 형태로 저장됩니다. 파일의 내용이 제대로 보이지 않을실 때는 웹브라우저 상단의 보기 -> 인코딩 -> 자동선택 여부를 확인하십시오. ~ Text(ASCII format) Excel format

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