[논문]Simultaneous Spectrometric Determination of Caffeic Acid, Gallic Acid, and Quercetin in Some Aromatic Herbs, Using Chemometric Tools

Kachbi, Abdelmalek; Abdelfettah-Kara, Dalila; Benamor, Mohamed; Senhadji-Kebiche, Ounissa

doi:10.5012/jkcs.2021.65.4.254

Simultaneous Spectrometric Determination of Caffeic Acid, Gallic Acid, and Quercetin in Some Aromatic Herbs, Using Chemometric Tools 원문보기

대한화학회지 = Journal of the Korean Chemical Society, v.65 no.4, 2021년, pp.254 - 259

Kachbi, Abdelmalek (Laboratoire des Procedes Membranaires et des Techniques de Separation et de Recuperation, Faculty of Technology, Universite de Bejaia) , Abdelfettah-Kara, Dalila (Laboratoire des Procedes Membranaires et des Techniques de Separation et de Recuperation, Faculty of Technology, Universite de Bejaia) , Benamor, Mohamed (Laboratoire des Procedes Membranaires et des Techniques de Separation et de Recuperation, Faculty of Technology, Universite de Bejaia) , Senhadji-Kebiche, Ounissa (Laboratoire des Procedes Membranaires et des Techniques de Separation et de Recuperation, Faculty of Technology, Universite de Bejaia)

Abstract ▼ AI-Helper

The purpose of this work is the development of a method for an effective, less expensive, rapid, and simultaneous determination of three phenolic compounds (caffeic acid, gallic acid, and quercetin) widely present in food resources and known for their antioxidant powers. The method relies on partial least squares (PLS) calibration of UV-visible spectroscopic data. This model was applied to simultaneously determine, the concentrations of caffeic acid (CA), gallic acid (GA), and quercetin (Q) in six herb infusion extracts: basil, chive, laurel, mint, parsley, and thyme. A wavelength range (250-400) nm, and an experimental calibration matrix with 21 samples of ternary mixtures composed of CA (6.0-21.0 mg/L), GA (10.0-35.2 mg/L), and Q (6.4-17.5 mg/L) were chosen. Spectroscopic data were mean-centered before calibration. Two latent variables were determined using the contiguous block cross-validation procedure after calculating the root mean square error cross-validation RMSECV. Other statistic parameters: RMSEP, R2, and Recovery (%) were used to determine the predictive ability of the model. The results obtained demonstrated that UV-visible spectrometry and PLS regression were successfully applied to simultaneously quantify the three phenolic compounds in synthetic ternary mixtures. Moreover, the concentrations of CA, GA and Q in herb infusion extracts were easily predicted and found to be 3.918-18.055, 9.014-23.825, and 9.040-13.350 mg/g of dry sample, respectively.

주제어

표/그림 (10)

그림 Figure 1. Absorbance spectra of caffeic acid, gallic acid and quercetin. Concentration of each component is 10 mg/L.
그림 Figure 2. Representation of the RMSECV vs. Latent Variable Number.
표 Table 1. Results of univariate calibration
표 Table 2. Concentration data for calibration set mixtures of caffeic acid, gallic acid and quercetin
그림 Figure 3. Representation of bi-plot scores and loadings on (LV1, LV2) plan.
그림 Figure 4. Loadings on LV 1 and LV 2.
표 Table 3. Concentration data for prediction set mixtures and recovery values
그림 Figure 5. Representation of the UV spectra of the six aqueous herb extracts.
그림 Figure 6. Predicted concentration of CA, GA and Q in the six aqueous herb extracts.
표 Table 4. Statistical parameters using PLS model

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