[논문]계면 제어를 기반으로 한 고성능 전고체 전지 연구

황인수; 이현정

doi:10.22805/jit.2022.42.1.019

계면 제어를 기반으로 한 고성능 전고체 전지 연구
Review of interface engineering for high-performance all-solid-state batteries 원문보기

産業技術硏究 : 江原大學校産業技術硏究所 = Journal of industrial technology, v.42 no.1, 2022년, pp.19 - 27

황인수 (School of Chemical and Biological Engineering and Institute of Chemical Processes, Seoul National University) , 이현정 (Division of Chemical Engineering and Bioengineering, Kangwon National University)

Abstract ▼ AI-Helper

This review will discuss the effort to understand the interfacial reactions at the anode and cathode sides of all-solid-state batteries. Antiperovskite solid electrolytes have received increasing attention due to their low melting points and anion tunability which allow controlling microstructure and crystallographic structures of this material system. Antiperovskite solid electrolytes pave the way for the understanding relationship between critical current density and mechanical properties of solid electrolytes. Microstructure engineering of cathode materials has been introduced to mitigate the volume change of cathode materials in solid-state batteries. The hollow microstructure coupled with a robust outer oxide layer effectively mitigates both volume change and stress level of cathode materials induced by lithium insertion and extraction, thus improving the structural stability of the cathode and outer oxide layer, which results in stable cycling performance of all-solid-state batteries.

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표/그림 (10)

그림 Fig. 1 Crystal structures of Li₃OCl and Li₂OHBr. Reproduced with permission^[12]. Copyright 2022, Royal Society of Chemistry.
$Fig. 2 X-ray diffraction patterns of (a) Li2OHCl, (b) Li2OHBr and (c) Li2OHCl0.9Br0.1. (d) Comparative XRD patterns of as-synthesized Li2OHX series (X=Cl1-xBrx, x=0,0.1,0.3,0.5,0.7,0.9 and 1. (a-d)Reproduced with permission[12]. Copyright 2022, Royal Society of Chemistry.$ 그림 Fig. 2 X-ray diffraction patterns of (a) Li₂OHCl, (b) Li₂OHBr and (c) Li₂OHCl_0.9Br_0.1. (d) Comparative XRD patterns of as-synthesized Li₂OHX series (X=Cl_1-xBr_x, x=0,0.1,0.3,0.5,0.7,0.9 and 1. (a-d)Reproduced with permission^[12]. Copyright 2022, Royal Society of Chemistry.
$Fig. 3 (a) Setup for the in situ high temperature X-ray diffraction analysis at APS 17 BM-B beamline. In situ high temperature XRD patterns of Li2OHCl (b) and Li2OHCl0.9Br0.1 (c) with the region around 7 degrees magnified. (b-c)Reproduced with permission[12]. Copyright 2022, Royal Society of Chemistry.$ 그림 Fig. 3 (a) Setup for the in situ high temperature X-ray diffraction analysis at APS 17 BM-B beamline. In situ high temperature XRD patterns of Li₂OHCl (b) and Li₂OHCl_0.9Br_0.1 (c) with the region around 7 degrees magnified. (b-c)Reproduced with permission^[12]. Copyright 2022, Royal Society of Chemistry.
그림 Fig. 4 Volumetric thermal expansion coefficients of Li₂OHCl_1-xBr_x series measured at 40~200℃. Reproduced with permission^[12]. Copyright 2022, Royal Society of Chemistry.
그림 Fig. 6 In situ XPS measurement during Li metal sputtering on the Li₂OHCl_0.9Br_0.1 pellet. Reproduced with permission^[12]. Copyright 2022, Royal Society of Chemistry.
그림 Fig. 5 (a) DSC profiles of Li₂OHCl_1-xBr_x series. (b) Digital photograph of Li₂OHBr antiperovskite solid electrolyte fabricated by melting and solidification. (c)　 Cross-sectional scanning electron microscopy（SEM） image of a Li₂OHCl pellet. Reproduced with permission^[12]. Copyright 2022, Royal Society of Chemistry.
그림 Fig. 7 (a) Changes of radial displacement (u_R/Rϵ^c) and volumetric energy density by the shell thickness–radius ratio (t/R) at various to values. (b) Change of hoop stress in CEI layer by shell thickness-radius ratio. Reproduced with permission^[22]. Copyright 2021, American Chemical Society.
그림 Fig. 9 PFIB cross-section SEM images of Al₂O₃-H-LNMO/LPSCl/VCF composite cathode after 100 cycles. The yellow arrows in the SEM image of the Al₂O₃-H-LNMO/LPSCl/VCF composite cathode show intimate contact between Al₂O₃-H-LNMO and LPSCl solid electrolyte after cycling. Reproduced with permission^[21]. Copyright 2022, American Chemical Society.
그림 Fig. 8 Scanning transmission electron microscopy (STEM) image of the synthesized H-LNMO particle and cross-section SEM image of the H-LNMO particle after FIB sectioning. Reproduced with permission^[22]. Copyright 2021, American Chemical Society.
그림 Fig. 10 (a) Cycling performance of SSBs with pellet- and film-type Al₂O₃–H-LNMO composite cathodes. Comparison of (b) the initial areal and specific capacities and (c) the capacity retention of SSBs composed of LNMO and solid sulfide electrolytes. Reproduced with permission^[21]. Copyright 2022, American Chemical Society

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표제어: PCR

동의어: Packet Collision Rate

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용어 설명: PCR은 세균 특이성이 있는 primer를 이용하여 적은 수의 세균이 있을지라도 쉽게 검출할 수 있는 유용한 방법이며, 이를 이용하여 구강 내 치면세균막이나 타액에서 직접 세균을 검출할 수 있게 되었다[8].

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