[논문]Unraveling the role of cobalt in the direct conversion of CO2 to high-yield liquid fuels and lube base oil

Jo, Heuntae; Khan, Muhammad Kashif; Irshad, Muhammad; Arshad, Malik Waqar; Kim, Seok Ki; Kim, Jaehoon

doi:10.1016/j.apcatb.2021.121041

[해외논문] Unraveling the role of cobalt in the direct conversion of CO2 to high-yield liquid fuels and lube base oil

Applied catalysis. B, Environmental, v.305, 2022년, pp.121041 -

Jo, Heuntae (School of Mechanical Engineering, Sungkyunkwan University) , Khan, Muhammad Kashif (School of Mechanical Engineering, Sungkyunkwan University) , Irshad, Muhammad (School of Chemical Engineering, Sungkyunkwan University) , Arshad, Malik Waqar (Carbon Resource Institute, Korea Research Institute of Chemical Technology) , Kim, Seok Ki (Carbon Resource Institute, Korea Research Institute of Chemical Technology) , Kim, Jaehoon (School of Mechanical Engineering, Sungkyunkwan University)

Abstract ▼ AI-Helper

Abstract Owing to their high CO2 methanation activity, the direct hydrogenation of CO2 to long-chain C5+ over Co-based catalysts is challenging. Here, we demonstrate a Na- and Mn-promoted, core-shell Co@CoOx/Co2C catalyst that produces a high C5+ yield of 21.1% at a CO2 conversion of 64.3% and low temperature of 270 °C. CO2 conversion and C5+ selectivity are ensured during long-term catalytic reactions up to 1425 h. C21+ selectivity increases to 14.9% with increasing time on stream. The catalyst exhibits high C5+ and C21+ selectivity, making it a promising option for producing liquid fuels and lube base oil in one-pass CO2 conversion. Direct CO2 dissociation and formate formation over the oxygen-vacant Co3O4 phase in the shell is the plausible reverse–water–gas–shift reaction mechanism. The Mn promoter facilitates the formation of the CoOx phase at the outermost surface, suppressing the direct contact between CO2 and the metallic Co core. Highlights Core-shell Co@CoOx/Co2C produces a high C5+ yield (21.1%) at a CO2 conversion. C5+ yield is maintained during long-term reactions up to 1425 h. C21+ selectivity increases to 14.9% with increasing time on stream. Oxygen-vacant Co3O4 is the site for RWGS reaction. CoOx phase suppresses CH4 formation by inhibiting contact between CO2 and Co0. Graphical Abstract [DISPLAY OMISSION]

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참고문헌 (60)

Energy Environ. Sci. Porosoff 9 62 2016 10.1039/C5EE02657A Catalytic reduction of CO2 by H2 for synthesis of CO, methanol and hydrocarbons: challenges and opportunities

상세보기
Appl. Catal. B Sibi 301 2022 10.1016/j.apcatb.2021.120813 High-yield synthesis of BTEX over Na-FeAlOx/Zn-HZSM-5@SiO2 by direct CO2 conversion and identification of surface intermediates

상세보기
ACS Catal. Sibi 11 8382 2021 10.1021/acscatal.1c00747 Synthesis of monocarboxylic acids via direct CO2 conversion over Ni-Zn intermetallic catalysts

상세보기
Appl. Catal. B Zhang 293 2021 10.1016/j.apcatb.2021.120207 Tuning the interaction between Na and Co2C to promote selective CO2 hydrogenation to ethanol

상세보기
Catal. Commun. Gnanamani 12 936 2011 10.1016/j.catcom.2011.03.002 Fischer-Tropsch synthesis: effect of CO2 containing syngas over Pt promoted Co/γ-Al2O3 and K-promoted Fe catalysts

상세보기
Appl. Catal. B Yang 282 2021 10.1016/j.apcatb.2020.119554 Revealing property-performance relationships for efficient CO2 hydrogenation to higher hydrocarbons over Fe-based catalysts: statistical analysis of literature data and its experimental validation

상세보기
Chem. Rev. Khodakov 107 1692 2007 10.1021/cr050972v Advances in the development of novel cobalt Fischer−Tropsch catalysts for synthesis of long-chain hydrocarbons and clean fuels

상세보기
Nature Zhong 538 84 2016 10.1038/nature19786 Cobalt carbide nanoprisms for direct production of lower olefins from syngas

상세보기
Appl. Catal. A Visconti 355 61 2009 10.1016/j.apcata.2008.11.027 Fischer-Tropsch synthesis on a Co/Al2O3 catalyst with CO2 containing syngas

상세보기
J. CO2 Util. Saeidi 5 66 2014 10.1016/j.jcou.2013.12.005 Hydrogenation of CO2 to value-added products-a review and potential future developments

상세보기
ACS Catal. Kim 10 8660 2020 10.1021/acscatal.0c01417 Cobalt ferrite nanoparticles to form a catalytic Co-Fe alloy carbide phase for selective CO2 hydrogenation to light olefins

상세보기
ACS Catal. Wang 9 11335 2019 10.1021/acscatal.9b04187 Cobalt-nickel catalysts for selective hydrogenation of carbon dioxide into ethanol

상세보기
Energy Environ. Sci. Dorner 3 884 2010 10.1039/c001514h Heterogeneous catalytic CO2 conversion to value-added hydrocarbons

상세보기
ACS Catal. Khan 10 10325 2020 10.1021/acscatal.0c02611 Selective conversion of carbon dioxide into liquid hydrocarbons and long-chain α-olefins over Fe-amorphous AlOx bifunctional catalysts

상세보기
Int. J. Hydrog. Energy Susanti 37 11677 2012 10.1016/j.ijhydene.2012.05.087 High-yield hydrogen production from glucose by supercritical water gasification without added catalyst

상세보기
Fuel Khan 182 650 2016 10.1016/j.fuel.2016.06.023 A non-catalytic, supercritical methanol route for effective deacidification of naphthenic acids

상세보기
Phys. Rev. B Kresse 54 11169 1996 10.1103/PhysRevB.54.11169 Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set

상세보기
Phys. Rev. B Lee 82 2010 Higher-accuracy van der Waals density functional
ACS Catal. Zhang 7 8285 2017 10.1021/acscatal.7b02800 C2 oxygenate synthesis via Fischer-Tropsch synthesis on Co2C and Co/Co2C interface catalysts: how to control the catalyst crystal facet for optimal selectivity

상세보기
Surf. Sci. Xu 605 1962 2011 10.1016/j.susc.2011.07.013 DFT studies on H2O adsorption and its effect on CO oxidation over spinel Co3O4 (110) surface

상세보기
Surf. Sci. Youmbi 621 1 2014 10.1016/j.susc.2013.10.012 Structure of CoO(001) surface from DFT+U calculations

상세보기
ACS Catal. Yan 9 6380 2019 10.1021/acscatal.9b01485 Surface structure of Co3O4 (111) under reactive gas-phase environments

상세보기
Cramer 2013 Essentials of Computational Chemistry: Theories and Models
Phys. Rev. Lett. Garrido Torres 122 2019 10.1103/PhysRevLett.122.156001 Low-scaling algorithm for nudged elastic band calculations using a surrogate machine learning model

상세보기
Catal. Sci. Technol. Rößler 9 4047 2019 10.1039/C9CY00671K Accumulation of liquid hydrocarbons during cobalt-catalyzed Fischer-Tropsch synthesis - influence of activity and chain growth probability

상세보기
Nat. Commun. Wei 8 15174 2017 10.1038/ncomms15174 Directly converting CO2 into a gasoline fuel

상세보기
ACS Catal. Ramirez 9 6320 2019 10.1021/acscatal.9b01466 Effect of zeolite topology and reactor configuration on the direct conversion of CO2 to light olefins and aromatics

상세보기
ACS Catal. Cui 9 3866 2019 10.1021/acscatal.9b00640 Selective production of aromatics directly from carbon dioxide hydrogenation

상세보기
Energy Environ. Sci. Klerk 4 1177 2011 10.1039/c0ee00692k Fischer-Tropsch fuels refinery design

상세보기
ChemistrySelect Guo 3 13705 2018 10.1002/slct.201803335 Enhanced liquid fuel production from CO2 Hydrogenation: catalytic performance of bimetallic catalysts over a two-stage reactor system

상세보기
ChemCatChem Bordet 10 4047 2018 10.1002/cctc.201800821 Enhancement of carbon oxides hydrogenation on iron-based nanoparticles by in-situ water removal

상세보기
J. Catal. Dinse 288 104 2012 10.1016/j.jcat.2012.01.008 Effects of Mn promotion on the activity and selectivity of Co/SiO2 for Fischer-Tropsch synthesis

상세보기
ACS Catal. Chen 7 8061 2017 10.1021/acscatal.7b02758 Mechanism of cobalt-catalyzed CO hydrogenation: 2. Fischer-Tropsch synthesis

상세보기
ACS Catal. Chen 8 1580 2018 10.1021/acscatal.7b03639 Influence of carbon deposits on the cobalt-catalyzed Fischer-Tropsch reaction: evidence of a two-site reaction model

상세보기
Chem. Mater. Martin de Vidales 7 1716 1995 10.1021/cm00057a022 Thermal behavior in air and reactivity in acid medium of cobalt manganese spinels MnxCo3-xO4 (1.ltoreq. x.ltoreq. 3) synthesized at low temperature

상세보기
ACS Catal. Zhao 8 228 2018 10.1021/acscatal.7b02403 Insight into the formation of Co@Co2C catalysts for direct synthesis of higher alcohols and olefins from syngas

상세보기
ACS Catal. Wu 7 1150 2017 10.1021/acscatal.6b02835 Ambient-pressure X-ray photoelectron spectroscopy study of cobalt foil model catalyst under CO, H2, and their mixtures

상세보기
ACS Catal. Zhu 7 2800 2017 10.1021/acscatal.7b00221 Role of manganese oxide in syngas conversion to light olefins

상세보기
Appl. Phys. Lett. Zhou 79 3512 2001 10.1063/1.1419235 Size-induced lattice relaxation in CeO2 nanoparticles

상세보기
ACS Catal. Lin 9 9554 2019 10.1021/acscatal.9b02513 Fischer-Tropsch synthesis to olefins: catalytic performance and structure evolution of Co2C-based catalysts under a CO2 environment

상세보기
ChemCatChem Paterson 10 5154 2018 10.1002/cctc.201800883 Manipulation of Fischer-Tropsch synthesis for production of higher alcohols using manganese promoters

상세보기
Appl. Catal. A Sanchez-Escribano 316 68 2007 10.1016/j.apcata.2006.09.020 On the mechanisms and the selectivity determining steps in syngas conversion over supported metal catalysts: an IR study

상세보기
Pavia 2015 Introduction to Spectroscopy
Appl. Catal. A Jiang 209 59 2001 10.1016/S0926-860X(00)00755-9 Adsorption properties of cobalt and cobalt-manganese catalysts studied by in situ diffuse reflectance FTIR using CO and CO+H2 as probes

상세보기
J. Catal. Weststrate 342 1 2016 10.1016/j.jcat.2016.07.010 Spectroscopic insights into cobalt-catalyzed Fischer-Tropsch synthesis: a review of the carbon monoxide interaction with single crystalline surfaces of cobalt

상세보기
J. Catal. Morales 246 91 2007 10.1016/j.jcat.2006.11.014 Effects of manganese oxide promoter on the CO and H2 adsorption properties of titania-supported cobalt Fischer-Tropsch catalysts

상세보기
J. Mol. Catal. A Chem. Das 350 75 2011 10.1016/j.molcata.2011.09.008 Synthesis, characterization and in situ DRIFTS during the CO2 hydrogenation reaction over supported cobalt catalysts

상세보기
ACS Catal. Lukashuk 8 8630 2018 10.1021/acscatal.8b01237 Operando insights into CO oxidation on cobalt oxide catalysts by NAP-XPS, FTIR, and XRD

상세보기
Davydov 2003 Molecular Spectroscopy of Oxide Catalyst Surfaces
ACS Catal. Johnson 5 5888 2015 10.1021/acscatal.5b01578 An Investigation into the effects of Mn promotion on the activity and selectivity of Co/SiO2 for Fischer-Tropsch synthesis: evidence for enhanced CO adsorption and dissociation

상세보기
Appl. Energy Gradisher 139 335 2015 10.1016/j.apenergy.2014.10.080 Catalytic hydrogen production from fossil fuels via the water gas shift reaction

상세보기
ACS Catal. Yao 9 5957 2019 10.1021/acscatal.9b01150 Quantitative determination of C-C coupling mechanisms and detailed analyses on the activity and selectivity for Fischer-Tropsch synthesis on Co(0001): microkinetic modeling with coverage effects

상세보기
ACS Catal. Liu 9 7073 2019 10.1021/acscatal.9b00352 Insight into the intrinsic active site for selective production of light olefins in cobalt-catalyzed Fischer-Tropsch synthesis

상세보기
J. Am. Chem. Soc. Liu 135 16284 2013 10.1021/ja408521w Crystallographic dependence of CO activation on cobalt catalysts: HCP versus FCC

상세보기
J. Phys. Chem. C Yu 124 11040 2020 10.1021/acs.jpcc.0c02537 Rediscovering tuning product selectivity by an energy descriptor: CH4 formation and C1-C1 coupling on the FCC Co surface

상세보기
ChemCatChem Rodemerck 5 1948 2013 10.1002/cctc.201200879 Catalyst development for CO2 hydrogenation to fuels

상세보기
ACS Catal. Mohandas 1 1581 2011 10.1021/cs200236q Fischer-Tropsch synthesis: characterization and reaction testing of cobalt carbide

상세보기
Catal. Lett. Blanchard 2 319 1989 10.1007/BF00770230 Cobalt catalysts for the production of alcohols in the F.T. synthesis

상세보기
Appl. Catal. A Gnanamani 499 39 2015 10.1016/j.apcata.2015.03.046 Fischer-Tropsch synthesis: effect of pretreatment conditions of cobalt on activity and selectivity for hydrogenation of carbon dioxide

상세보기
J. Am. Chem. Soc. Tsakoumis 139 3706 2017 10.1021/jacs.6b11872 Evaluation of reoxidation thresholds for γ-Al2O3-supported cobalt catalysts under Fischer-Tropsch synthesis conditions

상세보기

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