[논문]Large-scale pattern growth of graphene films for stretchable transparent electrodes

Kim, Keun Soo; Zhao, Yue; Jang, Houk; Lee, Sang Yoon; Kim, Jong Min; Kim, Kwang S.; Ahn, Jong-Hyun; Kim, Philip; Choi, Jae-Young; Hong, Byung Hee

doi:10.1038/nature07719

Large-scale pattern growth of graphene films for stretchable transparent electrodes

Nature, v.457 no.7230 = no.7230, 2009년, pp.706 - 710

Kim, Keun Soo ([1] Department of Chemistry, [2] SKKU Advanced Institute of Nanotechnology, [3] Center for Nanotubes and Nanostructured Composites, Sungkyunkwan University, Suwon 440-746, Korea) , Zhao, Yue (Department of Physics, Columbia University, New York, New York 10027, USA) , Jang, Houk (School of Advanced Materials Science and Engineering,) , Lee, Sang Yoon (Samsung Advanced Institute of Technology, PO Box 111, Suwon 440-600, Korea) , Kim, Jong Min (Samsung Advanced Institute of Technology, PO Box 111, Suwon 440-600, Korea) , Kim, Kwang S. (Department of Chemistry, Pohang University of Science and Technology, Pohang 790-784, Korea) , Ahn, Jong-Hyun ([1] School of Advanced Materials Science and Engineering, [2] SKKU Advanced Institute of Nanotechnology,) , Kim, Philip ([1] SKKU Advanced Institute of Nanotechnology, [2] Department of Physics, Columbia University, New York, New York 10027, USA) , Choi, Jae-Young (Samsung Advanced Institute of Technology, PO Box 111, Suwon 440-600, Korea) , Hong, Byung Hee ([1] Department of Chemistry, [2] SKKU Advanced Institute of Nanotechnology, [3] Center for Nanotubes and Nanostructured Composite)

Abstract ▼ AI-Helper

Problems associated with large-scale pattern growth of graphene constitute one of the main obstacles to using this material in device applications. Recently, macroscopic-scale graphene films were prepared by two-dimensional assembly of graphene sheets chemically derived from graphite crystals and graphene oxides. However, the sheet resistance of these films was found to be much larger than theoretically expected values. Here we report the direct synthesis of large-scale graphene films using chemical vapour deposition on thin nickel layers, and present two different methods of patterning the films and transferring them to arbitrary substrates. The transferred graphene films show very low sheet resistance of ∼280 Ω per square, with ∼80 per cent optical transparency. At low temperatures, the monolayers transferred to silicon dioxide substrates show electron mobility greater than 3,700 cm2 V-1 s-1 and exhibit the half-integer quantum Hall effect, implying that the quality of graphene grown by chemical vapour deposition is as high as mechanically cleaved graphene. Employing the outstanding mechanical properties of graphene, we also demonstrate the macroscopic use of these highly conducting and transparent electrodes in flexible, stretchable, foldable electronics.

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Large-scale pattern growth of graphene films for stretchable transparent electrodes

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Large-scale pattern growth of graphene films for stretchable transparent electrodes

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