[논문]Atomically dispersed nickel–nitrogen–sulfur species anchored on porous carbon nanosheets for efficient water oxidation

Hou, Yang; Qiu, Ming; Kim, Min Gyu; Liu, Pan; Nam, Gyutae; Zhang, Tao; Zhuang, Xiaodong; Yang, Bin; Cho, Jaephil; Chen, Mingwei; Yuan, Chris; Lei, Lecheng; Feng, Xinliang

doi:10.1038/s41467-019-09394-5

[해외논문] Atomically dispersed nickel–nitrogen–sulfur species anchored on porous carbon nanosheets for efficient water oxidation 원문보기

Nature communications, v.10 no.1, 2019년, pp.1392 -

Hou, Yang (Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, 310027 Hangzhou, China) , Qiu, Ming (Institute of Nanoscience and Nanotechnology, College of Physical Science and Technology, Central China Normal University, 430079 Wuhan, China) , Kim, Min Gyu (Beamline Division, Pohang Accelerator Laboratory, Pohang, Kyungbuk 37673 Republic of Korea) , Liu, Pan (WPI Advanced Institute for Materials Research, Tohoku University, Sendai, 980-8577 Japan) , Nam, Gyutae (Department of Energy Engineering, School of Energy and Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 44919 Republic of Korea) , Zhang, Tao (Center for Advancing Electronics Dresden (cfaed) & Department of Chemistry and Food Chemistry, Technische Universitaet Dresden, 01062 Dresden, Germany) , Zhuang, Xiaodong (Center for Advancing Electronics Dresden (cfaed) & Department of Chemistry and Food Chemistry, Technische Universitaet Dresden, 01062 Dresden, Germany) , Yang, Bin (Key Laboratory of Biomass Che) , Cho, Jaephil , Chen, Mingwei , Yuan, Chris , Lei, Lecheng , Feng, Xinliang

Abstract ▼ AI-Helper

Developing low-cost electrocatalysts to replace precious Ir-based materials is key for oxygen evolution reaction (OER). Here, we report atomically dispersed nickel coordinated with nitrogen and sulfur species in porous carbon nanosheets as an electrocatalyst exhibiting excellent activity and durability for OER with a low overpotential of 1.51 V at 10 mA cm−2 and a small Tafel slope of 45 mV dec−1 in alkaline media. Such electrocatalyst represents the best among all reported transition metal- and/or heteroatom-doped carbon electrocatalysts and is even superior to benchmark Ir/C. Theoretical and experimental results demonstrate that the well-dispersed molecular S|NiNx species act as active sites for catalyzing OER. The atomic structure of S|NiNx centers in the carbon matrix is clearly disclosed by aberration-corrected scanning transmission electron microscopy and synchrotron radiation X-ray absorption spectroscopy together with computational simulations. An integrated photoanode of nanocarbon on a Fe2O3 nanosheet array enables highly active solar-driven oxygen production.Water oxidation is considered the bottleneck reaction for light-driven water splitting due to the sluggish kinetics and poor stability. Here, authors show metal- and heteroatom-doped carbons as effective catalysts for both electrochemical and photoelectrochemical water splitting.

참고문헌 (60)

1. Sivula K Van de Krol R Semiconducting materials for photoelectrochemical energy conversion Nat. Rev. Mater. 2016 1 15010 10.1038/natrevmats.2015.10

상세보기
2. Roger I Shipman MA Symes MD Earth-abundant catalysts for electrochemical and photoelectrochemical water splitting Nat. Rev. Chem. 2017 1 0003 10.1038/s41570-016-0003

상세보기
3. Liu X Dai L Carbon-based metal-free catalysts Nat. Rev. Mater. 2016 1 16064 10.1038/natrevmats.2016.64

상세보기
4. Nellist MR Laskowski FAL Lin F Mills TJ Boettcher SW Semiconductor–electrocatalyst interfaces: theory, experiment, and applications in photoelectrochemical water splitting ACC Chem. Res. 2016 49 733 740 10.1021/acs.accounts.6b00001 27035051

상세보기
5. Yang J Wang D Han H Li C Roles of cocatalysts in photocatalysis and photoelectrocatalysis ACC Chem. Res. 2013 46 1900 1909 10.1021/ar300227e 23530781

상세보기
6. Meng F Zhong H Bao D Yan J Zhang X In situ coupling of strung Co 4 N and intertwined N-C fibers toward free-standing bifunctional cathode for robust, efficient, and flexible Zn-Air batteries J. Am. Chem. Soc. 2016 138 10226 10231 10.1021/jacs.6b05046 27463122

상세보기
7. Hunter BM Gray HB Müller AM Earth-abundant heterogeneous water oxidation catalysts Chem. Rev. 2016 116 14120 14136 10.1021/acs.chemrev.6b00398 27797490

상세보기
8. Kanan MW Nocera DG In situ formation of an oxygen-evolving catalyst in neutral water containing phosphate and Co 2+ Science 2008 321 1072 1075 10.1126/science.1162018 18669820

상세보기
9. Luo J Water photolysis at 12.3% efficiency via perovskite photovoltaics and earth-abundant catalysts Science 2014 345 1593 1596 10.1126/science.1258307 25258076

상세보기
10. Suntivich J May KJ Gasteiger HA Goodenough JB Shao-Horn Y A perovskite oxide optimized for oxygen evolution catalysis from molecular orbital principles Science 2011 334 1383 1385 10.1126/science.1212858 22033519

상세보기
11. Zhou H Highly active catalyst derived from a 3D foam of Fe(PO 3 ) 2 /Ni 2 P for extremely efficient water oxidation Proc. Natl Acad. Sci. U.S.A. 2017 114 5607 5611 10.1073/pnas.1701562114 28507120

상세보기
12. Walter C A molecular approach to manganese nitride acting as a high performance electrocatalyst in the oxygen evolution reaction Angew. Chem. Int. Ed. 2018 57 698 702 10.1002/anie.201710460

상세보기
13. Zhao B A tailored double perovskite nanofiber catalyst enables ultrafast oxygen evolution Nat. Commun. 2017 8 14586 10.1038/ncomms14586 28240282

상세보기
14. Ng JWD Gold-supported cerium-doped NiO x catalysts for water oxidation Nat. Energy 2016 1 16053 10.1038/nenergy.2016.53

상세보기
15. Chen L Dong X Wang Y Xia Y Separating hydrogen and oxygen evolution in alkaline water electrolysis using nickel hydroxide Nat. Commun. 2016 7 11741 10.1038/ncomms11741 27199009

상세보기
16. Cao J An ultrathin cobalt-based zeolitic imidazolate framework nanosheet array with a strong synergistic effect towards the efficient oxygen evolution reaction J. Mater. Chem. A 2018 6 18877 18883 10.1039/C8TA08337A

상세보기
17. Liu R Liang F Zhou W Yang Y Zhu Z Calcium-doped lanthanum nickelate layered perovskite and nickel oxide nano-hybrid for highly efficient water oxidation Nano Energy 2015 12 115 122 10.1016/j.nanoen.2014.12.025

상세보기
18. Seh ZW Combining theory and experiment in electrocatalysis: Insights into materials design Science 2017 355 eaad4998 10.1126/science.aad4998 28082532

상세보기
19. Hou Y Efficient electrochemical and photoelectrochemical water splitting by a 3D nanostructured carbon supported on flexible exfoliated graphene foil Adv. Mater. 2017 29 1604480 10.1002/adma.201604480

상세보기
20. Zhang J Zhao Z Xia Z Dai L A metal-free bifunctional electrocatalyst for oxygen reduction and oxygen evolution reactions Nat. Nanotechnol. 2015 10 444 10.1038/nnano.2015.48 25849787

상세보기
21. Fei H General synthesis and definitive structural identification of MN 4 C 4 single-atom catalysts with tunable electrocatalytic activities Nat. Catal. 2018 1 63 72 10.1038/s41929-017-0008-y

상세보기
22. Han Y Wu Y Lai W Cao R Electrocatalytic water oxidation by a water-soluble nickel porphyrin complex at neutral pH with low overpotential Inorg. Chem. 2015 54 5604 5613 10.1021/acs.inorgchem.5b00924 25985258

상세보기
23. Shearer J How does cyanide inhibit superoxide reductase? Insight from synthetic FeIIIN4S model complexes Proc. Natl Acad. Sci. U.S.A. 2003 100 3671 3676 10.1073/pnas.0637029100 12655068

상세보기
24. Yang TC Comparing the electronic properties of the low-spin cyano-ferric [Fe(N 4 )(Cys)] active sites of superoxide reductase and p450cam using ENDOR spectroscopy and DFT calculations J. Am. Chem. Soc. 2006 128 16566 16578 10.1021/ja064656p 17177406

상세보기
25. Stiebritz MT Reiher M A unifying structural and electronic concept for hmd and [FeFe] hydrogenase active sites Inorg. Chem. 2010 49 5818 5823 10.1021/ic902529c 20527808

상세보기
26. Kulkarni A Siahrostami S Patel A Nørskov JK Understanding catalytic activity trends in the oxygen reduction reaction Chem. Rev. 2018 118 2302 2312 10.1021/acs.chemrev.7b00488 29405702

상세보기
27. Cabán-Acevedo M Efficient hydrogen evolution catalysis using ternary pyrite-type cobalt phosphosulphide Nat. Mater. 2015 14 1245 10.1038/nmat4410 26366849

상세보기
28. Hou Y Metal−organic framework-derived nitrogen-doped core-shell-structured porous Fe/Fe 3 C@C nanoboxes supported on graphene sheets for efficient oxygen reduction reactions Adv. Energy Mater. 2014 4 1400337 10.1002/aenm.201400337

상세보기
29. Lei C Efficient alkaline hydrogen evolution on atomically dispersed Ni–N x species anchored porous carbon with embedded Ni nanoparticles by accelerating water dissociation kinetics Energy Environ. Sci. 2019 12 149 156 10.1039/C8EE01841C

상세보기
30. Hou Y An advanced nitrogen-doped graphene/cobalt-embedded porous carbon polyhedron hybrid for efficient catalysis of oxygen reduction and water splitting Adv. Funct. Mater. 2015 25 872 882 10.1002/adfm.201403657

상세보기
31. Yin J Ni-C-N nanosheets as catalyst for hydrogen evolution reaction J. Am. Chem. Soc. 2016 138 14546 14549 10.1021/jacs.6b09351 27775881

상세보기
32. Yang HB Identification of catalytic sites for oxygen reduction and oxygen evolution in N-doped graphene materials: Development of highly efficient metal-free bifunctional electrocatalyst Sci. Adv. 2016 2 e1501122 10.1126/sciadv.1501122 27152333

상세보기
33. Hu W CoNi 2 S 4 nanosheet arrays supported on nickel foams with ultrahigh capacitance for aqueous asymmetric supercapacitor applications ACS Appl. Mater. Interfaces 2014 6 19318 19326 10.1021/am5053784 25322454

상세보기
34. Kannan AG Zhao J Jo SG Kang YS Kim DW Nitrogen and sulfur co-doped graphene counter electrodes with synergistically enhanced performance for dye-sensitized solar cells J. Mater. Chem. A 2014 2 12232 12239 10.1039/C4TA01927J

상세보기
35. Hou Y Zuo F Dagg A Feng P A three-dimensional branched cobalt-doped α-Fe 2 O 3 nanorod/MgFe 2 O 4 heterojunction array as a flexible photoanode for efficient photoelectrochemical water oxidation Angew. Chem. Int. Ed. 2013 52 1248 1252 10.1002/anie.201207578

상세보기
36. Liang HW Molecular metal–N x centres in porous carbon for electrocatalytic hydrogen evolution Nat. Commun. 2015 6 7992 10.1038/ncomms8992 26250525

상세보기
37. Lei C Fe–N 4 sites embedded into carbon nanofiber integrated with electrochemically exfoliated graphene for oxygen evolution in acidic medium Adv. Energy Mater. 2018 8 1801912 10.1002/aenm.201801912

상세보기
38. Yan C Coordinatively unsaturated nickel-nitrogen sites towards selective and high-rate CO 2 electroreduction Energy Environ. Sci. 2018 11 1204 1210 10.1039/C8EE00133B

상세보기
39. Yang HB Atomically dispersed Ni (I) as the active site for electrochemical CO 2 reduction Nat. Energy 2018 3 140 147 10.1038/s41560-017-0078-8

상세보기
40. Zhao Z Li M Zhang L Dai L Xia Z Design principles for heteroatom-doped carbon nanomaterials as highly efficient catalysts for fuel cells and metal-air batteries Adv. Mater. 2015 27 6834 6840 10.1002/adma.201503211 26418520

상세보기
41. Jiao Y Zheng Y Davey K Qiao SZ Activity origin and catalyst design principles for electrocatalytic hydrogen evolution on heteroatom-doped graphene Nat. Energy 2016 1 16130 10.1038/nenergy.2016.130

상세보기
42. Lee DH Lee WJ Lee WJ Kim SO Kim YH Theory, synthesis, and oxygen reduction catalysis of Fe-porphyrin-like carbon nanotube Phys. Rev. Lett. 2011 106 175502 10.1103/PhysRevLett.106.175502 21635045

상세보기
43. Shinde SS Scalable 3-D carbon nitride sponge as an efficient metal-free bifunctional oxygen electrocatalyst for eechargeable Zn-Air batteries ACS Nano 2017 11 347 357 10.1021/acsnano.6b05914 28001038

상세보기
44. Pham TA Ping Y Galli G Modelling heterogeneous interfaces for solar water splitting Nat. Mater. 2017 16 401 10.1038/nmat4803 28068314

상세보기
45. Vijselaar W Spatial decoupling of light absorption and catalytic activity of Ni-Mo-loaded high-aspect-ratio silicon microwire photocathodes Nat. Energy 2018 3 185 192 10.1038/s41560-017-0068-x

상세보기
46. Hou Y Zuo F Dagg AP Liu J Feng P Branched WO 3 nanosheet array with layered C 3 N 4 heterojunctions and CoO x nanoparticles as a flexible photoanode for efficient photoelectrochemical water oxidation Adv. Mater. 2014 26 5043 5049 10.1002/adma.201401032 24848321

상세보기
47. Cho IS Codoping titanium dioxide nanowires with tungsten and carbon for enhanced photoelectrochemical performance Nat. Commun. 2013 4 1723 10.1038/ncomms2729 23591890

상세보기
48. Rao PM Simultaneously efficient light absorption and charge separation in WO 3 /BiVO 4 core/shell nanowire photoanode for photoelectrochemical water oxidation Nano Lett. 2014 14 1099 1105 10.1021/nl500022z 24437363

상세보기
49. Huang JW Zhang Y Ding Y Rationally designed/constructed CoO x /WO 3 anode for efficient photoelectrochemical water oxidation ACS Catal. 2017 7 1841 1845 10.1021/acscatal.7b00022

상세보기
50. Abdi FF Efficient solar water splitting by enhanced charge separation in a bismuth vanadate-silicon tandem photoelectrode Nat. Commun. 2013 4 2195 10.1038/ncomms3195 23893238

상세보기
51. Kim TW Choi KS Nanoporous BiVO 4 photoanodes with dual-layer oxygen evolution catalysts for solar water splitting Science 2014 343 990 994 10.1126/science.1246913 24526312

상세보기
52. Shi X Epitaxial growth of WO 3 nanoneedles achieved using a facile flame surface treatment process engineering of hole transport and water oxidation reactivity J. Mater. Chem. A 2018 6 19542 19546 10.1039/C8TA04081H

상세보기
53. Ma M Dual oxygen and tungsten vacancies on a WO 3 photoanode for enhanced water oxidation Angew. Chem. Int. Ed. 2016 55 11819 11823 10.1002/anie.201605247

상세보기
54. Shi X Efficient photoelectrochemical hydrogen production from bismuth vanadate-decorated tungsten trioxide helix nanostructures Nat. Commun. 2014 5 4775 10.1038/ncomms5775 25179126

상세보기
55. Jin B Solution-processed yolk-shell-shaped WO 3 /BiVO 4 heterojunction photoelectrodes for efficient solar water splitting J. Mater. Chem. A 2018 6 2585 2592 10.1039/C7TA08452H

상세보기
56. Grigioni I Corti A Dozzi MV Selli E Photoactivity and stability of WO 3 /BiVO 4 photoanodes: effects of the contact electrolyte and of Ni/Fe oxyhydroxide protection J. Phys. Chem. C. 2018 122 13969 13978 10.1021/acs.jpcc.8b01112

상세보기
57. Hou Y Integrated hierarchical cobalt sulfide/nickel selenide hybrid nanosheets as an efficient three-dimensional electrode for electrochemical and photoelectrochemical water splitting Nano Lett. 2017 17 4202 4209 10.1021/acs.nanolett.7b01030 28586217

상세보기
58. Chang X Enhanced surface reaction kinetics and charge separation of p-n heterojunction Co 3 O 4 /BiVO 4 photoanodes J. Am. Chem. Soc. 2015 137 8356 8359 10.1021/jacs.5b04186 26091246

상세보기
59. Hou Y Vertically oriented cobalt selenide/NiFe layered-double-hydroxide nanosheets supported on exfoliated graphene foil: an efficient 3D electrode for overall water splitting Energy Environ. Sci. 2016 9 478 483 10.1039/C5EE03440J

상세보기
60. Gao MR An efficient molybdenum disulfide/cobalt diselenide hybrid catalyst for electrochemical hydrogen generation Nat. Commun. 2015 6 5982 10.1038/ncomms6982 25585911

상세보기

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