[논문]GC-MS법을 이용한 울금의 퇴화물 분석

안춘순

doi:10.5850/jksct.2007.31.6.859

GC-MS법을 이용한 울금의 퇴화물 분석
Analysis of the Degradation Products of Turmeric using GC-MS 원문보기

한국의류학회지 = Journal of the Korean Society of Clothing and Textiles, v.31 no.6 = no.165, 2007년, pp.859 - 868

초록
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퇴색된 출토복식의 염료를 판정하기 위한 장기적인 프로젝트의 일환으로서 본 연구에서는 울금뿌리로부터 추출한 염료와 추출염료로 염색한 직물을 실험실 조건에서 28일간 퇴화시킨 후 그로부터 생성되는 퇴화 화합물을 가스 크로마토그라피 질량분석법(GC-MS)을 이용해 분석하였다. 2-propenoic acid, 3-(2-hydroxyphenyl)-는 오븐 퇴화시킨 울금추출액 전체에서 지속적으로 검출되었으며, 그 양은 7일 퇴화시료 까지 급격히 감소하다가 그 후 28일까지는 서서히 평형을 유지하였다 울금추출액의 오븐 퇴화 결과 위의 다섯 개 화합물 외에 isovanillin과 vanillic acid가 새롭게 검출되었다. 28일간 퇴화시킨 PER시료에서는 isovanillin과 그 외에 feruloylmethane, 2-propenoic acid, 3-(2-hydroxyphenyl)-, benzoic acid, and vanillic acid가 검출되었다. 울금추출액으로 염색한 직물로부터는 feruloylmethane과 2-propenoic acid, 3-(2-hydroxyphenyl)-가 퇴화물로 검출되었다. PER 방법에서 검출된 isovanillin과 feruloylmethane, 2-propenoic acid, 3-(2-hydroxyphenyl)-, benzoic acid, vanillic acid등은 출토복식 중 울금으로 염색된 직물을 확인하는 데 주요한 대조구 화합물로 사용될 수 있을 것으로 사료된다.

Abstract ▼ AI-Helper

Degradation products of the dye extracted from turmeric and the turmeric dyed textiles were examined by using GC-MS after 100 oven (OV) and $H_2O_2/UV/O_2$(PER) treatments for up to 28 days. Throughout the OV degradation times, 2-propenoic acid, 3-(2-hydroxyphenyl)- was found consistently, while isovanillin, and vanillic acid were newly detected. In 28 day PER degradation sample, feruloylmethane, 2-propenoic acid, 3-(2-hydroxyphenyl)-, benzoic acid, and vanillic acid were detected as well as isovanillin. Feruloylrnethane, and 2-propenoic acid, 3-(2-hydroxyphenyl)- were detected from the degraded fabric samples. With the absence of curcuminoids in the GC-MS result, the decreasing pattern of 2-propenoic acid, 3-(2-hydrokyphenyl)- reflect the degradation of curcuminoids in turmeric extraction with the progression of OV degradation times. It is suggested that isovanillin, feruloylmethane, 2-propenoic acid,3-(2-hydroxyphenyl)-, and vanillic acid are the probable fingerprint products for determining the turmeric dye from the badly faded archaeological textiles.

주제어

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문제 정의

, 1998). The purpose of the present research was to examine the degradation products of the dye extracted from the rhizome of turmeric after selective degradation treatments.

제안 방법

Liquid dye and the dye component extracted from the turmeric dyed textiles were both analyzed using the gas chromatography mass spectrometry(denoted 'GC-MS' in the following). Thermal treatment in 100℃ oven and H₂O₂/UV/O₂ (denoted 'PER' in the following) treatments were utilized for the degradation experiment.
Each sample was labeled for different degradation treatment and time. The thermal degradation samples were placed in a 100℃ oven for the thermal treatment for 2, 7, 14, 21, and 28 days. Control sample without the oven treatment was also prepared.

대상 데이터

(1996). Among the products detected in this research in either the control or degraded samples, zingiberene, dihydrocurcumene, benzene, 1 -(3-cyclopentylpropyl)-2, 4, and 2-prope- noic acid, 3-(2-hydroxyphenyl)-, not to mention curcumene itself, all have the base structure resembling or identical to curcumene backbone with the most common ion fragment occurring at m/z 119(Table 2). Therefore, it is safe to say that these six products are the fragmentation of curcuminoids in turmeric extract in the present investigation.
Dried rhizomes of turmeric were purchased from Korean traditional medicinal market. Methanol(HPL(2 grade) was purchased from Acros Organics(NJ), 30% H₂02(ACS reagent grade) was purchased from J.T. Baker(Phillipsburg, NJ). Reagent grade HC₁ was purchased from EM Science(Darmstadt, NJ).
Samples were analyzed on the Hewlett-Packard GC 6890 Series coupled to the Agilent Technologies 5973N MSD system. Front inlet was kept at splitless mode with initial temperature at 250℃.

후속연구

When gas chromatography(GC) is coupled with mass spectrometry(MS), the instrument becomes a powerful tool for separating and identifying the degradation products(Zhang & Lemley, 2006). By utilizing the two degradation treatments and the GC-MS analysis, the result of this study will become part of the cumulative collection of analytical data which can then be used as the fingerprint for the identification of turmeric dye in badly faded archaeological textiles. An example of such approach can be found in the previous research by the author which identified alizarin from the exhumed textile(Ahn, 2003).

참고문헌 (22)

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