단청, 불화, 벽화 등에 사용된 전통 무기질 안료는 대부분 광물이었으나, 근현대에 저렴한 화학안료로 대체되어 광물안료 제조법의 맥이 끊어졌다. 이 연구에서는 문화재 보존에 필요한 전통 광물안료 중 녹색-청색 계열 안료자원의 국내 산출과 광물학적 특성을 규명하고자 하였다. 구리를 함유한 녹색 - 청색 안료광물들은 구리-납-아연을 채굴하는 금속광산의 폐석장이나 갱내 풍화대에서 이차광물로 산출되었다. X선회절과 주사전자현미경 분석을 이용하여 광물동정을 실시한 결과, 녹색은 brochantite, devilline, 청색은 linarite, bechererite, schulenbergite 등의 함수구리황산염이 대표적인 발색광물이었으며, 그 외 소량의 녹색 antlerite, atacamite가 확인되었다. 이들 녹색-청색 안료광물과 함께 cerussite, smithsonite, anglesite, cuprite 등이 이차광물로 흔히 수반되었다. 녹색 규산염 안료인 뇌록은 현무암 파쇄대의 교대산물로 산출되며, 주발색광물인 celadonite 외에 단백석이 다양한 비율로 혼재되어 있었다. 녹색 규산염 안료인 해록석은 사질 서해 퇴적물 내에서 산출이 확인되었다. 이번 조사에서 대표적인 구리계열 녹색-청색 전통안료로 알려진 공작석과 남동석의 산출을 확인할 수 없었다.
단청, 불화, 벽화 등에 사용된 전통 무기질 안료는 대부분 광물이었으나, 근현대에 저렴한 화학안료로 대체되어 광물안료 제조법의 맥이 끊어졌다. 이 연구에서는 문화재 보존에 필요한 전통 광물안료 중 녹색-청색 계열 안료자원의 국내 산출과 광물학적 특성을 규명하고자 하였다. 구리를 함유한 녹색 - 청색 안료광물들은 구리-납-아연을 채굴하는 금속광산의 폐석장이나 갱내 풍화대에서 이차광물로 산출되었다. X선회절과 주사전자현미경 분석을 이용하여 광물동정을 실시한 결과, 녹색은 brochantite, devilline, 청색은 linarite, bechererite, schulenbergite 등의 함수구리황산염이 대표적인 발색광물이었으며, 그 외 소량의 녹색 antlerite, atacamite가 확인되었다. 이들 녹색-청색 안료광물과 함께 cerussite, smithsonite, anglesite, cuprite 등이 이차광물로 흔히 수반되었다. 녹색 규산염 안료인 뇌록은 현무암 파쇄대의 교대산물로 산출되며, 주발색광물인 celadonite 외에 단백석이 다양한 비율로 혼재되어 있었다. 녹색 규산염 안료인 해록석은 사질 서해 퇴적물 내에서 산출이 확인되었다. 이번 조사에서 대표적인 구리계열 녹색-청색 전통안료로 알려진 공작석과 남동석의 산출을 확인할 수 없었다.
Traditional inorganic pigments applied to dancheong, buddhist painting, and wall painting were produced from natural minerals which were later replaced by synthetic pigments, resulting in the loss of the recipe to prepare mineral pigments. This study examined the domestic occurrence and mineralogica...
Traditional inorganic pigments applied to dancheong, buddhist painting, and wall painting were produced from natural minerals which were later replaced by synthetic pigments, resulting in the loss of the recipe to prepare mineral pigments. This study examined the domestic occurrence and mineralogical characteristics of green and blue mineral pigments required for the conservation of cultural heritage. Cuprous green-blue mineral pigments were found as the weathering products of waste dumps and ores of abandoned Cu-Pb-Zn sulfide mines. Mineralogical analyses using X-ray diffraction and scanning electron microscopy identified diverse hydrous copper sulfate pigments of green (brochantite and devilline) and blue color (linarite, bechererite, and schulenbergite) with minor green pigments of antlerite and atacamite commonly associated with cerussite, smithsonite, anglesite, and cuprite. Noerok, a green silicate pigment, replaced the fractured basalt lava. Celadonite was responsible for the green color of Noerok, closely associated with opal in varying ratio. Glauconite, green silicate pigment, was identified in the Yellow Sea sediments. Malachite and azurite, the most important green and blue pigments of Korean cultural heritage, were not identified in this study.
Traditional inorganic pigments applied to dancheong, buddhist painting, and wall painting were produced from natural minerals which were later replaced by synthetic pigments, resulting in the loss of the recipe to prepare mineral pigments. This study examined the domestic occurrence and mineralogical characteristics of green and blue mineral pigments required for the conservation of cultural heritage. Cuprous green-blue mineral pigments were found as the weathering products of waste dumps and ores of abandoned Cu-Pb-Zn sulfide mines. Mineralogical analyses using X-ray diffraction and scanning electron microscopy identified diverse hydrous copper sulfate pigments of green (brochantite and devilline) and blue color (linarite, bechererite, and schulenbergite) with minor green pigments of antlerite and atacamite commonly associated with cerussite, smithsonite, anglesite, and cuprite. Noerok, a green silicate pigment, replaced the fractured basalt lava. Celadonite was responsible for the green color of Noerok, closely associated with opal in varying ratio. Glauconite, green silicate pigment, was identified in the Yellow Sea sediments. Malachite and azurite, the most important green and blue pigments of Korean cultural heritage, were not identified in this study.
IXRF 에너지분산X-선분석(EDS) 분광기가 부착된 TESCAN LMU VEGA 주사전자현미경을 이용하여 20 kV 100 µA 조건에서 후방산란전자(BSE)상 미세조직관찰과 각 광물의 정성화학조성을 분석하였다
XRD 분석은 40 kV의 가속전압과 30 mA의 전류에서 발생한 CuKα선을 사용하여 슬릿(slit) 조건 2/3°-0.3 mm-2/3°, 각도 범위3-65° (2θ), 계수간격 0.03°, 계수시간 2초의 조건에서 시행되었다
그러나 대부분의 분석용 분말의 양이 극히 작았고, 더구나미세하게 혼합된 상태에서는 색상별로 구분하여 준비하기 어려웠다. XRD 분석은 Rigaku사의 UltimaIV와 Bruker D8 Advance A25 XRD 기기를 이용하여 분석하였다. XRD 분석은 40 kV의 가속전압과 30 mA의 전류에서 발생한 CuKα선을 사용하여 슬릿(slit) 조건 2/3°-0.
03°, 계수시간 2초의 조건에서 시행되었다. 녹색 및 청색 광물 입자들의 미세 산출상태와 화학적 특성을 규명하기 위하여, 에폭시 처리한 시편으로부터 평탄한 연마편을 제작하여 탄소 코팅 후 주사전자현미경(SEM)으로 관찰하였다. IXRF 에너지분산X-선분석(EDS) 분광기가 부착된 TESCAN LMU VEGA 주사전자현미경을 이용하여 20 kV 100 µA 조건에서 후방산란전자(BSE)상 미세조직관찰과 각 광물의 정성화학조성을 분석하였다.
대상 데이터
가거도, 외연도와 진도 부근 해역(E125°3’42”-E125°10’10”/N34°0’12”-N34°2’48”)에서 2016년 채취한 표층퇴적물 시료를 해양과학기술원 남해연구소 해양시료도서관에서 받아 분석에 이용하였다(Fig
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