[논문]연료전지용 고분자 전해질 복합막의 최근 발전 동향

비자야레크쉬미 비자야쿠마르; 손태양; 남상용

doi:10.14478/ace.2018.1105

연료전지용 고분자 전해질 복합막의 최근 발전 동향
Recent Advances in Composite Polymer Electrolyte Membranes for Fuel Cell 원문보기

공업화학 = Applied chemistry for engineering, v.30 no.1, 2019년, pp.1 - 10

비자야레크쉬미 비자야쿠마르 (경상대학교 나노신소재융합공학과, 공학연구원) , 손태양 (경상대학교 나노신소재융합공학과, 공학연구원) , 남상용 (경상대학교 나노신소재융합공학과, 공학연구원)

Abstract ▼ AI-Helper

Composite polymer electrolyte membranes based on porous supports have been recognized as an alternative for fuel cell applications since it can provide both mechanical as well as electrochemical stabilities. This mini-review highlights recent advances in supported composite polymer electrolyte membranes using porous matrix and nanofibrous supports. In addition, a comprehensive table listing a wide range of anion and proton exchange pore filling membranes was provided at the end of the review.

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표/그림 (7)

그림 Figure 1. Synthetic schemes of (a) PAEK-OH and PAEK-b-PLA; (b)polymeric filler SPAEK (DS = 80%); and (c) preparation of pore filling composite membrane (Reproduced with permission from Elsevier).
그림 Figure 2. Schematic illustration of phase morphology and the relative humidity variation driven dimensional change of SN/S and S/S membranes(Reproduced with permission from Elsevier)[19].
그림 Figure 3. Comparison of dimensional change between SPAES, S/S and SN/S membranes with humidity cycling (repeated hydration-room temperature/100% RH/24 h and dehydration 80 ℃/50% RH/3 h)(Reproduced with permission from Elsevier)[19].
그림 Figure 4. Schematic structure of electro spun nano fiber enhanced SPPESK composite PEM (Reproduced with permission from Elsevier)[38].
그림 Figure 5. Schematic diagram of in-situ nano scale SF strategy(Reproduced with permission from Elsevier)[40].
표 Table 1. Summary of Composite Membranes
그림 Figure 6. (a) Schematic diagram of Nafion membrane with biofunctional SiO₂ nanofiber (cysteine) and (b) molecular structures of cysteine, serine, lysine and glycine (Reproduced with permission from Elsevier)[46].

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문제 정의

The main roles of the support in the composite polymer electrolyte are: (i) to reinforcing the membrane, which leads to better mechanical, dimensional and thermal stabilities and (ii) reduce the thickness of the membranes and improve ion conductivity. The purpose of this review is, to sum up the recent progress on PEMs based on pore filling and nanofibrous support composites.
Ionically conductive polymer gel with porous matrix or electrospun mat support may efficiently overcome the limitations associated with the state of the art perfluorosulfonic acid based membranes and enhance mechanical strength, conductivity, stability, selectivity and durability. This review gives an overview of various efforts that have been made during the last five years on porous supported polymer electrolyte membranes. Table 1 shows a summarized report on the work performed on various membranes.

참고문헌 (46)

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원문보기 상세보기
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