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고분자 전해질 막 연료전지 응용을 위한 고성능 과불소화계 전해질 막 개발 연구 동향
Research Trends on Developments of High-performance Perfluorinated Sulfonic Acid-based Polymer Electrolyte Membranes for Polymer Electrolyte Membrane Fuel Cell Applications 원문보기

멤브레인 = Membrane Journal, v.32 no.5, 2022년, pp.292 - 303  

최찬희 (경상국립대학교 나노신소재융합공학과) ,  황선수 (경상국립대학교 나노신소재융합공학과) ,  김기현 (경상국립대학교 나노신소재융합공학과)

초록
AI-Helper 아이콘AI-Helper

이산화탄소 배출이 없는 고분자 전해질 막 연료전지(polymer electrolyte membrane fuel cell, PEMFC)는 수송용, 발전용 시스템에 적용 가능한 친환경 에너지 변환장치이다. PEMFC의 주요 구성품 중 하나인 고분자 전해질 막(polymer electrolyte membrane, PEM)은 구동시간 동안의 높은 수소 이온 전도도와 물리화학적 안정성 갖춘 과불소화계 고분자(perfluorinated sulfonic acid, PFSA) 기반 PEM (PFSA-PEM)이 상용화 되어있다. 하지만 PFSA-PEM의 단점으로 지적되는 낮은 유리전이온도와 높은 기체 투과도의 보완이 요구되고 있다. 이에 본 총설에서는 PFSA-PEM의 성능 향상 및 단점 보완을 위해 1) PFSA의 측쇄부 길이를 조절함으로써 이온교환용량의 증가와 고분자의 결정성을 증가시켜 PFSA-PEM의 능력을 향상시킨 연구와 2) 유/무기 첨가제를 도입하여 수소 이온 전도도 및 물리적 안정성을 향상시키는 복합 막 연구 및 3) 다공성 지지체를 도입하여 PEM의 두께를 효과적으로 감소시켜 막 저항을 효과적으로 줄이고 내구성을 큰 폭으로 개선한 다공-충진막에 관한 연구를 소개하고자 한다.

Abstract ▼ AI-Helper 아이콘AI-Helper

An eco-friendly energy conversion device without the emission of pollutants has gained much attention due to the rapid use of fossil fuels inducing carbon dioxide emissions ever since the first industrial revolution in the 18th century. Polymer electrolyte membrane fuel cells (PEMFCs) that can produ...

주제어

#polymer electrolyte membrane fuel cell   #polymer electrolyte membrane   #perfluorinated sulfonic acid   #composite membrane   #pore-filling membrane  

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