[논문]연료전지용 MXenes의 등장

마노즈 카라코티; 남상용

doi:10.14478/ace.2023.1019

[국내논문] 연료전지용 MXenes의 등장
Emergence of MXenes for Fuel Cell 원문보기

공업화학 = Applied chemistry for engineering, v.34 no.2, 2023년, pp.99 - 105

마노즈 카라코티 (경상대학교 그린에너지융합기술연구소) , 남상용 (경상대학교 그린에너지융합기술연구소)

Abstract ▼ AI-Helper

Recently, 2D materials greatly impact in the various applications especially in the energy conversion and storage devices. Among the 2D materials, nowadays researchers are showing their propensity towards the MXenes due to their potential structural and physical properties as well as their use in various applications. Recently, MXenes have been used as filler in polymer electrolytes membranes and as catalytic support to increase the performance of fuel cells (FCs). But this review covers only recent progress and application of MXenes in proton and anion exchange membranes for FCs. Also, this review will provide a significant guidance and broad overview for future research in MXenes based polymer electrolyte membrane for FCs.

주제어

표/그림 (4)

그림 Figure 1. (a) MXenes (Reprint with the permission of Elsevier)[25], (b) MAX phases (Reprint with the permission of John Wiley and Sons)[31].
그림 Figure 2. Application of MXenes.
그림 Figure 3. The procedure for synthesis a hybrid membrane with MXene-CeO₂ coating (Reprint with the permission of American Chemical Society)[55].
그림 Figure 4. DSC curves of (a) Nafion-based membranes and (b) CS-based membranes. Stress-strain curves of (c) Nafion-based membranes and (d) CS-based membranes, (e) Single H₂/O₂ cell performances of Nafion-based membranes at 90 °C under humidified environment (80% RH) (Reprint with the permission of American Chemical Society)[58].

참고문헌 (65)

TRVST, https://www.trvst.world/renewable-energy/challenges-for-renewable-energy/, 12, Nov 2022.
C. Fan, P. Zhang, R. Wang, Y. Xu, X. Sun, J. Zhang, J. Cheng, and C. Xu, Applications of two dimensional material-mxene for proton exchange membrane fuel cells (PEMFCs) and water electrolysis, Curr. Nanosci., 17, 2-13 (2021).

상세보기
B. C. Steele and A. Heinzel, Materials for fuel-cell technologies, Nature, 414, 345-352 (2001).

상세보기
M. Wang, M. Chen, Z. Yang, G. Liu, J. K. Lee, W. Yang, and X. Wang, High-performance and durable cathode catalyst layer with hydrophobic C@ PTFE particles for low-Pt loading membrane assembly electrode of PEMFC, Energy Convers. Manage., 191, 132-140 (2019).

상세보기
F. M. Guangul, and G. T. Chala, A comparative study between the seven types of fuel cells, Appl. Sci. Eng. Prog., 13, 185-194 (2020).
G. He, Z. Li, J. Zhao, S. Wang, H. Wu, M. D. Guiver, and Z. Jiang, Nanostructured ion-exchange membranes for fuel cells: Recent advances and perspectives, Adv. Mater., 27, 5280-5295 (2015).

상세보기
M. Z. Jacobson, W. G. Colella, and D. M. Golden, Cleaning the air and improving health with hydrogen fuel-cell vehicles, Science, 308, 1901-1905 (2005).

상세보기
S. M. Haile; D. A. Boysen, C. R. I. Chisholm, and R. B. Merle, Solid acids as fuel cell electrolytes, Nature, 410, 910-913 (2001).

상세보기
M. R. Berber, M. S. Ismail, M. Pourkashanian, M. B. Zakaria Hegazy, and U. P. Apfel, Promising Membrane for polymer electrolyte fuel cells shows remarkable proton conduction over wide temperature and humidity ranges, ACS Appl. Polym. Mater., 3, 4275-4286 (2021).
G. Couture, A. Alaaeddine, F. Boschet, and B. Ameduri, Polymeric materials as anion-exchange membranes for alkaline fuel cells, Prog. Polym. Sci., 36, 1521-1557 (2011).

상세보기
Z. Sun and B. Lin, Applied Polymer MaterialsF. Yan, Anion-exchange membranes for alkaline fuel-cell applications: The effects of cations, ChemSusChem, 11, 58-70 (2018).

상세보기
M. Adamski, N. Peressin, and S. Holdcroft, On the evolution of sulfonated polyphenylenes as proton exchange membranes for fuel cells, Mater. Adv., 2, 4966-5005 (2021).

상세보기
M. Sugumar, V. Kugarajah, and S. Dharmalingam, Optimization of operational factors using statistical design and analysis of nanofiller incorporated polymer electrolyte membrane towards performance enhancement of microbial fuel cell, Process Saf. Environ., 158, 474-485 (2022).
J. Y. Chu, K. H. Lee, A. R. Kim, and D. J. Yoo, Graphene-mediated organic-inorganic composites with improved hydroxide conductivity and outstanding alkaline stability for anion exchange membranes, Compos. B Eng., 164, 324-332 (2019).
R. Narducci, E. Sgreccia, P. Knauth, and M. L. Di Vona, Anion exchange membranes with 1D, 2D and 3D fillers: A review. Polymers, 13, 3887 (2021).

상세보기
V. Nicolosi, M. Chhowalla, M. G. Kanatzidis, M. S. Strano, and J. N. Coleman, Liquid exfoliation of layered materials, Science, 340, 1226419 (2013).

상세보기
G. Fiori, F. Bonaccorso, G. Iannaccone, T. Palacios, D. Neumaier, A. Seabaugh, S. K. Banerjee, and L. Colombo, Electronics based on two-dimensional materials, Nat. Nanotechnol., 9, 768-779 (2014).

상세보기
Y. Chen, H. Yang, Z. Han, Z. Bo, J. Yan, K. Cen, and K. K. Ostrikov, MXene-based electrodes for supercapacitor energy storage, Energy Fuels, 36, 2390-2406 (2022).

상세보기
F. Ming, H. Liang, G. Huang, Z. Bayhan, and H. N. Alshareef, MXenes for rechargeable batteries beyond the lithium-ion, Adv. Mater., 33, 2004039 (2021).
L. Yin, Y. Li, X. Yao, Y. Wang, L. Jia, Q. Liu, J. Li, Y. Li, and D. He, MXenes for solar cells, Nanomicro Lett., 13, 1-17 (2021).
Z. Yang, M. Zhang, Z. Zhao, W. Lan, X. Zhang, and M. Fan, Application of 2D nanomaterial MXene in anion exchange membranes for alkaline fuel cells: Improving ionic conductivity and power density, Int. J. Hydrog. Energy, 47, 18122-18138 (2022).

상세보기
L. Chen, X. Dai, W. Feng, and Y. Chen, Biomedical applications of MXenes: From nanomedicine to biomaterials. AMR, 3, 785-798 (2022).
M. Naguib, M. Kurtoglu, V. Presser, J. Lu, J. Niu, M. Heon, L. Hultman, Y. Gogotsi, and M. W. Barsoum, Two-dimensional nanocrystals produced by exfoliation of Ti 3 AlC 2 . Adv. Mater., 23, 4248-4253 (2011).

상세보기
Z. Zhang, Z. Cai, Y. Zhang, Y. Peng, Z. Wang, L. Xia, S. Ma, Z. Yin, R. Wang, Y. Cao, and Z. Li, The recent progress of MXene-Based microwave absorption materials, Carbon, 174, 484- 499 (2021).

상세보기
S. Bae, Y. G. Kang, M. Khazaei, K. Ohno, Y. H. Kim, M. J. Han, K. J. Chang, and H. Raebiger, Electronic and magnetic properties of carbide MXenes - the role of electron correlations, Mater. Today Adv., 9, 100118 (2021).
S. Kim, F. Gholamirad, M. Yu, C. M. Park, A. Jang, M. Jang, N. Taheri-Qazvini, and Y. Yoon, Enhanced adsorption performance for selected pharmaceutical compounds by sonicated Ti 3 C 2 T X MXene, Chem. Eng. J., 406, 126789 (2021).
M. Naguib, V. N. Mochalin, M. W. Barsoum, and Y. Gogotsi, 25th Anniversary Article: MXenes: A new family of two-dimensional materials, Adv. Mater., 2, 992-1005 (2014).
M. Naguib, O. Mashtalir, J. Carle, V. Presser, J. Lu L. Hultman, Y. Gogotsi, and M. W. Barsoum, Two-dimensional transition metal carbides. ACS Nano, 6, 1322-1331 (2012).

상세보기
A. D. Dillon, M. J. Ghidiu, A. L. Krick, J. Griggs, S. J. May, Y. Gogotsi, M. W. Barsoum, and A. T. Fafarman. Highly conductive optical quality solution-processed films of 2D titanium carbide, Adv. Funct. Mater., 26, 4162-4168 (2016).

상세보기
J. Zhang, N. Kong, S. Uzun, A. Levitt, S. Seyedin, P. A. Lynch, S. Qin, M. Han, W. Yang, and J. Liu, Scalable Manufacturing of Free Standing, Strong Ti3C2Tx MXene Films with Outstanding Conductivity, Adv. Mater., 32, 2001093 (2020).
Y. Fan, L. Li, Y. Zhang, X. Zhang, D. Geng, and W. Hu, Recent advances in growth of transition metal carbides and nitrides (MXenes) crystals, Adv. Funct. Mater., 32, 2111357 (2022).

상세보기
M. W. Barsoum, The MN+ 1AXN phases: A new class of solids: Thermodynamically stable nanolaminates. Prog. Solid State Chem., 28, 201-281 (2000).

상세보기
K. Hideo, K. Tsuzura, and H. Shimizu, Ion exchange membranes, in: K. Dorfner (Ed.), Ion Exchangers, Walter de Gruyter, Berlin (1991).
H. Strathmann, Electrodialysis and related processes. In: R. D. Noble and S. A. Stern (ed.). Membrane Science and Technology, 2, 213-281, Elsevier, Amsterdam, Netherlands (1995).
C. Felice and D. Qu, Optimization of the synthesis of Nafion-montmorillonite nanocomposite membranes for fuel cell applications through statistical design-of-experiment, Ind. Eng. Chem. Res., 50, 721-727 (2011).

상세보기
B. Smitha, S. Sridhar, and A. A. Khan, Solid polymer electrolyte membranes for fuel cell applications-A review, J. Membr. Sci., 259, 10-26 (2005).

상세보기
D.J. Kim, M. J. Jo, and S. Y. Nam, A review of polymer-nanocomposite electrolyte membranes for fuel cell application, J. Ind. Eng. Chem., 21, 36-52 (2015).

상세보기
B. P. Tripathi and V. K. Shahi, Organic-inorganic nanocomposite polymer electrolyte membranes for fuel cell applications, Prog. Polym. Sci., 36, 945-979 (2011).

상세보기
H. Ahmad, S. K. Kamarudin, U. A. Hasran, and W. W. Daud, Overview of hybrid membranes for direct-methanol fuel-cell applications, Int. J. Hydrog. Energy, 35, 2160-2175 (2010).

상세보기
R. Q. Fu, J. J. Woo, S. J. Seo, J. S. Lee, and S. H. Moon,. Covalent organic/inorganic hybrid proton-conductive membrane with semi-interpenetrating polymer network: Preparation and characterizations. J. Power Sources, 179, 458-466 (2008).

상세보기
B. P. Tripathi and V. K. Shahi, Surface redox polymerized SPEEK-MO2-PANI (M Si, Zr and Ti) composite polyelectrolyte membranes impervious to methanol, Colloids Surf. A Physicochem. Eng. Asp., 340, 10-19 (2009).

상세보기
P. Krishnan, J. S. Park, and C. S. Kim, Preparation of proton-conducting sulfonated poly (ether ether ketone)/boron phosphate composite membranes by an in situ sol-gel process, J. Membr. Sci., 279, 220-229 (2006).

상세보기
R. Kannan, P. P. Aher, T. Palaniselvam, S. Kurungot, U. K. Kharul, and V. K. Pillai, Artificially designed membranes using phosphonated multiwall carbon nanotube- polybenzimidazole composites for polymer electrolyte fuel cells, J. Phys. Chem. Lett., 1, 2109-2113 (2010).

상세보기
M. Helen, B. Viswanathan, and S. S. Murthy, Fabrication and properties of hybrid membranes based on salts of heteropolyacid, zirconium phosphate and polyvinyl alcohol, J. Power Sources, 163, 433-439 (2006).

상세보기
A. F. Ismail, N. H. Othman, and A. Mustafa, Sulfonated polyether ether ketone composite membrane using tungstosilicic acid supported on silica-aluminium oxide for direct methanol fuel cell (DMFC), J. Membr. Sci., 329, 18-29 (2009).

상세보기
R. Gosalawit, S. Chirachanchai, S. Shishatskiy, and S. P. Nunes, Sulfonated montmorillonite/sulfonated poly (ether etherketone)(SMMT/SPEEK) nanocomposite membrane for direct methanol fuel cells (DMFCs), J. Membr. Sci., 323, 337-346 (2008).

상세보기
A. Boretti and S. Castelletto, MXenes in polymer electrolyte membrane hydrogen fuel and electrolyzer cells, Ceramics Int., 48, 34190-34198 (2022).
Z. Zeng, R. Song, S. Zhang, X. Han, Z. Zhu, X. Chen, and L. Wang, Biomimetic N-doped graphene membrane for proton exchange membranes, Nano Lett., 21, 4314-4319 (2021).

상세보기
D. E. Curtin, R. D. Lousenberg, T. J. Henry, P. C. Tangeman, and M. E. Tisack, Advanced materials for improved PEMFC performance and life, J. Power Sources, 131, 41-48 (2004).

상세보기
C. Zhou, M. A. Guerra, Z. M. Qiu, T. A. Zawodzinski, and D. A. Schiraldi, Chemical durability studies of perfluorinated sulfonic acid polymers and model compounds under mimic fuel cell conditions, Macromolecules, 40, 8695-8707 (2007).

상세보기
M. Danilczuk, F. D. Coms, and S. Schlick, Fragmentation of Fluorinated Model Compounds Exposed to Oxygen Radicals: Spin Trapping ESR Experiments and Implications for the Behaviour of Proton Exchange Membranes Used in Fuel Cells, Fuel Cells, 8, 436-452 (2008).

상세보기
L. Gubler, H. Kuhn, T. J. Schmidt, G. G. Scherer, H. P. Brack, and K. Simbeck, Performance and durability of membrane electrode assemblies based on radiation-grafted FEP-g-polystyrene membranes, Fuel Cells, 4, 196-207 (2004).

상세보기
M. P. Rodgers, L. J. Bonville, H. R. Kunz, D. K. Slattery, and J. M. Fenton, Fuel cell perfluorinated sulfonic acid membrane degradation correlating accelerated stress testing and lifetime, Chem. Rev., 112, 6075-6103 (2012).

상세보기
A. Panchenko,H. Dilger, J. Kerres, M. Hein, A. Ullrich, T. Kaz, and E. Roduner, In-situ spin trap electron paramagnetic resonance study of fuel cell processes, Phys. Chem. Chem. Phys., 6, 2891-2894 (2004).

상세보기
S. Zhao, R. Wang, T. Tian, H. Liu, H. Zhang, and H. Tang, Self-assembly-cooperating in situ construction of MXene-CeO 2 as hybrid membrane coating for durable and high-performance proton exchange membrane fuel cell, ACS Sustain. Chem. Eng., 10, 4269-4278 (2022).
A. Al-Othman, M. F. Hassan, M. Tawalbeh, and A. Ka'ki, Proton conductivity studies in zirconium phosphate/MXenes in PEM fuel cells, Advances in Science and Engineering Technology International Conferences (ASET), IEEE, February 2022, 1-5.
J. Zhang, Y. Liu, Z. Lv, T. Zhao, P. Li, Y. Sun, and J. Wang, Sulfonated Ti3C2Tx to construct proton transfer pathways in polymer electrolyte membrane for enhanced conduction, Solid State Ion., 310, 100-111 (2017).

상세보기
Y. Liu, J. Zhang, X. Zhang, Y. Li, and J. Wang, Ti 3 C 2 T x filler effect on the proton conduction property of polymer electrolyte membrane, ACS Appl. Mater. Interfaces, 8, 20352-20363 (2016).
J. R. Varcoe and R. C. Slade, Prospects for alkaline anion-exchange membranes in low temperature fuel cells, Fuel Cells, 5, 187-200 (2005).

상세보기
M. Hren, M. Bozic, D. Fakin, K. S. Kleinschek and S. Gorgieva, Alkaline membrane fuel cells: Anion exchange membranes and fuels, Sustain. Energy Fuels, 5, 604-637 (2021).
W. E. Mustain, M. Chatenet, M. Page, and Y. S. Kim, Durability challenges of anion exchange membrane fuel cells, Energy Environ. Sci., 13, 2805-2838 (2020).

상세보기
R. Narducci, E. Sgreccia, P. Knauth, and M. L. Di Vona, Anion exchange membranes with 1D, 2D and 3D Fillers: A review, Polymers, 13, 3887 (2021).

상세보기
Z. Yang, M. Zhang, Z. Zhao, W. Lan, X. Zhang, and M. Fan, Application of 2D nanomaterial MXene in anion exchange membranes for alkaline fuel cells: Improving ionic conductivity and power density, Int. J. Hydrog. Energy, 47, 18122-18138 (2022).

상세보기
X. Zhang, C. Fan, N. Yao, P. Zhang, T. Hong, C. Xu, and J. Cheng, Quaternary Ti 3 C 2 T x enhanced ionic conduction in quaternizedpolysulfone membrane for alkaline anion exchange membrane fuel cells, J. Membr. Sci., 563, 882-887 (2018).

상세보기
L. Wang and B. Shi, Hydroxide conduction enhancement of chitosan membranes by functionalized MXene, Materials, 11, 2335 (2018).

상세보기

저자의 다른 논문 :

표제어: PCR

동의어: Packet Collision Rate

용어 설명 출처 목록 (6)

용어 설명: PCR은 세균 특이성이 있는 primer를 이용하여 적은 수의 세균이 있을지라도 쉽게 검출할 수 있는 유용한 방법이며, 이를 이용하여 구강 내 치면세균막이나 타액에서 직접 세균을 검출할 수 있게 되었다[8].

내보내기 구분	파일저장 인쇄 메일전송
구성항목	기본정보 상세정보 관리번호, 논문명, 저널/프로시딩명, 저자 , 발행년, 권, 호, 시작페이지, 끝페이지, 발행기관 관리번호, 논문명, 대등논문명, 저자 , 저널/프로시딩명, 발행기관, 발행년, 발행언어, 권, 호, 시작페이지, 끝페이지, ISBN, ISSN, 주제분야, 키워드, 초록(한글), 초록(영문), 저자(소속기관)
저장형식	Text(ASCII format) Excel format RefWorks Direct Export RIS format (for Reference Manager, ProCite, EndNote), Scholar's Aids, Mendeley
메일정보	받는사람 (필수) @ 보내는사람 (선택) @ 제목 내용 KISTI 검색결과 이메일 서비스
안내	총 건의 자료가 검색되었습니다. 다운받으실 자료의 인덱스를 입력하세요. (1-10,000) 검색결과의 순서대로 최대 10,000건 까지 다운로드가 가능합니다. 데이타가 많을 경우 속도가 느려질 수 있습니다.(최대 2~3분 소요) 다운로드 파일은 UTF-8 형태로 저장됩니다. 파일의 내용이 제대로 보이지 않을실 때는 웹브라우저 상단의 보기 -> 인코딩 -> 자동선택 여부를 확인하십시오. ~ Text(ASCII format) Excel format

연합인증