[논문]NCM 리튬 이온 배터리의 양극 표면 코팅물질에 따른 성능변화

유진욱; 표성규

doi:10.5695/jsse.2024.57.2.57

NCM 리튬 이온 배터리의 양극 표면 코팅물질에 따른 성능변화
Performance variation of Nickel-Cobalt-Manganese lithium-ion battery by cathode surface coating materials 원문보기

한국표면공학회지 = Journal of the Korean institute of surface engineering, v.57 no.2, 2024년, pp.57 - 70

유진욱 (중앙대학교 융합공학부) , 표성규 (중앙대학교 융합공학부)

Abstract ▼ AI-Helper

Nickel-cobalt-manganese (NCM) lithium-ion batteries(LIBs) are increasingly prominent in the energy storage system due to their high energy density and cost-effectiveness. However, they face significant challenges, such as rapid capacity fading and structural instability during high-voltage operation cycles. Addressing these issues, numerous researchers have studied the enhancement of electrochemical performance through the coating of NCM cathode materials with substances like metal oxides, lithium composites, and polymers. Coating these cathode materials serves several critical functions: it acts as a protection barrier against electrolyte decomposition, mitigates the dissolution of transition metals, enhances the structural integrity of the electrode, and can even improve the ionic conductivity of the cathode. Ultimately, these improvements lead to better cycle stability, increased efficiency, and enhanced overall battery life, which are crucial for the advancement of NCM-based lithium-ion batteries in high-demand applications. So, this paper will review various cathode coating materials and examine the roles each plays in improving battery performance.

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표/그림 (7)

그림 Fig. 1. Comparison of five different Lithium-ion batteries (Lithium cobalt oxide, Lithium manganese oxide, Lithium iron phosphate, Lithium nickel-cobalt-manganese, Lithium nickel-cobalt-aluminum) ; Reproduced with permission from ref [14]; Copyright 2019 MDPI.
그림 Fig. 2. Schematic illustration of surface coated cathode active material.
그림 Fig. 3. (a) Schematic diagram of the Al₂O₃ dry coating process, (b) Cycling performance of NMC dry-coated with different amounts of Al₂O₃. Nyquist plots of the uncoated and coated NCM by 1 wt% Al₂O₃. c) 4th charge, and d) 50th charge; Reproduced with permission from ref [35]; Copyright 2021 Wiley.
그림 Fig. 4. Schematic illustration of the difference in reaction of TiO₂-coated NCM and pristine NCM electrodes with electrolyte; Reproduced with permission from ref [36]; Copyright 2021 ACS Publications.
그림 Fig. 5. (a) Cyclic performance of TiO₂ coated and uncoated NCM at 1 C at room temperature. (b) Component variations of residual lithium (LiOH, Li₂CO₃) of pristine NCM and NCM@TiO₂ are exposed for a week (60 °C, 35% RH); Reproduced with permission from ref [32]; Copyright 2020 ACS Publications.
그림 Fig. 6. Surface SEM and TEM images of the (c),(d)bare and (a),(b)ZrO₂ coated NCM samples. Charge/discharge voltage profile; e) bare, f) ZrO₂ coated NCM; Reproduced with permission from ref [40]; Copyright 2021 Wiley.
그림 Fig. 7. Schematic illustration of (a) the mechanism of Lithium rich Mn based NCM @ Ph-COOH; Reproduced with permission from ref [44]; Copyright 2024 Wiley, and (b) the Polymer coated layer formed by the in situ self-polymerization of HFBM on the NCM cathode surface; Reproduced with permission from ref [45]; Copyright 2024 ACS Publications.

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