[논문]Microporous Carbon Nanoparticles for Lithium–Sulfur Batteries

Kang, Hui-Ju; Bari, Gazi A. K. M. Rafiqul; Lee, Tae-Gyu; Khan, Tamal Tahsin; Park, Jae-Woo; Hwang, Hyun Jin; Cho, Sung Yong; Jun, Young-Si

doi:10.3390/nano10102012

[해외논문] Microporous Carbon Nanoparticles for Lithium–Sulfur Batteries 원문보기

Nanomaterials, v.10 no.10, 2020년, pp.2012 -

Kang, Hui-Ju (Department of Advanced Chemicals & Engineering, Chonnam National University, 77 Yongbong-ro, Buk-gu, Gwangju 61186, Korea) , Bari, Gazi A. K. M. Rafiqul (gmlwn120@gmail.com (H.-J.K.)) , Lee, Tae-Gyu (grafiqulbari@gmail.com (G.A.K.M.R.B.)) , Khan, Tamal Tahsin (dlxorb007@gmail.com (T.-G.L.)) , Park, Jae-Woo (jaewoopark0218@gmail.com (J.-W.P.)) , Hwang, Hyun Jin (Department of Advanced Chemicals & Engineering, Chonnam National University, 77 Yongbong-ro, Buk-gu, Gwangju 61186, Korea) , Cho, Sung Yong (gmlwn120@gmail.com (H.-J.K.)) , Jun, Young-Si (grafiqulbari@gmail.com (G.A.K.M.R.B.))

Abstract ▼ AI-Helper

Rechargeable lithium–sulfur batteries (LSBs) are emerging as some of the most promising next-generation battery alternatives to state-of-the-art lithium-ion batteries (LIBs) due to their high gravimetric energy density, being inexpensive, and having an abundance of elemental sulfur (S8). However, one main, well-known drawback of LSBs is the so-called polysulfide shuttling, where the polysulfide dissolves into organic electrolytes from sulfur host materials. Numerous studies have shown the ability of porous carbon as a sulfur host material. Porous carbon can significantly impede polysulfide shuttling and mitigate the insulating passivation layers, such as Li2S, owing to its intrinsic high electrical conductivity. This work suggests a scalable and straightforward one-step synthesis method to prepare a unique interconnected microporous and mesoporous carbon framework via salt templating with a eutectic mixture of LiI and KI at 800 °C in an inert atmosphere. The synthesis step used environmentally friendly water as a washing solvent to remove salt from the carbon–salt mixture. When employed as a sulfur host material, the electrode exhibited an excellent capacity of 780 mAh g−1 at 500 mA g−1 and a sulfur loading mass of 2 mg cm−2 with a minor capacity loss of 0.36% per cycle for 100 cycles. This synthesis method of a unique porous carbon structure could provide a new avenue for the development of an electrode with a high retention capacity and high accommodated sulfur for electrochemical energy storage applications.

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