[논문]주석 페로브스카이트 태양전지에 관한 고찰: 재료 및 장치적 특성

최다영; 임세영; 김한결

doi:10.21218/cpr.2023.11.1.018

주석 페로브스카이트 태양전지에 관한 고찰: 재료 및 장치적 특성
Review on Tin Perovskite Solar Cells: Material and Device Properties 원문보기

Current photovoltaic research = 한국태양광발전학회논문지, v.11 no.1, 2023년, pp.18 - 26

최다영 (화학공학과, 포항공과대학교) , 임세영 (화학공학과, 포항공과대학교) , 김한결 (화학공학과, 포항공과대학교)

Abstract ▼ AI-Helper

Tin perovskite solar cells have attracted a lot of attention due to their potential to address the toxicity of lead, which is the biggest barrier to commercialization of perovskite solar cells. Unlike other lead-free perovskite, tin perovskite have a direct bandgap, which is suitable for use as light harvesting, and relatively good stability, which has led to a lot of attention. Since the first tin perovskite solar cell was reported in 2014, it has achieved an impressive power conversion efficiency of 14.81%. However, this efficiency is still low compared to that of lead perovskite solar cells, and the stability of tin perovskite solar cells is also an issue that needs to be addressed. In this review, we will discuss the basic properties of the tin atom in comparison to the lead atom, and then discuss the crystal structure, phase transition, and basic properties of tin perovskite. We will then discuss the advantages, applications, challenges, and strategies of tin perovskite, In particular, we will focus on how to prevent the oxidation of tin, which is arguably the biggest challenge for using tin perovskite solar cells. At the end, we summarize the key factors that need to be addressed for higher efficiency and stability, emphasizing what is needed to commercialize tin perovskite solar cells.

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표/그림 (5)

그림 Fig. 1. (a) Structure of halide based perovskite. (b) Elements applicable to the perovskite structure¹²⁾. (c) Element candidates that can be used as lead-free perovskites¹⁴⁾. (d) Characteristics of lead-free perovskites19). (e) Highest efficiency of tin perovskite solar cells by year²¹⁾. (f) Main strategies for stable tin perovskite solar cells²⁷⁾.
표 Table 1. Comparison of basic information of tin and lead atoms
그림 Fig. 2. (a) Structure of perovskite along the B-X-B angle³⁴⁾. (b) Changes in tin perovskite structure with temperature³⁵⁾. (c) Goldschmidt tolerance coefficients according to A cation, B cation and X anion³⁸⁾. (d) Energy levels of different perovskite compositions³⁴⁾.
표 Table 2. Effective masses of electrons and holes in tin and lead based perovskite, respectively
그림 Fig. 3. (a) Oxidation of tin with oxygen and water⁴⁷⁾. (b) Oxidation process of tin perovskite⁴⁸⁾. (c) Process of adding reductive to the precursor to prevent oxidation of tin perovskite⁴⁹⁾. (d) Process of adding TM-DHP to precursor to prevent oxidation of tin perovskite⁵³⁾. (e) Process of suppressing oxidation of tin perovskite by adding phenylhydrazinium halide antioxidant⁵⁸⁾.

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