[논문]고성능 이차 전지용 하이브리드 에너지 저장 메커니즘을 위한 고용체 화학

하시온; 김경호

doi:10.4313/jkem.2024.37.1.2

[국내논문] 고성능 이차 전지용 하이브리드 에너지 저장 메커니즘을 위한 고용체 화학
Hybrid Energy Storage Mechanism Through Solid Solution Chemistry for Advanced Secondary Batteries

전기전자재료학회논문지 = Journal of the Korean Institute of Electrical and Electronic Material Engineers, v.37 no.1, 2024년, pp.11 - 25

하시온 (부경대학교 재료공학과) , 김경호 (부경대학교 재료공학과)

Abstract ▼ AI-Helper

Lithium-ion batteries (LIBs) have attracted great attention as the common power source in energy storage fields of large-scale applications such as electrical vehicles (EVs), industries, power plants, and grid-scale energy storage systems (ESSs). Insertion, alloying, and conversion reactions are the main electrochemical energy storage mechanisms in LIBs, which determine their electrochemical properties and performances. The electrochemical reaction mechanisms are determined by several factors including crystal structure, components, and composition of electrode materials. This article reviews a new strategy to compensate for the intrinsic shortcomings of each reaction mechanism by introducing the material systems to form a single compound with different types of reaction mechanisms and to allow the simultaneous hybrid electrochemical reaction of two different mechanisms in a single solid solution phase.

주제어

표/그림 (12)

표 Table 1. Three different types of anode materials based on the lithium storage mechanism and their advantages and common issues.
그림 Fig. 1. Specific capacities and working potentials (V vs. Na/Na⁺) for different classes of anode materials for SIBs.
그림 Fig. 2. (a) Crystal structure, ionic radius of transition metal (TM), and formation enthalpy of various 1st row transition metal monophosphides (TM = Ti - Ni). Schematic illustration of three main energy storage mechanism as (b) insertion, (c) alloying, and (d) conversion reactions.
그림 Fig. 3. (a) Refined lattice parameters, (b) galvanostatic discharge/charge profiles, and (c) corresponding differential capacity plots (DCPs) of Mn1-xFexP (x=0.0, 0.5, 0.75, and 1.0) electrodes [☆ in (a) is the lattice parameter from ICDD] [11].
그림 Fig. 4. Cycling performance at a current density of (a) 2 A g^-1 for Mn_1-xFe_xP and CoP electrodes and (b) schematic illustration for the discharged state of MnP, FeP, and Mn1-xFexP electrodes [11].
그림 Fig. 5. (a) Crystal structures of VP and MnP, (b) Rietveld refined lattice parameters, and (c) prismatic site parameters of Mn_1-xV_xP (x=0, 0.25, 0.5, 0.75, and 1.0) [12].
그림 Fig. 6. (a) Galvanostatic discharge/charge voltage profiles and (b) corresponding differential capacity plots, and ex-situ XRD patterns for (i) pristine, (ii) fully lithiated (0.01 V vs. Li/Li⁺), and (iii) delithiated (2.0 V vs. Li/Li⁺) states of Mn_1-xV_xP (x = 0, 0.25, 0.50, 0.75, and 1.0) electrodes [12].
$Fig. 7. (a) HAADF STEM image, (b) corresponding FFT pattern, and (c) EDS mapping images of combination of Mn, V, and P K for fully lithiated Mn0.75V0.25P electrode. (d) Crystal structure illustration and diffraction pattern of aligned along the [100] direction for Li-inserted Mn0.75V0.25P, Li3MnP2, and hybrid alloying/insertion phases, respectively [12].$ 그림 Fig. 7. (a) HAADF STEM image, (b) corresponding FFT pattern, and (c) EDS mapping images of combination of Mn, V, and P K for fully lithiated Mn_0.75V_0.25P electrode. (d) Crystal structure illustration and diffraction pattern of aligned along the [100] direction for Li-inserted Mn_0.75V_0.25P, Li₃MnP₂, and hybrid alloying/insertion phases, respectively [12].
그림 Fig. 8. (a) Long-term cycle performance of Mn_1-xV_xP (x=0.25), MnP/VP (3:1), and commercial graphite electrodes at 1 A g^-1, (b) cross sectional SEM images before cycle and fully lithiated state for (b,c) MnP, (d,e) VP, and (f,g) Mn_0.75V_0.25P electrodes, respectively, and (h) schematic illustration for the cycling behavior of MnP/VP mixture and Mn_0.75V_0.25P solid solution electrodes [12].
그림 Fig. 9. (a) XRD patterns, (b) cycling performance at a current density of 500 mA g^-1 with activation of 3 cycles at 50 mA g^-1, and (c) nyquist plots after 50 cycles (inset figure for pristine state) for MnP₄ and Mn_0.75TM_0.25P₄ (TM = V and Fe) electrodes, respectively [The reference peaks for MnP4 (ICDD # 01-072-0949, black dash line), VP₄ (ICDD # 01-077-0262, green dash line), and FeP₄ (ICDD # 01-079-0486, brown dash line) are included in (a)] [13].
그림 Fig. 10. (a) XRD patterns of NiP_2-xS_x (x = 0, 0.5, 1.0, 1.5 and 2.0) nanopowders and (b) enlargement of the patterns in 2 theta range of 50~60° [The reference peaks for NiP₂ (ICDD # 01-073-0436, red dash line) and NiS₂ (ICDD # 01-078-4702, orange dash line) are included], and (c) 1st cycle dQ/dV plots of NiP_2-xS_x (x = 0, 0.5, 1.0, 1.5 and 2.0) at 50 mA g^-1 [14].
그림 Fig. 11. (a) The 1st cycle galvanostatic discharge/charge voltage profiles, (b) corresponding dQ/dV plots at 50 mA g^-1 and (c) the 1st discharge capacities at different current densities of the NiP_2-xS_x (x = 0, 0.5, and 2.0) and NiP₂/NiS₂ (3:1) electrodes. (d) Schematic illustration for the sodiation/desodiation process of the NiP_2-xS_x solid solution [14].

참고문헌 (27)

H. S. Das, M. M. Rahman, S. Li, and C. W. Tan, Renewable？Sustainable Energy Rev., 120, 109618 (2020).？doi: https://doi.org/10.1016/j.rser.2019.109618

상세보기
M. A. Hannan, M. M. Hoque, A. Mohamed, and A. Ayob,？Renewable Sustainable Energy Rev., 69, 771 (2017).？doi: https://doi.org/10.1016/j.rser.2016.11.171

상세보기
B. Xiao, J. Ruan, W. Yang, P. D. Walker, and N. Zhang,？Renewable Sustainable Energy Rev., 149, 111194 (2021).？doi: https://doi.org/10.1016/j.rser.2021.111194

상세보기
M. R. Khalid, I. A. Khan, S. Hameed, M.S.J. Asghar, and J. S.？Ro, IEEE Access, 9, 128069 (2021).？doi: https://doi.org/10.1109/ACCESS.2021.3112189

상세보기
C. D. Quilty, D. Wu, W. Li, D. C. Bock, L. Wang, L. M. Housel,？A. Abraham, K. J. Takeuchi, A. C. Markchilok, and E. S.？Takeuchi, Chem. Rev., 123, 1327 (2023).？doi: https://doi.org/10.1021/acs.chemrev.2c00214

상세보기
Y. Liu, G. Zhou, K. Liu, and Y. Cui, Acc. Chem. Res., 50, 2895？(2017).？doi: https://doi.org/10.1021/acs.accounts.7b00450

상세보기
G. G. Amatucci and N. Pereira, J. Fluorine Chem., 128, 243？(2007).？doi: https://doi.org/10.1016/j.jfluchem.2006.11.016

상세보기
J. Lu, Z. Chen, F. Pan, Y. Cui, and K. Amine, Electrochem.？Energy Rev., 1, 35 (2018).？doi: https://doi.org/10.1007/s41918-018-0001-4

상세보기
S. Chae, S. H. Choi, N. Kim, J. Sung, and J. Cho, Angew. Chem.？Int. Ed., 59, 110 (2020).？doi: https://doi.org/10.1002/anie.201902085

상세보기
H. J. Kwon, J. Y. Hwang, H. J. Shin, M. G. Jeong, K. Y. Chung,？Y. K. Sun, and H. G. Jung, Nano Lett., 20, 625 (2020).？doi: https://doi.org/10.1021/acs.nanolett.9b04395

상세보기
K. H. Kim, W. S. Kim, and S. H. Hong, Nanoscale, 11, 13494？(2019).？doi: https://doi.org/10.1039/c9nr02016k

상세보기
K. H. Kim, J. Oh, C. H. Jung, M. Kim, B. M. Gallant, and S. H.？Hong, Energy Storage Mater., 41, 310 (2021).？doi: https://doi.org/10.1016/j.ensm.2021.06.011

상세보기
K. H. Kim and S. H. Hong, Adv. Energy Mater., 11, 2003609？(2021).？doi: https://doi.org/10.1002/aenm.202003609

상세보기
H. H. Kim, K. H. Kim, and S. H. Hong, Chem. Eng. J., 455,？140798 (2023).？doi: https://doi.org/10.1016/j.cej.2022.140798

상세보기
P. G. Bruce, B. Scrosati, and J. M, Tarason, Angew. Chem. Int.？Ed., 47, 2930 (2008).？doi: https://doi.org/10.1002/anie.200702505

상세보기
M. G. Kim and J. Cho, Adv. Funct. Mater., 19, 1497 (2009).？doi: https://doi.org/10.1002/adfm.200801095

상세보기
J. H. Chen and K. H. Whitmire, Coord. Chem. Rev., 355, 271？(2018).？doi: https://doi.org/10.1016/j.ccr.2017.08.029

상세보기
C. M. Park, Y. U. Kim, and H. J. Sohn, Chem. Mater., 21, 5566？(2009).？doi: https://doi.org/10.1021/cm902745a

상세보기
C. Yao, J. Xu, Y. Zhu, R. Zhang, Y. Shen, and A. Xie, Appl.？Surf. Sci., 513, 145777 (2020).？doi: https://doi.org/10.1016/j.apsusc.2020.145777

상세보기
G. Cai, Z. Wu, T. Luo, Y. Zhong, X. Guo, Z. Zhang, X. Wang,？and B. Zhong, RSC Adv., 10, 3936 (2020).？doi: https://doi.org/10.1039/c9ra10729k

상세보기
D. Bresser, S. Passerini, and B. Scrosati, Energy. Environ. Sci.,？9, 3348 (2016).？doi: https://doi.org/10.1039/c6ee02346k

상세보기
F. Wu, J. Bai, J. Feng, and S. Xiong, Nanoscale, 7, 17211 (2015).？doi: https://doi.org/10.1039/c5nr04791a

상세보기
G. Martin, L. Rentsch, M. Hock, and M. Bertau, Energy Storage？Mater., 6, 171 (2017).？doi: https://doi.org/10.1016/j.ensm.2016.11.004

상세보기
K. Chayambuka, G. Mulder, D. L. Danilov, and P.H.L. Notten,？Adv. Energy Mater., 8, 1800079 (2018).？doi: https://doi.org/10.1002/aenm.201800079

상세보기
P. K. Nayak, L. Yang, W. Brehm, and P. Adelhelm, Angew.？Chem. Int. Ed., 57, 102 (2018).？doi: https://doi.org/10.1002/anie.201703772

상세보기
E. Edison, S. Sreejith, C. T. Lim, and S. Madhavi, Sustainable？Energy Fuels, 2, 2567 (2018).？doi: https://doi.org/10.1039/c8se00381e

상세보기
N. Gong, C. Deng, B. Wan, Z. Wang, Z. Li, H. Gou, and F. Gao,？Inorg. Chem., 57, 9385 (2018).？doi: https://doi.org/10.1021/acs.inorgchem.8b01380

상세보기

표제어: PCR

동의어: Packet Collision Rate

용어 설명 출처 목록 (6)

용어 설명: PCR은 세균 특이성이 있는 primer를 이용하여 적은 수의 세균이 있을지라도 쉽게 검출할 수 있는 유용한 방법이며, 이를 이용하여 구강 내 치면세균막이나 타액에서 직접 세균을 검출할 수 있게 되었다[8].

내보내기 구분	파일저장 인쇄 메일전송
구성항목	기본정보 상세정보 관리번호, 논문명, 저널/프로시딩명, 저자 , 발행년, 권, 호, 시작페이지, 끝페이지, 발행기관 관리번호, 논문명, 대등논문명, 저자 , 저널/프로시딩명, 발행기관, 발행년, 발행언어, 권, 호, 시작페이지, 끝페이지, ISBN, ISSN, 주제분야, 키워드, 초록(한글), 초록(영문), 저자(소속기관)
저장형식	Text(ASCII format) Excel format RefWorks Direct Export RIS format (for Reference Manager, ProCite, EndNote), Scholar's Aids, Mendeley
메일정보	받는사람 (필수) @ 보내는사람 (선택) @ 제목 내용 KISTI 검색결과 이메일 서비스
안내	총 건의 자료가 검색되었습니다. 다운받으실 자료의 인덱스를 입력하세요. (1-10,000) 검색결과의 순서대로 최대 10,000건 까지 다운로드가 가능합니다. 데이타가 많을 경우 속도가 느려질 수 있습니다.(최대 2~3분 소요) 다운로드 파일은 UTF-8 형태로 저장됩니다. 파일의 내용이 제대로 보이지 않을실 때는 웹브라우저 상단의 보기 -> 인코딩 -> 자동선택 여부를 확인하십시오. ~ Text(ASCII format) Excel format

연합인증