[논문]2차원 결정성 탄소 소재의 최근 이차전지 소재 개발 동향: 그래핀(graphene)과 그라파인(graphyne)의 이차전지 개발 최근 동향

이혁진; 봉성율

doi:10.5229/jkes.2022.25.4.162

2차원 결정성 탄소 소재의 최근 이차전지 소재 개발 동향: 그래핀(graphene)과 그라파인(graphyne)의 이차전지 개발 최근 동향
Progress in Recent Research of 2D and Crystalline Carbon Materials in Secondary-ion Battery Application 원문보기

전기화학회지 = Journal of the Korean Electrochemical Society, v.25 no.4, 2022년, pp.162 - 173

이혁진 (공주대학교 화학교육과) , 봉성율 (공주대학교 화학교육과)

초록
AI-Helper

우리의 삶에 있어 새로운 물질의 개발/발견은 전 세계의 환경 및 에너지 문제를 해결하는 데 필수적인 열쇠이다. 이러한 관점에서 결정성 탄소계 2차원 재료는 벌집 또는 sp/sp² 하이브리드 구조의 탄소 소재의 전기 전도도, 화학적 안정성, 표면 공학 등 다양한 관점에서 오랜 시간 동안 연구되어 왔다. 특히, 그래핀을 포함한 새로운 2차원 탄소 소재 개발은 신재생 에너지 분야에서 수십 년 동안 지속적으로 개발되고 있다. 구체, 입방체 등의 다양한 구조 형태의 금속나노입자와 함께 복합화하여 시너지 효과를 낼 수 있는 탄소동소체가 연구되고 있으며, 이를 통하여 신재생 에너지 분야의 디바이스 성능이 획기적으로 향상되고 있다. 본 총설에서는 2D 탄소동소체 재료, 그래핀 및 그라파인의 연구 방향과 재생 에너지 분야의 성능을 향상시키기 위한 응용 방법을 소개하고자 한다.

Abstract ▼ AI-Helper

The development of new materials is an essential key for unraveling the environmental and energy problems all over the world. Among the various application materials in this area, crystalline and two-dimensional carbon materials have been studied from points of view such as electrical conductivity, chemical stability, and surface engineering due to the assembly of honeycomb and sp/sp2 hybridization structure. Novel two-dimensional materials, including graphene and graphyne, have been continuously reported for several decades to develop in renewable energy fields. Also, various pristine/engineered two-dimensional carbon allotropes have been researched to combine metal nanoparticles in the form of a sphere, cubic, and so on. The renewable energy performance to apply for these materials is drastically increased. In this review, we introduce the research points of the 2D carbon allotrope materials, graphene and graphyne, and applications to improve the performance of renewable energy applications.

주제어

표/그림 (8)

그림 Fig. 1. Various structures of graphene (0D bucky ball, 1D carbon nanotube, 3D graphite).^5,6)
그림 Fig. 2. Schematic illustration showing synthesis of graphene nanosheet supported catalyst. (1) Oxidation of graphite to graphite oxide with larger inter layer distance, (2) exfoliation of graphite oxide by ultrasonication and (3) preparation of GNS based catalyst by colloidal method.¹³⁾
그림 Fig. 3. Schematic of general elementary steps of a typical CVD process. First, reactant gases (blue circles) are transported into the reactor (step a). Then, there are two possible routes for the reactant gases: directly diffusing through the boundary layer (step b) and adsorbing onto the substrate (step c); or forming intermediate reactants (green circles) and by-products (red circles) via the gas-phase reaction (step d) and being deposited onto the substrate by diffusion (step b) and adsorption (step c). Surface diffusion and heterogeneous reactions (step e) take place on the surface of substrate before the formation of thin films or coatings. Finally, by-products and unreacted species are desorbed from the surface and forced out of the reactor as exhausts (step f). CVD, chemical vapour deposition.¹⁴⁾
그림 Fig. 4. 2D graphyne structure.^3,21)
그림 Fig. 5. (a) E_ads of Li adsorbed on the monolayer graphyne under different strains: 0, 6, 10, and 12%. The maximum Li capacity of Li-adsorbed monolayer graphyne under the strain of (b) 0, (c) 6, (d) 10, and (e) 12%. The blue, yellow, and red balls in (e) represent the first, second, and third Li layers, respectively. (Reprinted with permission from ref 64. Copyright (2018) American Chemical Society.)
표 Table 1. Comparison and evaluation of graphene doping with different methods²⁵⁾
그림 Fig. 6. (a) Total energy with the interlayer distance of multilayer graphyne without strain and under the 12% strain. The top and side view of (b) Li-intercalated graphyne (Li₃C₆) without strain, (c) Li-intercalated graphyne (Li₆C₆) under the 12% strain, and (d) Li-intercalated graphyne (Li₇C₆) under the 12% strain. (Reprinted with permission from ref 64. Copyright (2018) American Chemical Society.)
그림 Fig. 7. Holey graphyne (HGY) produced using bottom-up synthesis. The molecular structure of HGY is highly consistent with alternately linked benzene rings and C ≡ C bonds, comprised of six-vertex and highly strained eight-vertex rings and an equal percentage of sp² and sp hybridized carbon atoms.⁶⁶⁾

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표제어: PCR

동의어: Packet Collision Rate

용어 설명 출처 목록 (6)

용어 설명: PCR은 세균 특이성이 있는 primer를 이용하여 적은 수의 세균이 있을지라도 쉽게 검출할 수 있는 유용한 방법이며, 이를 이용하여 구강 내 치면세균막이나 타액에서 직접 세균을 검출할 수 있게 되었다[8].

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저장형식	Text(ASCII format) Excel format RefWorks Direct Export RIS format (for Reference Manager, ProCite, EndNote), Scholar's Aids, Mendeley
메일정보	받는사람 (필수) @ 보내는사람 (선택) @ 제목 내용 KISTI 검색결과 이메일 서비스
안내	총 건의 자료가 검색되었습니다. 다운받으실 자료의 인덱스를 입력하세요. (1-10,000) 검색결과의 순서대로 최대 10,000건 까지 다운로드가 가능합니다. 데이타가 많을 경우 속도가 느려질 수 있습니다.(최대 2~3분 소요) 다운로드 파일은 UTF-8 형태로 저장됩니다. 파일의 내용이 제대로 보이지 않을실 때는 웹브라우저 상단의 보기 -> 인코딩 -> 자동선택 여부를 확인하십시오. ~ Text(ASCII format) Excel format

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