[논문]Ti3Ci2Tix MXene 기반 전극 소재의 자가 치유 적용 기술 개발 동향

최준상; 정승부; 김종웅

doi:10.6117/kmeps.2023.30.3.020

[국내논문] Ti3Ci2Tix MXene 기반 전극 소재의 자가 치유 적용 기술 개발 동향
Recent Progress of Ti3Ci2Tix MXene Electrode Based Self-Healing Application 원문보기

마이크로전자 및 패키징 학회지 = Journal of the Microelectronics and Packaging Society, v.30 no.3, 2023년, pp.20 - 34

최준상 (성균관대학교 지능형팹테크융합전공) , 정승부 (성균관대학교 신소재공학과) , 김종웅 (성균관대학교 지능형팹테크융합전공)

초록
AI-Helper

수 나노미터의 두께의 단일 또는 여러 층으로 구성된 2차원 소재는 전기전도성, 유연성, 광학적 투명성 등의 고유한 특성으로 많은 연구 분야에서 활용되고 있다. 이 중 Electronic skin (E-Skin)이나 Smart Textile 과 같은 반복적인 기계적 동작이 수반될 수 있다. 또한, 온도, 습도, 압력과 같은 외부적 요인에 노출이 되는 경우가 빈번하다. 이 때, 소자의 내구성과 수명 저하를 유발하기 때문에 자가 치유 특성이 내포된 소자를 제작하기 위한 연구가 많이 이루어지고 있다. 최근 다양한 2차원 소재 중 자가 치유 기능을 구현할 수 있는 Ti₃Ci₂Ti_x MXene 기반 전극의 복합 소재의 연구 결과가 학계의 주목을 받고 있다. 본 논문에서는 Ti₃Ci₂Ti_x MXene의 다양한 합성 방법 및 특성에 대해 소개한 후, Ti₃Ci₂Ti_x MXene 전극 기반의 자가 치유 적용 기술 사례에 대해 알아보고자 한다.

Abstract ▼ AI-Helper

Single or multi-layered two-dimensional (2D) materials, with thicknesses in the order of a few nanometers, have garnered substantial attention across diverse research domains owing to their distinct properties, including electrical conductivity, flexibility, and optical transparency. These materials are frequently subjected to repetitive mechanical actions in applications like electronic skin (E-Skin) and smart textiles. Moreover, they are often exposed to external factors like temperature, humidity, and pressure, which can lead to a deterioration in component durability and lifespan. Consequently, significant research efforts are directed towards developing self-healing properties in these components. Notably, recent investigations have revealed promising outcomes in the field of self-healing composite materials, with Ti3Ci2Tix MXene being a prominent component among the myriad of available 2D materials. In this paper, we aim to introduce various synthesis methods and characteristics of Ti3Ci2Tix MXene, followed by an exploration of self-healing application technologies based on Ti3Ci2Tix MXene.

주제어

표/그림 (9)

그림 Fig. 1. Anticorrosion/self-healing mechanism of f-MXene@PU coating⁸³⁾.
그림 Fig. 2. (a) Digital photographs of the self-healing behaviors of samples. SEM images of (b) cut sample, (c) surface and (d) interior of healed sample. (e) Tensile stress-strain curves of original and healed sample. (f) Mechanism diagram of self-healing progress⁸⁴⁾
그림 Fig. 3. (a) Fracture and reconstruction of hydrogen bonds and imine bonds in A-MXenes/D-PDMS; (b) stereomicroscope images (scale bar, 500 μm) of 10 wt% A-MXene/D-PDMS damaged and healed samples; (c) stretching, bending, and twisting photos of a healed sample; (d) stress-strain curve of samples before and after self-healing; and (e) stress-strain curves of 10 wt % A-MXenes/DPDMS original samples, 6 h repaired samples, 12 h repaired samples, and 24 h repaired samples ⁸⁵⁾.
그림 Fig. 4. (a) The self-healing behavior of the MXene-PAA-ACC hydrogel: (I) original hydrogel, (II) completely broken hydrogel, (III) selfhealed hydrogel, and (IV) stretched hydrogel after self-healing. (b) Cyclic strain sweeps of the MXene-PAA-ACC hydrogel. (c) A circuit consisting of the MXene-PAA-ACC hydrogel in series with a red LED bulb: (I) original hydrogel, (II) completely broken hydrogel, (III) self-healed hydrogel, and (IV-VI) the corresponding schematic diagrams of the circuit⁸⁷⁾.
그림 Fig. 5. (a) Digital photographs showing the self-healing property of the PVA-CA-MXene hydrogel. (b) Self-heal ability test through using PVA-CA-MXene hydrogel as connecter between the battery (18 V) and LED indicator. (c) Real-time resistance of hydrogel during several cycles of bifurcation and self-healing, and (d) the time evolution of the healing process⁸⁸⁾.
그림 Fig. 6. (a) Tensile properties of PAM/TA/MXene hydrogels with different TA concentrations. (b) Tensile properties of PTSM hydrogels at different SA concentrations. (c) Optical picture of the hydrogel stretching process. (d) Loading-unloading curves of PTSM hydrogel at 1000% strain for 100 consecutive cycles. (e) Loading-unloading curves of PTSM hydrogels at 100, 2000, and 3000% strain. (f, g) Mechanical properties of hydrogels under different healing times. Optical pictures of PTSM hydrogels for (h) conductivity and (i) adhesion measurements⁸⁹⁾.
그림 Fig. 7. Performance and application of 3D self-healing MSCs. (a) Cyclic voltammogram curves (50 mV s-1), (b) galvonostatic charge- discharge (0.4 mA cm-2) curves, and (c) Nyquist curves of the original and after several self-healings of MSC. (d) Photographs of the 3D self-healing MSC (the left is the original MSC, the middle is the MSC after cutting, the right is MSC after self-healing). (e) SEM image of perovskite nanowires. (f) XRD patterns of PbI2 and perovskite nanowires. (g,h) Illustration and circuit diagram of MSCs driving a perovskite nanowire based photodetector. (i) Performances of a photodetector driven by the original and after a healing cycle on MSC (red curve corresponds to an original MSC, and the black curve corresponds to the MSC after a healing cycle)⁹²⁾.
$Fig. 8. (a) Digital photographs showing the self-healing behaviors of the WPU@MXene3/PEG under the NIR light irradiation, (b) tensile stress-strain curves of the original and healed sample, POM images showing the self-healing process of fractures for the (c) cut sample and (d) healed sample, (e) visual images showing the healed sample withstood bending deformation, (f) FTIR spectra of the original and healed samples<sup>93)</sup>.$ 그림 Fig. 8. (a) Digital photographs showing the self-healing behaviors of the WPU@MXene3/PEG under the NIR light irradiation, (b) tensile stress-strain curves of the original and healed sample, POM images showing the self-healing process of fractures for the (c) cut sample and (d) healed sample, (e) visual images showing the healed sample withstood bending deformation, (f) FTIR spectra of the original and healed samples⁹³⁾.
그림 Fig. 9. Sensing performance of the MXene/rGO aerogel pressure sensor. (A) High-precision pressure sensing system. (B) I-V curves of the pressure sensor under different pressures; the good linearity indicates excellent ohmic characteristics. (C) Sensitivity curves of the sensor. (D) I-t curves of the sensor at different pressures. (E) Sensor recognition for different speeds at 25.32 kPa. (F) Fast response (10 ms) and recovery (5 ms) times at 5.12 kPa. (G) I-t and P-t curves; the good coincidence indicates the characteristic of fast response. (H) Excellent stability (>25,000 cycles) at 13.26 kPa. (I) Bending test platform. (J) I-t curves for different bending angles. (K) Self-healing process of the sensor, which can still bear 100 g of weight after self-repair. (L) Sensing capability retained by the sensor after multiple self-repair treatments⁹⁴⁾.

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저자의 다른 논문 :

표제어: PCR

동의어: Packet Collision Rate

용어 설명 출처 목록 (6)

용어 설명: PCR은 세균 특이성이 있는 primer를 이용하여 적은 수의 세균이 있을지라도 쉽게 검출할 수 있는 유용한 방법이며, 이를 이용하여 구강 내 치면세균막이나 타액에서 직접 세균을 검출할 수 있게 되었다[8].

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